Amination of biochar surface from watermelon peel for toxic chromium removal enhancement

Watermelon peel residues were used to produce a new biochar by dehydration method. The new biochar has undergone two methods of chemical modification and the effect of this chemical modification on its ability to adsorb Cr(VI) ions from aqueous solution has been investigated. Three biochars, Melon-B, Melon-BO-NH_2 and Melon-BO-TETA, were made from watermelon peel via dehydration with 50% sulfuric acid to give Melon-B followed by oxidation with ozone and amination using ammonium hydroxide to give Melon-BO-NH_2 or Triethylenetetramine(TETA) to give Melon-BO-TETA. The prepared biochars were characterized by BET, BJH,SEM, FT-IR, TGA, DSC and EDAX analyses. The highest removal percentage of Cr(VI) ions was 69% for Melon-B,98% for Melon-BO-NH_2 and 99% for Melon-BO-TETA biochars of 100 mg·L~(-1) Cr(VI) ions initial concentration and 1.0 g·L~(-1) adsorbents dose. The unmodified biochar(Melon-B) and modified biochars(Melon-BO-NH_2 and Melon-BO-TETA) had maximum adsorption capacities(Qm) of 72.46, 123.46, and 333.33 mg·g~(-1), respectively.The amination of biochar reduced the pore size of modified biochar, whereas the surface area was enhanced.The obtained data of isotherm models were tested using different error function equations. The Freundlich,Tempkin and Langmuir isotherm models were best fitted to the experimental data of Melon-B, Melon-BO-NH_2 and Melon-BO-TETA, respectively. The adsorption rate was primarily controlled by pseudo-second–order rate model. Conclusively, the functional groups interactions are important for adsorption mechanisms and expected to control the adsorption process. The adsorption for the Melon-B, Melon-BO-NH_2 and Melon-BO-TETA could be explained for acid–base interaction and hydrogen bonding interaction.     

一种氯磺化聚乙烯橡胶及其生产工艺

户外鞋底加工用轻质防滑型橡胶纤维复合材料     

一种用于建筑3D打印的橡胶粉超高延性砂浆及制备

正由同济大学申请的专利(公布号CN 111807790A,公布日期2020-10-23)"一种用于建筑3D打印的橡胶粉超高延性砂浆及制备",涉及的砂浆材料配方为:水泥400～800,硅灰100～200,粉煤灰400～800,砂80～400,胶粉20～120,减水剂1～4,水300～390,聚乙烯纤维10～20。与现有技术相比,本发明通过配方的优化设计,进一步提升了3D打印胶粉砂浆材料的超高延性和高耗能能力,从而实现无筋的建筑3D打印。     

Covalent triazine framework with efficient photocatalytic activity in aqueous and solid media

Covalent triazine frameworks (CTFs) have been recently employed for visible light-driven photocatalysis due to their unique optical and electronic properties. However, the usually highly hydrophobic nature of CTFs, which originates from their overall aromatic backbone, leads to limitations of CTFs for applications in aqueous media. In this study, we aim to extend the range of the application media of CTFs and design hybrid material of a CTF and mesoporous silica (SBA-15) for efficient photocatalysis in aqueous medium. A thiophene-containing CTF was directly synthesized in mesopores of SBA-15. Due to the high surface area and the added hydrophilic properties by silica, the hybrid material demonstrated excellent adsorption of organic molecules in water. This leads not only to high photocatalytic performance of the hybrid material for the degradation of organic dyes in water, but also for efficient photocatalysis in solvent-free and solid state. Furthermore, the reusability, stability and easy recovery of the hybrid material offers promising metal-free heterogeneous photocatalyst for broader applications in different reaction media.     

基于控制算法理论及网络图的计算机算法研究

随着科学技术的不断发展,计算机技术领域逐步普及,相关技术理论等已经渗透到我们工作、生活的方方面面,各行业发展势头迅猛.在计算机的算法研究领域中,将计算机的控制算法与网络图的计算机算法相互融合,共同协作发展,并可在控制算法上实现定性与定量的相关优势.本文以文献对比法和理论分析法,首先对计算机网络显示及控制算法的相关运行原理及作用机理进行研究,重点阐述了计算机网络显示的具体应用策略,并对在计算机网络显示与控制算法中存在的不足进行分析,针对性提出有关解决措施,供参考.     

High Power Fiber Bundle Array Coupled LDA Module

1 Introduction High power laser diode arrays (LDA) have many advan- tages such as small volume, long working life, high slope efficiency and high optical density, so they have many applications in medical treatment, material pro- cessing, and for the pumping source of solid laser and etc. But unfortunately, the LDA can not be easy to use directly in these fields because of their poor beam quality and extremely asymmetric divergent beams (!x≈ 5°～10°and !y≈20°～35°, for example), so it …     

High Temperature Property Development of Bauxite Based Bricks

Physical properties and microstructural evolution on firing of 3 types of bauxite based refractory bricks were carried out using techniques such as porosimetry,XRD and SEM.The groups differed from each other by progressive refining of the matrix or bond phase.It is revealed that such a refinement of the matrix can improve the high temperature properties of the bricks made from poor grade materials.     

河床变形对水电站动力设备工作条件的影响

水电站运行过程中河床变形会使河底高程逐渐降低。从而导致下游流量特性曲线下降以及水电站水头增大。水头增大使水电站气蚀特性发生变化，导致动力设备的正常工作条件受到破坏。并对其运行安全性和效率造成不利影响。以卡马河的沃特金水电站为例，阐述了河床变形对水电站动力设备工作条件的影响。