Synthesis and characterisation of copolyesters from poly(ethylene terephthalate) and poly(hexamethylene terephthalate)

Copolyesters containing poly(ethylene terephthalate) and poly(hexamethylene terephthalate) (PHT) were prepared by a melt condensation reaction. The copolymers were characterised by infrared spectroscopy and intrinsic viscosity measurements. The density of the copolyesters decreased with increasing percentage of PHT segments in the backbone. Glass transition temperatures (T_g). melting points (T_m) and crystallisation temperatures (T_c) were determined by differential scanning calorimetry. An increase in the percentage of PHT resulted in decrease in T_g, T_m and T_c. The as-prepared copolyesters were crystalline in nature and no exotherm indicative of cold crystallisation was observed. The relative thermal stability of the polymers was evaluated by dynamic thermogravimetry in a nitrogen atmosphere. An increase in percentage of PHT resulted in a decrease in initial decomposition temperature. The rate of crystallisation of the copolymers was studied by small angle light scattering. An increase in percentage of PHT resulted in an increase in the rate of crystallisation.     

Effect of structure on the thermal behaviour of ethynyl-terminated imide resins

A series of ethynyl-terminated aromatic imide monomers containing phosphine oxide in the backbone were synthesized by the reaction of tris(3-aminophenyl) phosphine oxide (TAP) or bis(3-aminophenyl)methyl phosphine oxide (BAP) with pyromellitic dianhydride (PMDA) or 3, 3′,4, 4′-benzophenone tetracarboxylic acid dianhydride (BTDA) or 4, 4′-perfluoroisopropylidenebis(phthalic anhydride), and 3-ethynyl aniline. Structural characterization was done by infrared, nuclear magnetic resonance spectroscopy and elemental analysis. Thermal characterization was done by differential scanning calorimetry and thermogravimetric analysis. The decomposition temperatures of cured resins were above 500°C in nitrogen atmosphere. Char yield at 800°C ranged from 52–63.5%.     

Template‐Free Fabrication of Mesoporous Alumina Nanospheres Using Post‐Synthesis Water‐Ethanol Treatment of Monodispersed Aluminium Glycerate Nanospheres for Molybdenum Adsorption

This work reports the template‐free fabrication of mesoporous Al₂O₃ nanospheres with greatly enhanced textural characteristics through a newly developed post‐synthesis “water‐ethanol” treatment of aluminium glycerate nanospheres followed by high temperature calcination. The proposed “water‐ethanol” treatment is highly advantageous as the resulting mesoporous Al₂O₃ nanospheres exhibit 2–4 times higher surface area (up to 251 m² g^?1), narrower pore size distribution, and significantly lower crystallization temperature than those obtained without any post‐synthesis treatment. To demonstrate the generality of the proposed strategy, a nearly identical post‐synthesis “water treatment” method is successfully used to prepare mesoporous monometallic (e.g., manganese oxide (MnO₂)) and bimetallic oxide (e.g., CuCo₂O₄ and MnCo₂O₄) nanospheres assembled of nanosheets or nanoplates with highly enhanced textural characteristics from the corresponding monometallic and bimetallic glycerate nanospheres, respectively. When evaluated as molybdenum (Mo) adsorbents for potential use in molybdenum‐99/technetium‐99m (⁹⁹Mo/^99mTc) generators, the treated mesoporous Al₂O₃ nanospheres display higher molybdenum adsorption performance than non‐treated Al₂O₃ nanospheres and commercial Al₂O₃, thereby suggesting the effectiveness of the proposed strategy for improving the functional performance of oxide materials. It is expected that the proposed method can be utilized to prepare other mesoporous metal oxides with enhanced textural characteristics and functional performance.     

A review on solar still: a simple desalination technology to obtain potable water

Present review paper presents an overall summarised presentational view of the research work to be discussed on the solar still. The current review paper also includes the infused crisis and struggle for obtaining fresh water for drinking purpose and consumption for other household activities which are a result of the ecological imbalance that has prevailed and is in continuation for past many centuries. It also shows the various tested and applied techniques for freshwater production and their suitability in the usability context in the present scenario of the scarcity of clean water. The use of solar desalination technology is discussed elaborately for a broader consumption to be employed in the current and future works.     

