Metallurgical parameters,mechanical properties and machinability of ductile cast iron

Results on the effect of solidification cooling rate on the microstructure, mechanical properties and machinability of spheroidal graphite (SG) iron have been presented. The effect of ferritic heat treatment on the same properties has been also investigated. The microstructural observation, tensile properties and hardness values of the present SG iron has been developed. The tool life criterion was used as a measure of machinability. It was found that during turning of SG iron by using a single point cutting tool, its life increased with decreasing the solidification cooling rate for both sand and metal moulds. The tool life was found to be significantly affected by the variation of nodule characteristics. A decrease in tool life due to an increase of nodule count was observed. The tool life was found to be directly proportional to the ductility of SG iron whether for the as cast or ferritic heat-treated ingots.     

Discrepancy search for the flexible job shop scheduling problem

The flexible job shop scheduling problem (FJSP) is a generalization of the classical job shop problem in which each operation must be processed on a given machine chosen among a finite subset of candidate machines. The aim is to find an allocation for each operation and to define the sequence of operations on each machine, so that the resulting schedule has a minimal completion time. We propose a variant of the climbing discrepancy search approach for solving this problem. We also present various neighborhood structures related to assignment and sequencing problems. We report the results of extensive computational experiments carried out on well-known benchmarks for flexible job shop scheduling. The results demonstrate that the proposed approach outperforms the best-known algorithms for the FJSP on some types of benchmarks and remains comparable with them on other ones.     

Automatic speech recognition system for Tunisian dialect

Although Modern Standard Arabic is taught in schools and used in written communication and TV/radio broadcasts, all informal communication is typically carried out in dialectal Arabic. In this work, we focus on the design of speech tools and resources required for the development of an Automatic Speech Recognition system for the Tunisian dialect. The development of such a system faces the challenges of the lack of annotated resources and tools, apart from the lack of standardization at all linguistic levels (phonological, morphological, syntactic and lexical) together with the mispronunciation dictionary needed for ASR development. In this paper, we present a historical overview of the Tunisian dialect and its linguistic characteristics. We also describe and evaluate our rule-based phonetic tool. Next, we go deeper into the details of Tunisian dialect corpus creation. This corpus is finally approved and used to build the first ASR system for Tunisian dialect with a Word Error Rate of 22.6%.     

Adsorptive removal of nitrate and phosphate anions from aqueous solutions using functionalised SBA‐15: Effects of the organic functional group

Adsorption of nitrate and monovalent phosphate anions from aqueous solutions on mono, di‐ and tri‐ammonium‐functionalised mesoporous SBA‐15 silica was investigated. The adsorbents were prepared via a post‐synthesis grafting method, using either 3‐aminopropyltrimethoxysilane (N‐silane) or [1‐(2‐aminoethyl)‐3‐aminopropyl]trimethoxysilane (NN‐silane) or 1‐[3‐(trimethoxysilyl)‐propyl]‐diethylenetriamine (NNN‐silane), followed by acidification in HCl solution to convert the attached surface amino groups to positively charged ammonium moieties. The nominal loading of amino moieties on the SBA‐15 surface was varied from 5% to 20% as organoalkoxysilane/silica molar ratio. The adsorption experiments were conducted batchwise at room temperature. Results showed that adsorption capacity increased with increasing the concentration of monoammonium groups on the SBA‐15 adsorbent. Nitrate adsorption capacity increased from 0.34 to 0.66 mmol ${\rm NO}_{3}^{{-} } /{\rm g}$ adsorbent while phosphate adsorption capacity increased from 0.34 to 0.63 mmol ${\rm H}_{2} {\rm PO}_{4}^{{-} } /{\rm g}$ adsorbent when the molar ratio organoalkoxysilane/silica was varied from 5% to 20%, respectively. Also, for the same organoalkoxysilane/silica molar ratio of 10%, the adsorption capacity increased with the increase of the number of protonated amines in the functional groups. Therefore, maximum adsorption capacities of 0.80, 1.16 and 1.38 mmol ${\rm NO}_{3}^{{-} } /{\rm g}$ adsorbent and 0.72, 0.82 and 1.17 mmol ${\rm H}_{2} {\rm PO}_{4}^{{-} } /{\rm g}$ adsorbent were obtained using mono‐, di‐ and triammonium functionalised SBA‐15 adsorbents, respectively. © 2011 Canadian Society for Chemical Engineering     

