Structure and mechanical properties of polyethylene-fullerene composites

The microhardness of films of fullerene-polyethylene composites prepared by gelation from semidilute solution, using ultrahigh molecular weight polyethylene (PE) (6×10⁶), has been determined. The composite materials were characterized by optical microscopy and X-ray diffraction techniques. The microhardness of the films is shown to increase notably with the concentration of fullerene particles within the films. In addition, a substantial hardening of the composites is obtained after annealing the materials at high temperatures (T _a=130 °C) and long annealing times (t _a=10⁵s). The hardening of the composites with annealing temperature has been identified with the thickening of the PE crystalline lamellae. Comparison of X-ray scattering data and the microhardness values upon annealing leads to the conclusion of phase separation of C₆₀ molecules from the polyethylene crystals within the material. The temperature dependence is discussed in terms of the independent contribution of the PE matrix of the C₆₀ aggregates to the hardness value.     

Integrated Data Management for a Fleet of Search‐and‐rescue Robots

Search‐and‐rescue operations have recently been confronted with the introduction of robotic tools that assist the human search‐and‐rescue workers in their dangerous but life‐saving job of searching for human survivors after major catastrophes. However, the world of search and rescue is highly reliant on strict procedures for the transfer of messages, alarms, data, and command and control over the deployed assets. The introduction of robotic tools into this world causes an important structural change in this procedural toolchain. Moreover, the introduction of search‐and‐rescue robots acting as data gatherers could potentially lead to an information overload toward the human search‐and‐rescue workers, if the data acquired by these robotic tools are not managed in an intelligent way. With that in mind, we present in this paper an integrated data combination and data management architecture that is able to accommodate real‐time data gathered by a fleet of robotic vehicles on a crisis site, and we present and publish these data in a way that is easy to understand by end‐users. In the scope of this paper, a fleet of unmanned ground and aerial search‐and‐rescue vehicles is considered, developed within the scope of the European ICARUS project. As a first step toward the integrated data‐management methodology, the different robotic systems require an interoperable framework in order to pass data from one to another and toward the unified command and control station. As a second step, a data fusion methodology will be presented, combining the data acquired by the different heterogenic robotic systems. The computation needed for this process is done in a novel mobile data center and then (as a third step) published in a software as a service (SaaS) model. The SaaS model helps in providing access to robotic data over ubiquitous Ethernet connections. As a final step, we show how the presented data‐management architecture allows for reusing recorded exercises with real robots and rescue teams for training purposes and teaching search‐and‐rescue personnel how to handle the different robotic tools. The system was validated in two experiments. First, in the controlled environment of a military testing base, a fleet of unmanned ground and aerial vehicles was deployed in an earthquake‐response scenario. The data gathered by the different interoperable robotic systems were combined by a novel mobile data center and presented to the end‐user public. Second, an unmanned aerial system was deployed on an actual mission with an international relief team to help with the relief operations after major flooding in Bosnia in the spring of 2014. Due to the nature of the event (floods), no ground vehicles were deployed here, but all data acquired by the aerial system (mainly three‐dimensional maps) were stored in the ICARUS data center, where they were securely published for authorized personnel all over the world. This mission (which is, to our knowledge, the first recorded deployment of an unmanned aerial system by an official governmental international search‐and‐rescue team in another country) proved also the concept of the procedural integration of the ICARUS data management system into the existing procedural toolchain of the search and rescue workers, and this in an international context (deployment from Belgium to Bosnia). The feedback received from the search‐and‐rescue personnel on both validation exercises was highly positive, proving that the ICARUS data management system can efficiently increase the situational awareness of the search‐and‐rescue personnel.     

Formulation and characterisation of nanosuspension of herbal extracts for enhanced antiradical potential

Nanotechnology is a promising technique to increase the bioavailability of herbal medicines. This paper presents the nanosuspension approach for increasing the aqueous solubility and thereby bioactivity of important herbal extracts. Nanosuspensions of the seeds of three plants extract (Silybum marianum, Elettaria cardamomum and Coriandrum sativum) were prepared by using polyvinyl alcohol (1.5% w/v) as a stabiliser. Prepared nanoparticles were characterised by scanning electron microscope. Activity of nanosuspension formulation was assessed by using four in vitro antioxidant assays. S. marianum, E. cardamomum and C. sativum particle size was observed to fall in range of 446.1 ± 112.6, 456.63 ± 339.2 and 432.1 ± 172.8 nm, respectively, most of the particles were having spherical shape and smooth topology. These synthesised nanoparticles were found to be more effective against quenching free radical than their crude extracts and standards [butylated hydroxyl toluene and ascorbic acid]. C. sativum nanosuspension showed most free radical scavenging potential against 2,2-diphenyl-1-picrylhdrazyl (DPPH) and superoxide free radical scavenging assays (IC₅₀ 0.59 ± 0.01 and 0.81 ± 0.11 mg/ml). S. marianum nanosuspension was found to be most effective against DPPH radicals scavenging (IC₅₀ 0.34 ± 0.02 mg/ml). It was concluded that nanosuspension of herbal medicines potentiates the antioxidant potential.     

