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1.
Zenan Yu Julian Moore Jean Calderon Lei Zhai Jayan Thomas 《Small (Weinheim an der Bergstrasse, Germany)》2015,11(39):5289-5295
Cable‐shaped supercapacitors (SCs) have recently aroused significant attention due to their attractive properties such as small size, lightweight, and bendability. Current cable‐shaped SCs have symmetric device configuration. However, if an asymmetric design is used in cable‐shaped supercapacitors, they would become more attractive due to broader cell operation voltages, which results in higher energy densities. Here, a novel coil‐type asymmetric supercapacitor electrical cable (CASEC) is reported with enhanced cell operation voltage and extraordinary mechanical‐electrochemical stability. The CASECs show excellent charge–discharge profiles, extraordinary rate capability (95.4%), high energy density (0.85 mWh cm−3), remarkable flexibility and bendability, and superior bending cycle stability (≈93.0% after 4000 cycles at different bending states). In addition, the CASECs not only exhibit the capability to store energy but also to transmit electricity simultaneously and independently. The integrated electrical conduction and storage capability of CASECS offer many potential applications in solar energy storage and electronic gadgets. 相似文献
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Asok Aparna A. S Sethulekshmi Jitha S. Jayan Appukuttan Saritha Kuruvilla Joseph 《大分子材料与工程》2021,306(11):2100429
Boron nitride (BN) is an eminent inorganic compound having many interesting characteristics such as improved oxidation resistance, mechanical strength, good thermal conductivity (TC), higher bandgap, high chemical stability, thermal stability, high hydrophobicity, and electrical insulation. The use of BN as a filler in polymers is a well-established strategy to tailor the properties of polymer composites. Recent studies depict an interesting urge to reap the synergistic effect of various nanofillers with BN in the form of hybrids. Hence the consolidation of the works on BN based hybrid fillers would definitely attract researchers so that these new filler systems could be transformed into useful polymer nanocomposites in future. This review article focuses on the synthesis and characterization of various boron nitride based hybrids in detail. Moreover, the review also throws light on different BN hybrid reinforced polymer nanocomposites (PNCs) and their thermal, electrical, electronic as well as biomedical applications in a detailed manner. Thus the review anticipates serving as a tool toward understanding the recent trends in the field of boron nitride hybrid based ternary polymer composites. 相似文献
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This paper proposes an accelerated iterative procedure for a nonlinear fourth order elliptic equation with nonlocal boundary conditions. First, an existence and uniqueness theorem is proved for the fourth order elliptic equation via the accelerated iterative procedure. To solve this problem numerically, a finite difference based numerical scheme is also developed in view of the main theorem. Theoretically, the monotone property as well as the convergence analysis are proved for both the continuous and discretized cases. The main result also supplements several algorithms for computing the solution of the fourth order elliptic integro-partial differential equation. The proposed scheme not only accelerates the scheme in the literature but also provides a greater flexibility in choosing the initial guess. The efficacy of the proposed scheme is demonstrated through a comparative numerical study with the recent literature. The numerical simulation confirms the theoretical claims too. 相似文献
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Aqueous sol–gel processing was used to synthesize neodymium-doped magnesium hexaaluminate (La1?x Nd x MgAl11O19; x = 0, 0.3, 0.4, 0.5) ceramic powder and subsequently calcined at 1450 and 1600 °C for 2 h. Randomly grown platelets of lanthanum–magnesium hexaaluminate formed a porous interlocking structure. Presence of various percentages of neodymium oxide significantly modifies the porous interlocking microstructure into self-reinforced, card-house-like microstructure. Platelets of rare earth-rich magnesium hexaaluminate were grown preferentially more than the stoichiometric rare earth magnesium hexaaluminate at elevated temperature greater than 1450 °C. Rare earth-rich magnesium hexaaluminate platelets form the skeleton of a card-house structure and the tiny platelets of stoichiometric rare earth magnesium hexaaluminate fill the house. The specific heat capacities, micro-hardness, and fracture toughness were studied in details. 相似文献
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The principle aim of the present study is to synthesis a novel mesoporous silica-based dual drug delivery system (DDDS) with unique features for the delivery of amoxicillin (antibiotic) and thiamine hydrochloride (vitamin). The DDDS was characterized by Fourier transform infrared, X ray diffraction, differential scanning calorimetry, scanning electron microscopy and atomic force micrographs analyses. The stimuli response behaviour of the drug carrier was studied by conducting swelling experiments as a function of pH and time. Drug release studies were carried out by mimicking gastric and intestinal conditions and found that the release of both drugs attained its maximum in the intestinal condition. The in vitro release data were analysed using Peppa’s potential equation in order to predict the release mechanism. The release of antibiotic follows non-Fickian mechanism whereas that of vitamin was diffusion controlled. An in vitro cytotoxicity analysis was carried out on L929 cells and the results showed that the synthesized DDDS is safe. DPPH assay and antibacterial activity were also analysed. From the investigation, it is evident that the prepared DDDS has potential application as dual drug carrier. 相似文献
6.
Jayan Ozhikandathil Andrew Morrison Muthukumaran Packirisamy Rolf W��thrich 《Microsystem Technologies》2011,17(3):373-380
Controlling precisely the depth in glass micro-drilling by spark assisted chemical engraving (SACE) remains challenging, particularly
for low depths. The possibility of using an electrically conductive material as an etch-stop layer for SACE gravity-feed drilling
is investigated in this paper. Micromachining with constant DC and pulsed DC of 30–35 μm thick SiO2 deposited on low resistive silicon substrate demonstrated the etch-stop function of the conductive silicon. Measurements
of etch rates and hole profiles along with scanning electron microscope imaging revealed the mechanism underlying the etch-stop
process. Low resistive silicon is demonstrated to be a good etch-stop layer for SACE gravity-feed drilling. Demonstration
of machining of SiO2 layer on silicon as a substrate and an etch-stop layer opens up new possibilities to adapt SACE for developing devices on
silicon platform. 相似文献
7.
Field Assessment of the Performance of a Ballasted Rail Track with and without Geosynthetics 总被引:1,自引:0,他引:1
Buddhima Indraratna Sanjay Nimbalkar David Christie Cholachat Rujikiatkamjorn Jayan Vinod 《Canadian Metallurgical Quarterly》2010,136(7):907-917
Understanding the complex mechanisms of stress transfer and strain accumulation in layers of track substructure under repeated wheel loading is essential to predict the desirable track maintenance cycle as well as the design of the new track. Various finite element and analytical techniques have been developed in the past to understand the behavior of composite track layers subjected to repeated wheel loads. The mechanical behavior of ballast is influenced by several factors, including the track confining pressure, type of aggregates, and the number of loading cycles. A field trial was conducted on an instrumented track at Bulli, New South Wales, Australia, with the specific aims of studying the benefits of a geocomposite installed at the ballast-capping interface, and to evaluate the performance of moderately graded recycled ballast in comparison to traditionally very uniform fresh ballast. It was found that recycled ballast can be effectively reused if reinforced with a geocomposite. It was also found that geocomposite can effectively reduce vertical and lateral strains of the ballast with obvious implications for improved track stability and reduced maintenance costs. 相似文献
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A method is reported for the growth of multiwall carbon nanotubes (MWCNTs) using polyacrylonitrile as a solid carbon source and nanosized SiO2 particles as catalyst. The nanotubes were grown either on a Si substrate or as a freestanding film at temperatures as low as 800 °C. The smallest measured inner diameter of the resultant MWCNTs is about 0.6 nm and therefore this method provides a new direction to prepare MWCNTs with very small inner diameter from solid carbon source. 相似文献