Fourier transform infrared-probed O(3P) microreactor: demonstration with ethylene reactions in argon matrix

To demonstrate the development of an oxygen atom microreactor in the form of liquid-helium-cooled solid argon matrix deposited on an infrared (IR) window, the oxidation of ethylene by mobile O atoms has been investigated. O atom diffusion through the argon matrix is confirmed and used to examine ethylene-oxygen atom reactions. In a bench-scale matrix isolation system probed with a Fourier transform infrared (FT-IR) spectrometer, matrices of solid Ar at 8-10 K doped with NO2 and ethylene have been prepared on a ZnSe window within an evacuated cryostat. The matrices have been photolyzed using 350-450 nm photons, and the reaction products resulting from the reaction of O(3P), one of the photolysis products of NO2, with ethylene have been identified using FT-IR and a Gaussian 98W simulation program. These products include oxirane, acetaldehyde, ethyl nitrite radical, and ketene. The temperature effect in the range of 10-30 K on the products formed has also been investigated. The reaction mechanisms are discussed and the viability of the solid Ar matrix being a low temperature microreactor to examine reaction mechanisms of mobile oxygen atoms is elaborated.     

Effect of Salt Stress on the Expression and Promoter Methylation of the Genes Encoding the Mitochondrial and Cytosolic Forms of Aconitase and Fumarase in Maize

The influence of salt stress on gene expression, promoter methylation, and enzymatic activity of the mitochondrial and cytosolic forms of aconitase and fumarase has been investigated in maize (Zea mays L.) seedlings. The incubation of maize seedlings in 150-mM NaCl solution resulted in a several-fold increase of the mitochondrial activities of aconitase and fumarase that peaked at 6 h of NaCl treatment, while the cytosolic activity of aconitase and fumarase decreased. This corresponded to the decrease in promoter methylation of the genes Aco1 and Fum1 encoding the mitochondrial forms of these enzymes and the increase in promoter methylation of the genes Aco2 and Fum2 encoding the cytosolic forms. The pattern of expression of the genes encoding the mitochondrial forms of aconitase and fumarase corresponded to the profile of the increase of the stress marker gene ZmCOI6.1. It is concluded that the mitochondrial and cytosolic forms of aconitase and fumarase are regulated via the epigenetic mechanism of promoter methylation of their genes in the opposite ways in response to salt stress. The role of the mitochondrial isoforms of aconitase and fumarase in the elevation of respiration under salt stress is discussed.     

A new methodology for the identification of ball bond degradation during high-temperature aging tests on devices in standard plastic packages

We describe a new methodology for the “in situ” identification of wire-bond degradation at early stages during high-temperature aging tests on devices with standard plastic packages. This methodology is based on the measurement of the changes in wire bond resistance, which is deduced from the I(V) characteristics of the ESD protection diodes on each contact pad of the circuit. In a first stage, the measurement procedure is described, with emphasis on the initial temperature calibration. This procedure allows for an “in situ” measurement sequence, where the packages stay in the aging chamber, at elevated temperature, during the electrical tests on the pad connections performed at different aging durations. By following accurately the package temperature, using a thermocouple, it is possible to correct for slight changes and thus get a reliable I–V measurement for each interconnection. In the second stage, the aging test results are described, showing the evolution of each individual interconnection. We were able to identify the onset of wire-bond degradation through the progressive increase of their resistance. To allow for better determination of the degradation process, once an increase in wire bond resistance was detected, complete I(V) curves were recorded at the pin(s) of interest. For each pin of a TQFP64 package, the tests were performed at least twice a day, with increased density when initial failure is detected (one complete measurement every 3 h). This strategy allowed for the detection of different behaviors on the wire bonds: good ball bonds (i.e. ball bonds with no change in their resistance), ball bond with intermittent opens (these ball bonds are in the process of degradation, and thermo-mechanical stresses induced in the resin by very small temperature changes are sufficient to open or close the circuits) and completely destroyed ball bonds, for which the resistance stays in an “high” level. This approach to wire-bond degradation in plastic packages is very powerful in terms of the number of interconnections which can be followed “in real time” and especially has the advantage, over other classical approaches, that the devices under test stay operational, contrary to what occurs with other types of destructive testing. These electrical test results are compared with metallographic investigations performed after a series of mechanical tests on the ball bonds (wire pull/ball shear tests) on a set of identical devices which undergone exactly the same High Temperature Storage (HTS) aging for 2000 h at 165 °C.