A strategy for the electro-organic synthesis of new hydrocaffeic acid derivatives

Electrochemical treatment processes can significantly contribute to the protection of the environment through the minimization of waste and toxic materials in effluents. From a pharmaceutical point of view and due to the existing resemblance between the electrochemical and biological reactions, it can be assumed that the oxidation mechanisms on the electrode and in the body share similar principles. In this paper, the application of electrochemical studies in the design of an environmentally friendly method was delineated for the new hydrocaffeic acid (HCA, 3,4-dihydroxy hydrocinnamic acid) derivatives synthesis at carbon electrodes in an undivided cell. In this cell, the EC mechanism reaction was involved, comprising two steps alternatively; (1) electrochemical oxidation and (2) chemical reaction. In particular, the electro-organic reactions of HCA, an important biological molecule, were studied in a water–acetonitrile (90:10 v/v) mixture in the presence of benzenesulfinic acid (3) and p-toluenesulfinic acid (4). The research included the use of a variety of experimental techniques, such as cyclic voltammetry, controlled-potential electrolysis and product spectroscopic identification.     

Generalized Gabor filters for palmprint recognition

Orientation-based coding approaches have recently been widely employed for face and palmprint recognition where generally, one starts with a set of Gabor filters to extract orientation information and then proceeds to code dominant orientations as features for each point of the palmprint. However, as the Gabor filter is developed to model two-dimensional receptive fields of simple cells in straits cortex, it might not be our best choice when dealing with curved and complex structures inherent in the palmprint texture. Motivated by this intuition, this paper shows that Gabor filters are a subset of a bigger family of filters which we refer to as generalized Gabor filter (GGF). Depending on the values of its parameters, a GGF takes a rather diverse shapes and orientations, which results in a potentially finer feature extraction capability. We show this improved capability by employing GGFs in the palmprint verification process. In applying our method, two different sub-banks of GGFs are defined for the orientation-based feature extraction of palmprints, and when compared with Gabor filters, it will be shown that GGFs have the upper hand in capturing orientation features. Furthermore, compared with the competitive code—one of the well-known orientation-based coding methods—the number of employed orientations is reduced to half. This would automatically compensate for a double usage of the filter banks, which otherwise could increase the time complexity of using GGFs. These ideas are further elaborated using a set of experiments on PolyU II and PolyU 2D/3D palmprint databases. The results show the preeminence of using GGFs both in terms of accuracy and efficiency.     

Preparation of the γ-Al2O3/PANI nanocomposite via enzymatic polymerization

Peroxidase-catalyzed template-guided polymerization of aniline in the presence of γ- alumina nanosheet (NS) particles have been carried out in aqueous media and γ-Al₂O₃/PANI nanocomposite was obtained. The polymerization of aniline occurred in aqueous solution in the presence of SPS (sulfonated polystyrene) as a template and SDS (sodium dodecyl sulfate) as a surfactant. Both obtained nanocomposites were comparable by SEM images. It was demonstrated that the γ-Al₂O₃ NS/PANI-SPS nanocomposite has higher conductivity and the γ-Al₂O₃ NS/PANI-SDS nanocomposite has higher void areas. The higher conductivity of γ-Al₂O₃ NS/PANI-SPS nanocomposite is attributed to the higher coated areas of γ-Al₂O₃ NS during polymerization in comparison with γ-Al₂O₃ NS/PANI-SDS which are not coated efficiently as the former. The FT-IR studies showed that the γ-Al₂O₃ NS/PANI nanocomposite was formed by interaction of the polyaniline (PANI) and γ-Al₂O₃ NS. FTIR also showed that the amount of PANI in γ-Al₂O₃ NS/PANI-SPS is more than in γ-Al₂O₃ NS/PANI-SDS. POLYM. COMPOS., 2009. © 2008 Society of Plastics Engineers     

Electrodeposition of nickel oxide nanoparticles on glassy carbon surfaces: application to the direct electron transfer of tyrosinase

This work describes the performance of a tyrosinase/nickel oxide nanoparticles/glassy carbon (Tyr/NiO NPs/GC) electrode. This electrode was prepared by first applying a NiO NPs electrochemical deposition onto the GC electrode surface and then tyrosinase immobilization was applied to the surface of electrodeposited NiO NPs. Scanning electron microscopy (SEM) and atomic force microscopy (AFM) procedures demonstrated the existence of different NiO NP geometrical structures. These geometrical structures could lead to better immobilization of proteins on their surfaces. The copper containing enzyme tyrosinase successfully achieved electrical contact with the electrode because of the unique structural alignment of tyrosinase enzyme on the nanometer-scale nickel oxide surfaces. This method could be suitable for application to nanofabricated devices facilitating better performance. It was concluded that tyrosinase can be effectively applied to nanometer-scale nickel oxide surfaces.     

