Surface wettability improvement of silicone elastomers synthesized with water‐soluble polyacrylic acid molds

The aim of this work was to evaluate the use of water‐soluble hydrophilic plastic molds for preparing siloxane based random copolymers and for enhancing the surface wettability of resultant polymers, with a view for contact lens manufacture. The random copolymer consisted of silicone monomers and a small amount of N‐vinyl‐2‐pyrrolidone (NVP) along with vinyl acetate and diethyleneglycoldiallylether as a crosslinker. The surface of this copolymer, which faced against a polyacrylic acid (PAA) mold, showed a higher degree of wettability compared to that obtained against a hydrophobic polypropylene (PP) mold. After heating at 80°C for 4 h, the surface of this copolymer became hydrophobic. When it was immersed in water, however, the high degree of surface wettability regained within 30 s, whereas no significant change in wettability was observed for the PP‐facing surface. The results obtained from X‐ray photoelectron spectroscopy indicated that the polar fraction, which is attributed to NVP fractions of the copolymer, concentrated at the vicinity of the PAA facing surface and, in consequence, improved the surface wettability. This surface also showed a dynamic rearrangement of the wettability in response to changes of the surrounding environment. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 3786–3789, 2003     

Syntheses and biodegradability of benzylated waste pulps and graft copolymers from PBzs and L‐lactic acid

Benzylated waste pulps (PBzs) were synthesized from treated waste pulp (Pulp), and benzyl chloride with phase transfer catalyst (PTC), and graft copolymers (PBz‐g‐LA) were synthesized from PBzs and L‐lactic acid (LA). Thermal properties, solubility, crystallinity, and biodegradability of the obtained PBzs and graft copolymers were investigated. PBzs with the degree of substitution (DS) higher than 1.5 showed T_g and T_m in DSC measurement. All PBz‐g‐LA exhibited no T_m. However, the graft copolymers obtained from lower DS PBzs having no T_g, exhibited T_g. The solubility of PBzs enhanced with increasing DS, and the crystallinity of PBzs reduced with increasing DS because of hydrophobicity and steric effect of benzyl groups. The solubility of graft copolymers was similar to that of original PBzs. Biodegradation tests for PBzs, Pulp, and graft copolymers were performed using cellulase in 0.1 M acetate buffer solution (pH 5.5) at 37°C. All samples showed biodegradability though the biodegradation rate decreased with increasing DS of PBz. In PBz‐g‐LA, the initial biodegradation rate was faster than that of original PBz because of hydrolysis of LA units. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 2658–2664, 2004     

Study on the mechanism of critical heat flux enhancement for subcooled flow boiling in a tube with internal twisted tape under nonuniform heating conditions

Critical heat flux (CHF) of subcooled flow boiling with water in a tube with an internal twisted tape under nonuniform heating conditions was experimentally investigated by direct current heating of a stainless steel tube. The boiling curve of the subcooled flow under a high heat flux was measured to confirm the characteristics of the nucleate boiling. The net vapor generation (NVG) point almost agreed with the Levy correlation. The increase of the CHF with an internal twisted tape under nonuniform heating conditions was explained by assuming an alternate development and disruption of the bubble boundary layer in which the bubble boundary layer is assumed to be disrupted when the heat flux is lower than the NVG heat flux. © 1997 Scripta Technica, Inc. Heat Trans Jpn Res, 25(5): 293–307, 1996     

Critical heat flux in subcooled flow boiling with water in a tube with axially nonuniform heating