Fuel economy standards for light duty vehicles and their potential to aid Iran toward achieving fuel saving and emissions reduction

At this time, more than 58.4 % of the total amount of oil productions in Iran is consumed in the transportation section. Different fuel saving initiatives and approaches such as the fuel economy standards and labels program for motor vehicles in the transportation section have been applied in many developed countries. This work investigates the influence of executing the fuel economy standard program on the fuel saving and its effects on the environment. The calculation of the standards program is done consider to the data of motor vehicles in Iran. It is found that by implementing the program around 3.81 billion liters of fuel is expected to be saved, from 2013 to 2018. Also, it is estimated that the emission reduction of some gases such as CO₂, CO, and NO _x is equal to 7.35 million ton, 2.54, and 1.2 ton, respectively.     

A review on fuel economy test procedure for automobiles: Implementation possibilities in Malaysia and lessons for other countries

Automobiles are considered as the main energy consumer in the transportation sector. According to the National Energy Balance, its accounted for about 36% of the total energy consumption in Malaysia. In order to reduce energy consumption in this sector, this country must consider setting fuel economy standards for motor vehicles sometime in near future. The first step toward developing fuel economy standards is to create a precise test and rating procedure for the automobiles. The test procedure is the technical foundation for all related programs namely; fuel economy standards, fuel economy labels and incentive programs. The test conditions should represent the driving situations and environment of the country. This paper is attempts to present a critical review on fuel economy testing procedure around the world and to propose a process for selecting a fuel economy test procedure for automobiles based on the conditions and requirements of the country. The internationally recognize test procedure adopted by several countries is also presented in this paper. Even though the paper only discusses the test procedure for automobiles, the methods can be directly applied for other types of vehicles and in other countries without major modifications.     

Comparative Study on Thermodynamic Analysis of CO2 Utilization Reactions

Thermodynamic analysis of dimethyl ether (DME) and methane synthesis from CO₂ hydrogenation, and dry reforming of methane was performed using Gibbs free energy minimization. The effects of temperature, pressure, and feed composition on conversion, selectivity, and yield were investigated for each process. High pressure, high H₂/CO₂ ratio, and low temperature favored DME production. The yield of methane during CO₂ methanation increased at lower temperature, higher pressure, and H₂/CO₂ ratio. The yield of synthesis gas improved at higher temperature. Comparison of the three processes demonstrated that the CO₂ conversion was highest during CO₂ methanation reaction if the fraction of CO₂ mol in the feed was less than 0.3. Above this value in the feed, dry reforming allowed the highest CO₂ conversion.     

Natural gas and CO2 price variation: impact on the relative cost-efficiency of LNG and pipelines

This article develops a formal model for comparing the cost structure of the two main transport options for natural gas: liquefied natural gas (LNG) and pipelines. In particular, it evaluates how variations in the prices of natural gas and greenhouse gas emissions affect the relative cost-efficiency of these two options. Natural gas is often promoted as the most environmentally friendly of all fossil fuels, and LNG as a modern and efficient way of transporting it. Some research has been carried out into the local environmental impact of LNG facilities, but almost none into aspects related to climate change. This paper concludes that at current price levels for natural gas and CO₂ emissions the distance from field to consumer and the volume of natural gas transported are the main determinants of transport costs. The pricing of natural gas and greenhouse emissions influence the relative cost-efficiency of LNG and pipeline transport, but only to a limited degree at current price levels. Because more energy is required for the LNG process (especially for fuelling the liquefaction process) than for pipelines at distances below 9100 km, LNG is more exposed to variability in the price of natural gas and greenhouse gas emissions up to this distance. If the prices of natural gas and/or greenhouse gas emission rise dramatically in the future, this will affect the choice between pipelines and LNG. Such a price increase will be favourable for pipelines relative to LNG.     

A novel hybrid model of Bagging-based Naïve Bayes Trees for landslide susceptibility assessment

Bulletin of Engineering Geology and the Environment - Landslide susceptibility assessment was performed using the novel hybrid model Bagging-based Naïve Bayes Trees (BAGNBT) at Mu Cang Chai...     

A review on fuel economy standard for motor vehicles with the implementation possibilities in Malaysia

This paper focused on a review of international experiences on fuel economy standard based on technologies available. It also attempts to identify savings possibilities and greenhouse gas (GHG) emissions reductions. It is known that road transport, particularly private cars are responsible for large, and increasing share of transport fuel use and emissions. With the implementation of fuel economy standard and label for motor vehicles, it will reduce the risks of increasing dependency on petroleum-based fuel and will increase the profit to consumers. The GHG emissions, which causing global warming, air pollution, diseases, etc. can be reduced as well. In this regard, advanced technologies such as, engine, transmission, and vehicle technologies may brought significant consumers and social benefits. Studies in developed countries have shown that fuel economy standard is beneficial for the society, government as well as the environment.