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排序方式: 共有240条查询结果,搜索用时 10 毫秒
1.
Toshimitsu Suzuki Osamu Yamada Yasuhiko Takahashi Yoshihisa Watanabe 《Fuel Processing Technology》1985,10(1):33-43
Hydroliquefaction of low-sulfur Australian coals (Wandoan and Yallourn) was studied using iron carbonyl complexes as catalyst. The addition of Fe(CO)5 (2.8 wt% Fe of coal) increased coal conversion from 48.6 to 85.2% for Wandoan coal, and from 36.7 to 69.7% for Yallourn coal in 1-methylnaphthalene at 425°C under an initial hydrogen pressure of 50 kg cm?2. When molecular sulfur was added to iron carbonyls (Fe(CO)5, Fe2(CO)9 and Fe3(CO)12), higher coal converions ( > 92%) and higher oil yields (>46%) were obtained, along with an increase in the amount of hydrogen transferred to coal from the gas phase (0.2 to 2.8%, d.a.f. coal basis). In the liquefaction studies using a hydrogen donor solvent, tetralin, Fe(CO)5S catalyst increased the amount of hydrogen absorbed from the gaseous phase and decreased the amount of naphthalene dehydrogenated from tetralin. The direct hydrogen transfer reaction from molecular hydrogen to coal fragment radicals seems to be a major reaction pathway. Organic sulfur compounds, dimethyldisulfide and benzothiophene, and inorganic FeS2 and NiS were found to be good sulfur sources to Fe(CO)5. From X-ray diffraction analyses of liquefaction residues, it is concluded that Fe(CO)5 was converted into pyrrhotite (Fe1?xS) when sulfur was present, but into Fe3O4 in the absence of sulfur. 相似文献
2.
This paper introduces the Precise Rendering Method, which generates accurately anti-aliased and highlighted images from tessellated polygons. The Precise Rendering Method first solves the aliasing problems of hidden surface removal by using the Cross Scanline Algorithm. This algorithm can exactly calculate polygon areas projected onto each pixel by using horizontal and vertical scanlines. Aliasing artifacts in shading are then prevented by the Reflection Intergration Method, which analytically integrates the intensity of reflection in the solid angle defined by surface normals at vertices of the projected area. Several synthesized images are created to show the efficiency of the Precise Rendering Method. 相似文献
3.
Na-oyoshi Iwasaki Takanori Miyake Eriko Yagasaki Toshimitsu Suzuki 《Catalysis Today》2006,111(3-4):391-397
Attention has been increasingly paid to the partial oxidation of lower alkanes to synthesis gas, due to its intrinsic energy saving process. We studied the partial oxidation of ethane (POE) on Co loaded on various supports. The POE performance varied as follows: Y2O3, CeO2, ZrO2, La2O3 SiO2, Al2O3, TiO2 > MgO. Comparing Y2O3 and CeO2, the carbon deposition during the POE was negligible on CeO2 and therefore CeO2 was the most preferable support. By changing space velocity and O2 partial pressure, reaction mechanism of POE was studied and it was revealed that two-step mechanism was prevailing; combustion of ethane to H2O and CO2 and subsequent reforming of ethane with H2O and CO2 to synthesis gas. Co/CeO2 catalyst exhibited high and stable catalytic activity for 10 h; high ethane conversion of 18% (maximum ethane conversion 20% at O2/C2H6 = 0.2) with H2 and CO selectivities of 93 and 84%, respectively. 相似文献
4.
Maki Itoh Toshimitsu Suzuki Yoshihiko Tsujimoto Ken-ichi Yoshii Yoshinobu Takegami Yoshihisa Watanabe 《Fuel》1983,62(1):98-102
Thermal cracking of tar-sand bitumens has been carried out using a two-stage pyrolysis reactor with temperature zones of 440°C and 750–800°C, respectively. Feedstocks were pyrolysed in the first stage into cracked oils, which were carried to the second stage for subsequent pyrolysis. Only 12–14 wt% of ethylene was obtained from tar-sand bitumens at the residence time of 1.2 s in the second stage, although 27 and 16 wt% were obtained from Taching and Iranian heavy vacuum residues, respectively. The tar-sand bitumens contain shorter paraffinic straight-chains and have more branched molecules than the vacuum residues of petroleum. A straight-chain paraffin index is proposed, with which a good correlation was obtained between ethylene yield and the fraction of straight-chain paraffin carbons in the heavy oil. 相似文献
5.
Preparation of zinc ferrite in the presence of carbon material and its application to hot-gas cleaning 总被引:3,自引:0,他引:3
In order to develop an efficient absorbent of H2S in coal gasification, zinc ferrite (ZnFe2O4) was prepared in the presence of carbon materials such as activated carbon (AC), activated carbon fiber (ACF), and Yallourn coal (YL). The absorption behavior of absorbents for H2S was examined using a fixed-bed flow type reactor equipped with a quadrupole mass spectrometer.Carbon material-supported ZnFe2O4 exhibited larger desulfurization capacity for H2S than unsupported ferrites. They could efficiently remove H2S from 4000 ppm levels in a simulated coal gasification gas to less than 1 ppm at 500 °C. The absorption capacity of H2S with ZnFe2O4/AC, ZnFe2O4/ACF, and ZnFe2O4/YL exhibited nearly 100% of stoichiometric amount of loaded metal species. They could be regenerated by an air oxidation in O2-Ar (50 vol%) at 450 °C for 30 min. The regenerated ferrite can be used for repeated absorption of H2S with a very slight decrease in the absorption capacity. 相似文献
6.