Conducting carbon/polymer composites as a catalyst support for proton exchange membrane fuel cells

Carbon/poly(3,4‐ethylene dioxythiophene) (C/PEDOT) composites are synthesized by in situ chemical oxidative polymerization of EDOT monomer on carbon black in order to decrease carbon corrosion that occurred in carbon‐supported catalysts used in proton exchange membrane fuel cell. The effects of different dopants including polystyrene sulfonic acid, p‐toluenesulfonic acid and camphorsulfonic acid with the addition of ethylene glycol or dimethyl sulfoxide on the properties of the composites are investigated. The synthesized composites are characterized by X‐ray diffraction, Fourier transform infrared spectroscopy, thermogravimetric analysis, surface area analysis and scanning electron microscope. Electrical conductivity is determined by using the four‐point probe technique. Electrochemical oxidation characteristics of the synthesized C/PEDOT composites are investigated by cyclic voltammetry by applying 1.2 V for 24 h. The composite prepared at 25 °C with p‐toluenesulfonic acid and ethylene glycol shows the best carbon corrosion resistance. Platinum‐supported catalyst by using this composite was prepared using microwave irradiation technique, and it was seen that the prepared catalyst did not significantly lose its hydrogen oxidation and oxygen reduction reaction activities after electrochemical oxidation. Copyright © 2013 John Wiley & Sons, Ltd.     

Polymerization of epoxides catalyzed by a mixed‐valent iron trifluoroacetate [Fe3O(O2CCF3)6(H2O)3]

The readily available mixed‐valent iron trifluoroacetate complex [Fe₂^IIIFe^II(µ₃‐O)(O₂CCF₃)₆(H₂O)₃] is an effective catalyst for the polymerization of epoxides. A very small amount of the catalyst (1.0–0.01 mol%) could initiate the polymerization of cyclohexene oxide, cyclopentene oxide and epichlorohydrin. Based on quantitative end‐group analysis by ¹⁹F NMR spectroscopy, a Lewis acid (LA^⊕) catalyzed anionic reaction mechanism is proposed. Copyright © 2012 Society of Chemical Industry     

A Novel Sprague-Dawley Rat Model Presents Improved NASH/NAFLD Symptoms with PEG Coated Vitexin Liposomes

Chronic liver disease (CLD) is a global threat to the human population, with manifestations resulting from alcohol-related liver disease (ALD) and non-alcohol fatty liver disease (NAFLD). NAFLD, if not treated, may progress to non-alcoholic steatohepatitis (NASH). Furthermore, inflammation leads to liver fibrosis, cirrhosis, and hepatocellular carcinoma. Vitexin, a natural flavonoid, has been recently reported for inhibiting NAFLD. It is a lipogenesis inhibitor and activates lipolysis and fatty acid oxidation. In addition, owing to its antioxidant properties, it appeared as a hepatoprotective candidate. However, it exhibits low bioavailability and low efficacy due to its hydrophobic nature. A novel rat model for liver cirrhosis was developed by CCL4/Urethane co-administration. Vitexin encapsulated liposomes were synthesized by the ‘thin-film hydration’ method. Polyethylene glycol (PEG) was coated on liposomes to enhance stability and stealth effect. The diseased rats were then treated with vitexin and PEGylated vitexin liposomes, administered intravenously and orally. Results ascertained the liposomal encapsulation of vitexin and subsequent PEG coating to be a substantial strategy for treating liver cirrhosis through oral drug delivery.     

Dark fermentative hydrogen production from sucrose and molasses

There are many factors affecting the dark fermentative hydrogen production. The interaction of these factors, that is, their combined effects, should be investigated for better design of the systems with stable and higher hydrogen yields. This study aimed to investigate the combined effects of initial substrate, pH, and biomass (or initial substrate to biomass) values on hydrogen production from sucrose and sugar‐beet molasses. Therefore, optimum initial chemical oxygen demand (COD), pH, and volatile suspended solids (VSS) or initial substrate to biomass (VSS) ratio (S/X_o) values leading to the highest dark fermentative hydrogen production were investigated in batch reactors. An experimental design approach (response surface methodology) was used. Results revealed that when sucrose was the substrate, maximum hydrogen production yield (HY) of 2.3 mol H₂/mol sucrose_added was obtained at initial pH of 7 and COD of 10 g/L. Initial S/X_o values studied (4–20 g COD/g VSS) had no effect on HY, while the initial pH was found as the parameter mostly affecting both HY and hydrogen production rate (HPR). When substrate was molasses, initial COD concentration was the only variable affecting HY and HPR. Maximum of both was achieved at 10 g/L initial COD. Initial VSS values studied (2.5–7.5 g/L) had no effect on HPR and HY. This study also indicated that molasses leads to homoacetogenesis for potentially containing intrinsic microorganism and/or natural constituents; thus, sucrose is more advantageous for hydrogen production via fermentation. Homoacetogenesis should be prevented for effective optimization via response surface methodology, if substrate is a natural carbon source potential to have intrinsic microorganisms. Copyright © 2017 John Wiley & Sons, Ltd.     

Size and expansion ratio analysis of micro nozzle gas flow

Size and expansion ratio effects on the flowfield are investigated for micro converging-diverging nozzles. Numerical computations are conducted by using two dimensional augmented Burnett equations and Navier-Stokes equations that were derived from the Boltzmann equation. The Maxwell-Smoluchowski slip boundary condition is used for adiabatic walls, and Steger-Warming flux vector splitting scheme is applied to the convective inviscid flux terms. The results from the augmented Burnett equation are compared with Navier-Stokes and Direct Simulation Monte Carlo (DSMC) results. Then, nozzle-size analysis is conducted for between 2 µm and 100 µm throat width. Influence of the Knudsen number is investigated, and temperature and Mach number variations are presented. In addition, the influence of the expansion ratio is studied with three (1.7:1, 3.4:1, and 6.8:1) different configurations. The results are compared with each other and an experimental data in the literature.