Critical heat flux (CHF) in subcooled flow boiling under axially nonuniform heating conditions was experimentally investigated using a tube heated with a dc power source. The thickness of the tube wall in the axial direction was varied to attain axially nonuniform heating. The different thicknesses, therefore, separated the tube into regions of high heat flux and regions of low heat flux. The lengths of these regions of the tube were also varied to study the effect on the CHF. The objective of this system is to initiate boiling in the high-heat-flux region, thus increasing heat transfer, and to interrupt the bubble boundary layer in the low-heat-flux region. Because it is the initiation of boiling that increases heat transfer, the performance of such a system is linked to its effectiveness in repeatedly interrupting and re-establishing the bubble boundary layer. Our experiments, involving tubes that had sections of different thicknesses and different lengths, showed that when the heat flux in the low-heat-flux region was below the net vapor generation (NVG) heat flux, this system enhanced the CHF, but not when it was above the NVG. Also, for relatively short low-heat-flux regions, the CHF was not enhanced, presumably because there was insufficient time to interrupt the bubble boundary layer. © 1998 Scripta Technica, Heat Trans Jpn Res, 27(2): 169–178, 1998     

On the pressure drop and the velocity distribution in the cylindrical vortex chamber with two inlet pipes for the control of vortex flow

Vortex flow is applied to a cyclone dust collector, a vortex combustion chamber, and a vortex diode for vortex control. In order to apply the vortex flow to the industries, it is necessary to keep the stable flow condition and to estimate the response time of the transient flow process and also the intensity of the vortex flow. For control vortex flow, two types of vortex chamber with two inlet pipes were designed. One of them is to promote the vortex flow named as Co-Rotating Flow System and another one is to hinder the vortex flow named as Counter-Rotating Flow System. The pressure drops and the velocity distributions were measured for these vortex chambers. The estimation of the tangential velocity by the application of the angular momentum flux is compared with the measured velocity by a cylindrical Pitot-tube. The characteristics of the total pressure drop could be explained by introducing the circulation.     

Output variation of photovoltaic modules with environmental factors — II: seasonal variation

This study investigated how seasonal changes in cell temperature and spectral solar radiation effect the seasonal variation in photovoltaic (PV) module conversion efficieny for CdS–CdTe and two-layer tandem-amorphous silicon (for simplicity referred to as CdS and 2L A Si, respectively). First, using the measured data, the ratio of the spectral solar radiation available for solar cell utilization to the global solar radiation (denoted hereafter as “available spectral ratio”), the mean cell temperature, and the conversion efficiency for each month were obtained, and seasonal variations were analyzed. Mean cell temperature and available spectral ratio seasonal changes were found to be 9% for CdS and 16% for 2L A Si.The CdS conversion efficiency increased during summer by 7%, whereas 2L A Si exhibited a more substantial 14% variation. During summer, although the spectral ratio available to CdS increases, the conversion efficiency does not increase by the same amount, because of an increase in cell temperature. Similarly, although 2L A Si, experienced a much greater increase in available spectral ratio and had a better overall performance, there was still only a 2% variation, because of the cell temperature increases.If the basic characteristics of solar cell output for various types are compared with the variation in environmental factors, such as irradiance, cell temperature and spectral solar radiation, it is possible to calculate the precise output of a solar cell. Accordingly, it is possible to evaluate the seasonal variation in conversion efficiency for each solar cell type and utilize this information to optimize the PV power system.     

Therapeutic potential of hen egg white peptides for the treatment of intestinal inflammation

Inflammatory bowel disease (IBD) is a chronic and recurring inflammation of the gastrointestinal tract; however, current pharmaceutical treatments are only moderately effective and have potential long-term toxicity, therefore novel IBD therapies are required. Hen egg white has been shown to be an abundant source of novel immunomodulating proteins and peptides. The anti-inflammatory activity of egg white peptides was examined using a porcine model of dextran sodium sulphate (DSS)-induced colitis. DSS was administered for five days via intra-gastric catheter to induce experimental colitis, followed by five days of treatment with egg white peptides (EWP) or saline.Supplementation with EWP attenuated the DSS-induced clinical symptoms, including weight loss, mucosal and submucosal inflammation, crypt distortion, and colon muscle thickening, and restored gut barrier function by decreasing intestinal permeability and increasing mucin gene expression. Furthermore, treatment with EWP significantly reduced the local expression of pro-inflammatory cytokines TNF-α, IL-6, IL-1β, IFN-γ, IL-8, and IL-17, suggesting that EWP is a promising novel therapeutic for the treatment of IBD.