W. Ariyasriwatana W. Buente M. Oshiro D. Streveler 《New Review of Hypermedia and Multimedia》2013,19(4):317-340
Yelp, a social media site, undeniably has an influence on consumers' food choice in spite of its ability to reflect consumers' real voice being criticized. Since unhealthy food choices contribute to health problems, such as obesity and malnourishment, we attempted to examine these problems by better understanding consumers through health-related cues to action—a construct from the Health Belief Model (HBM)— on Yelp Honolulu's restaurant reviews. Our research revealed 13 main categories: Ingredient, Type of food, Taste, Lifestyle, Cooking, Option, Price, Portion, Well-being, Nutrition, Hygiene, Emotional attachment and indulgence, and Feeling. We argue that these categories may ultimately lead consumers to make healthier food choices. In search of the most appealing way to communicate with the target group, underlying concepts that derived from these categories can be tested. Marketers in food industry (or public health policy-makers) can craft their strategies for healthy food brands/products (or healthy eating scheme) based on the concept test research. Moreover, Yelp can apply these insights in the development of their algorithm and filter system in order to help consumers find healthy food if they wish to do so. Restaurants can also improve their strategy, menu, and communication execution to meet the growing demands of health conscious consumers. 相似文献
7.
This article proposes a function for color information detection using genetic programming (GP). In image-processing, object
detection is one of the important processes. In cases where the object has a complex color domain, detection becomes more
difficult. We generated a detection function for a complex color domain by using GP. The detection function deals with one
pixel of an input image, and it obtains an output image by processing for all pixels. We aimed at a reduction in the time
taken by a human to consider an image-processing system design. We applied the generation of GP to detect a target color region
in actual images. The results show that the detection function has sufficient ability for these detections. 相似文献
8.
Abstract The dynamic properties of doubly-scattered speckles produced at the image plane have been investigated using a scattering model that consists of a coherent Gaussian beam, a cascade of two moving diffusers and a single imaging lens. Dependence of the fluctuation speed of time-varying image speckles on the velocities of the diffusers is found to change with the size of illuminating speckles and the width of the point-spread function of the imaging lens. When the point-spread function and the focal position satisfy certain conditions, three kinds of velocity information—the velocity of each diffuser, the average velocity of the diffusers and the velocity difference between the diffusers—can be obtained by measuring a temporal correlation length of the time-varying speckle intensity. Experimental results confirm the theoretical predictions. 相似文献
9.
Hiro-aki Nishimoto Kiyoharu Nakagawa Na-oki Ikenaga Toshimitsu Suzuki 《Catalysis Letters》2002,82(3-4):161-167
Ru-loaded Y2O3 catalyst was investigated for the partial oxidation of methane to synthesis gas. Ru(0.5 wt%)/Y2O3 catalyst afforded a high CH4 conversion of 27% at a CH4:O2 ratio of 5 to give nearly a 1:2 ratio of CO and H2 with a selectivity of 75% at 873 K. Ru(0.5 wt%)/Y2O3 catalyst maintained high catalytic activity over 10 h in the partial oxidation of methane. Carbon deposition of the catalyst surface in the reaction of CH4 was examined by thermogravimetric analyses, and it was found that no carbon deposition occurred on the Ru(0.5 wt%)/Y2O3 catalyst. The synthesis-gas production proceeded basically via a two-step reaction consisting of methane combustion to give H2O and CO2, followed by the reforming of methane from CO2 and steam. 相似文献
10.
Hideki Shige Toshitsugu Ishikawa Michio Suzukawa Masato Nishiwaki Takeshi Yamashita Kei Nakajima Toshimitsu Ito Kenji Higashi Makoto Ayaori Atsushi Yonemura Paul Nestel Haruo Nakamura 《Lipids》1998,33(12):1169-1175
The effects of vitamin E on cholesteryl ester (CE) metabolism in 1774 cells were examined. Pretreatment of 1774 cells with
vitamin E at concentrations above 50 μM significantly decreased acetylated low density lipoprotein (LDL)-induced incorporation
of [14C]oleate into CF in cells in a dose-dependent manner. This was partly due to vitamin E Also significantly inhibiting the uptake
of [3H]CE-labeled acetylated LDL by 1774 cells. A trend existed toward suppression of acyl-CoA:cholesterol acyltransferase (ACAT)
activity in the cell lysate at high vitamin E concentration, but there was no effect on hydrolysis of CE. These data indicate
that vitamin E reduces the uptake of modified LDL and suppresses ACAT activity, resulting in less cholesterol esterification
in macrophages; a novel mechanism underlying the antiatherogenic properties of vitamin E. 相似文献