Modeling Transient Evaporation from Descending Shallow Groundwater Table Based on Brooks–Corey Retention Function

In arid and semi-arid regions a large amount of rainfall and irrigation water that enters into the soil is lost through soil surface via evaporation. In such regions, there are some areas with shallow groundwater table, evaporating huge amounts of water and accumulating salts at the soil surface. Thus, the evaporation phenomenon not only is responsible for water loss but also is a major reason for soil salinization. The objective of this study was to develop and verify an analytical model for one dimensional transient unsaturated upward flow from water table to soil surface. Consequently, an analytical solution was developed based on the Richards equation with initial and boundary conditions governing evaporation phenomenon. The parametric Brooks and Corey retention function was used to describe water status in the vadose zone. Based on the proposed model, the saccumulative evaporation is estimated as function of water table drawdown and soil retention parameters. To collect the data required for model verification, nine large lysimeters were constructed and packed with sandy loam, silty clay loam, and silty clay soil textures. The results indicated reasonable agreements between the experimental data and those predicted with the proposed model. Although the overall predicted results were well resemble the real conditions, there were some underestimations for a certain period. This can be attributed to evaporation from side gap of columns, upward flow due to vapor phase movement of moisture, and the collapse of macropores resulting from soil packing.     

Concavity-orientation coding for palmprint recognition

Efficient feature extraction strategies play an important role in palmprint recognition systems. Among various feature extraction methods, orientation methods such as Competitive Code and Half Orientation Code are the baseline ones. They encode responses of a bank of orientational filters into a binary representation and can match a test palmprint sample in real-time with a relatively good accuracy. However, they use the orientation information based upon this idea that palmprints encompass only straight lines with different orientations, whereas in reality, the majority of palm’s lines are curved. This observation naturally brings the idea that the concavity and orientation features as different aspects of palmprints curves might provide more reliable and discriminative representations in palmprint recognition. Motivated by this idea, in this work we investigate the use of the concavity feature in different orientations for palmprint recognition. The experimental results, which are applied on PolyU II, 2D/3D PolyU, and blue and near infrared range images from Multispectral PolyU palmprint databases prove the efficiency of this idea compared to other coding-based methods.     

An Inverse Modeling Approach to Calibrate Parameters for a Drainage Model with Two Optimization Algorithms on Homogeneous/Heterogeneous Soil

Water Resources Management - Due to the time and spatial limitations of subsurface drainage pilots, simulation models have been extensively applied for evaluating these systems. Since the accuracy...     

A coding-guided holistic-based palmprint recognition approach

In the past few years, the need for accuracy and robustness against luminosity variations has drawn a considerable share of the palmprint research toward coding-based approaches. However, on the downside coding-based approaches require a high computational cost. On the contrary, while holistic-based palmprint recognition methods are easy to implement and have low computational burden, they usually do not result in a highly desirable accuracy. As a result, more recently hybridization of the holistic-based and coding-based methods has gained a boost. These hybridization schemes take advantages of both holistic and coding information to achieve a better performance. However, their computational burden due to incorporating the coding approach is still much heavier than the holistic methods. In this paper, we propose a new hybridization scheme based on Anisotropic Filter (AF) coding and the two-phase test sample representation (TPTSR) for the palmprint identification. In our scheme, the coding-based method is only applied on a super narrowed gallery in order to measure the classification confidence for a given test sample. Then, we apply our Guided Holistic (GH)-based method for classifying the test sample if the holistic-based algorithm is not sufficiently confident. Experimental results demonstrate the efficiency of our method in enhancing both the complexity cost and the accuracy of the results.     

Low-temperature ultrasound synthesis of nanocrystals CoTiO3 without a calcination step: Effect of ultrasonic waves on formation of the crystal growth mechanism

CoTiO₃ nanocrystallites with an average diameter of 50 nm were synthesized successfully by the sonochemical method without a calcination step and using C₁₀H₁₆N₂O₈ (EDTA) as the chelating agent. To reach an in-depth understanding of the scientific basis of the proposed process, an in-detail analysis was carried out for characterization of nanoscale CoTiO₃ particles via XRD, FTIR, FE-SEM and UV–vis diffuse reflectance spectroscopy (DRS). The crystallite size, average particle size and band gap are found to be 10.7 nm, in the range of 50 nm and 4.64 eV, respectively. The mechanism and the formation process of CoTiO₃ in the sonochemical process were proposed. It was found that nanocrystals were formed directly before being oriented and aggregated into large particles in aqueous solution under ultrasonic irradiation. The nucleation in the sonocrystallization process was accelerated by the implosive collapse of bubbles, while the crystal growth process was inhibited or delayed by shock waves and turbulent flow created by ultrasonic radiation. A pure complex perovskite phase of spherical shape was formed completely in a short irradiation time without the calcination process. Sonochemical irradiation could accelerate spherical shape formation of the particles significantly. These results provide new insights into the development and design of better nanomaterial synthesis methods.