Equilibrium Studies of the System'(Fe,Co)O'–(Fe,Co)3O4 by Solid-State emf Measurements in the Temperature Range 970 to 1370 K

The equilibrium reaction 3'(Fe, Co)O'( ss ) +1/2O₂ ( g ) ⇄ (Fe, Co)₃O₄( ss ) was studied in the temperature range 970 to 1370 K for seven different total compositions of molar ratios 0.5 < Fe/(Fe + Co) ≤ 1.0. The equilibrium pressures of oxygen were determined by using galvanic cells incorporating calcia stabilized zirconia as solid electrolyte and the Fe/Co ratios in the solid-solution phases by wavelength dispersive spectrometry microprobe analyses. The activities of 'FeO' in the cobaltowüstite phase were then derived from the experimental results obtained.     

Roll force,torque, lever arm coefficient,and strain distribution in edge rolling

Due to the growing importance of width control in strip and plate mills, edge rolling is currently an im-portant process in hot rolling mills. Research in edge rolling has been carried out, and in the present ar-ticle, models for roll force, torque, and lever arm coefficient are derived using the upper bound method. A simple, kinematically admissible deformation zone and velocity field, independent of friction in the roll gap, is proposed, and the energy dissipation rate is derived. The formula for energy dissipation rate has, in practice, no limitation because all edge rolling geometries are safely in the area where the formula is valid. Roll force and torque are derived by means of two independent integrals. Thus, the lever arm coef-ficient is evaluated from the expressions for roll force and torque using conventional rolling theory. Roll-ing trials report good agreement with theory. Measured roll forces are similar to calculated forces. Furthermore, the shape of the dogbone that arises during edge rolling is in fairly good agreement with the calculated dogbone shape. Deviations are due to the deviation from ideally plastic material in the ex-periments. Also, the strain distribution over the dogbone is similar to the proposed deformation zone. Thus, a new formula has been developed to a stage that it can be implemented in width control systems for edge rolling stands in hot strip and plate mills.     

Photochemical oxidation of fatty acid esters with and without chlorophyll

1. It has been confirmed that the principal products formed in the oxidation of methyl oleate by oxygen under a variety of conditions are predominantlytrans hydroperoxides. However no inversion of the double bond occurs in unoxidized oleate. Hence the conversion ofcis totrans double bonds and peroxide formation occur together in the same molecules.
2. The autoxidation of methyl linoleate at low temperature yields predominantlycis,trans conjugated hydroperoxides. Autoxidation at 25°C., oxidation catalyzed by visible light, or ultraviolet light and copper soap catalyzed oxidation at temperatures appreciably above 0°C., lead to the formation primarily oftrans,trans conjugated hydroperoxides. The inversion of the second double bond in this case appears to be independent of the peroxide-forming reactions.
3. The photochlorophyll oxidation of methyl linoleate leads to the formation of some unconjugated hydroperoxides, some of which containtrans double bonds.
4. Under all of the conditions employed in the present investigation, the oxidation of methyl oleate and linoleate led primarily to the formation of monomeric peroxides which retained most of the unsaturation of the parent compound.

     

A case study of factor influencing role improvisation in crisis response teams

Common characteristics of crisis situations are ambiguous and unplanned for events. The need for improvised roles can therefore be an imperative factor for the success of an operation. The aim of this study is to deepen the understanding of the processes taking place during improvised work “as it happens”. A case study of a crisis management team at work is presented and provides an in-depth analysis of the information and communication flow of persons acting in improvised roles, including contextual factors influencing the task at hand. The analysis suggests that three main factors lay behind decreased performance by the team when some of its members were forced to take on roles for which they lacked professional training; lack of language skills, lack of domain knowledge and insufficient organizational structure of the tasks. Based on the observations from this case study, we suggest three ways of improving a team’s performance and hence resilience when forced to improvise due to lack of personnel in one or more required competence areas. These are training to take on the responsibility for tasks or roles outside ones professional area of specialization, developing formal routines for changes in roles and tasks and developing and using tools and routines for information sharing.     

A computational study of vortex-airfoil interaction using high-order finite difference methods

Simulations of the interaction between a vortex and a NACA0012 airfoil are performed with a stable, high-order accurate (in space and time), multi-block finite difference solver for the compressible Navier-Stokes equations.We begin by computing a benchmark test case to validate the code. Next, the flow with steady inflow conditions are computed on several different grids. The resolution of the boundary layer as well as the amount of the artificial dissipation is studied to establish the necessary resolution requirements. We propose an accuracy test based on the weak imposition of the boundary conditions that does not require a grid refinement.Finally, we compute the vortex-airfoil interaction and calculate the lift and drag coefficients. It is shown that the viscous terms add the effect of detailed small scale structures to the lift and drag coefficients.     

Ultrastructural evidence for an innervation of epithelial enterochromaffine cells in the guinea pig duodenum

The innervation of the duodenal enterochromaffine cells (E.C.) of the guinea pig was studied at the electronmicroscopic level. Pretreatment with 5-OH-dopamine was performed to visualize catecholaminergic (CA) nervous elements. Near the basement membrane of all examined E.C. in the crypts, bundles of unmyelinated nerve processes were observed, only partly ensheathed in a Schwann cell cover. At least 4 types of processes could be observed. 1) Boutons containing only small clear vesicles, probably cholinergic fibres; 2) boutons with small clear vesicles, and in addition large (greater than 200 nm) granules with a dense matrix (P-type-fibres); 3) boutons with small electron-dense vesicles, probably CA-fibres; and 4) processes with few vesicles but having the appearance of dendrites. No typical synaptic arrangements were observed, but the minimal distance between the E.C. and the nerve bundles was 150 to 250 nm, thus well within the functional limits of the "autonomic gap". Thus epithelial E.C. may be influenced by several types of nervous elements, including CA-fibres.     

Eliminating the effect of freezing frames on user perceptive by using a time interleaving technique

Streaming video over a wireless network faces several challenges such as high packet error rates, bandwidth variations, and delays, which could have negative effects on the video streaming and the viewer will perceive a frozen picture for certain durations due to loss of frames. In this study, we propose a Time Interleaving Robust Streaming (TIRS) technique to significantly reduce the frozen video problem and provide a satisfactory quality for the mobile viewer. This is done by reordering the streaming video frames as groups of even and odd frames. The objective of streaming the video in this way is to avoid the losses of a sequence of neighbouring frames in case of a long sequence interruption. We evaluate our approach by using a user panel and mean opinion score (MOS) measurements; where the users observe three levels of frame losses. The results show that our technique significantly improves the smoothness of the video on the mobile device in the presence of frame losses, while the transmitted data are only increased by almost 9% (due to reduced time locality).     

Treatment of log yard runoff in a couch grass infiltration wetland in Sweden

Sprinkling is often used in Scandinavia to protect round wood stored for industrial use from fungal and insect attack and drying cracks. Log yard runoff can be harmful for the water recipient due to eutrophication and oxygen depletion. A wetland system for treatment of log yard runoff is being evaluated in central Sweden. The purification capacity of a sloping couch grass (Elytrigia repens L.) field was examined when log yard runoff was applied to the field through a sprinkling system. Water samples were taken from groundwater pipes during four summer seasons (May to September, 2002–2005) and analysed for total organic carbon, total phosphorus (TP), total nitrogen and distillable phenols to evaluate the purification capacity of the infiltration wetland. Results from 2002 to 2004 were compared with results from 2005 when the irrigation intensity was considerably lower. Overall, the results showed good purification capacity although the concentrations of TP in the groundwater increased during 2005. The reduced hydraulic load did not increase purification.