High‐quality colloidal silver nanoparticles (AgNP) were synthesised via a green approach by using hydroalcoholic extracts of Malva sylvestris. Silver nitrate was used as a substrate ion while the plant extract successfully played the role of reducing and stabilising agents. The synthesised nanoparticles were carefully characterised by using transmission electron microscopy, atomic‐force microscopy, energy dispersive X‐ray spectroscopy, Fourier transform infrared spectroscopy and UV–vis spectroscopy. The maximum absorption wavelengths of the colloidal solutions synthesised using 70 and 96% ethanol and 100% methanol, as extraction solvents, were 430, 485 and 504 nm, respectively. Interestingly, the size distribution of nanoparticles depended on the used solvent. The best particle size distribution belonged to the nanoparticles synthesised by 70% ethanol extract, which was 20–40 nm. The antibacterial activity of the synthesised nanoparticles was studied on Escherichia coli, Staphylococcus aureus and Streptococcus pyogenes using disk diffusion, minimum inhibitory concentrations and minimum bactericidal concentrations assays. The best antibacterial activity obtained for the AgNPs produced by using 96% ethanolic extract.Inspec keywords: silver, nanoparticles, nanofabrication, antibacterial activity, colloids, particle size, transmission electron microscopy, atomic force microscopy, X‐ray chemical analysis, Fourier transform spectra, infrared spectra, ultraviolet spectra, visible spectra, microorganisms, nanomedicine, biomedical materialsOther keywords: Green synthesis, flower extract, Malva sylvestris, antibacterial activity, high‐quality colloidal silver nanoparticles, hydroalcoholic extracts, plant extract, reducing agents, stabilising agents, transmission electron microscopy, atomic‐force microscopy, energy dispersive X‐ray spectroscopy, Fourier transform infrared spectroscopy, UV– vis spectroscopy, colloidal solutions, particle size distribution, Escherichia coli, Staphylococcus aureus, Streptococcus pyogenes, disk diffusion, minimum inhibitory concentrations, minimum bactericidal concentrations assays, ethanolic extract, size 430 nm, size 485 nm, size 504 nm, size 20 nm to 40 nm, Ag相似文献
This paper addresses a methodology to properly represent a road network in the geographic information system (GIS) for network analysis. Over the years, the real world has become too complex to model properly within a given information system, such as GIS. Ideally, when the real world is represented as accurately as possible, a GIS can answer a question in its virtual world that coincides with the exact answer in the real world. However, existing methods related to impedance modeling for each segment of a road network in a route planning analysis that includes only a distance or time variable do not give proper results. Hence, this study investigates how a road network can represent the real world in a GIS and offer route planning tools. To address this, first, additional realistic variables are taken into account. These include weather, sight-seeing information, road type, and so on. Second, to combine these variables, an impedance model (IM) using the analytical hierarchical process (AHP) method is proposed. Finally, all of the models are implemented and verified with a sensitivity analysis. The models were successfully implemented in this work. All of the paths of the route planning analysis were successfully matched with the drivers’ paths that would normally be chosen in reality. It is anticipated that the use of other techniques such as analytical network process (ANP) in addition to AHP would be useful to overcome the aforementioned problem. 相似文献
This article puts forward a new algorithm for voice conversion which not only removes the necessity of parallel corpus in the training phase but also resolves the issue of insufficiency of the target speaker’s corpus. The proposed approach is based on one of the new voice conversion models utilizing classical LPC analysis-synthesis model combined with GMM. Through this algorithm, the conversion functions among vowels and demi-syllables are derived. We assumed that these functions are rather the same for different speakers if their genders, accents, and languages are alike. Therefore, we will be able to produce the demi-syllables with just having access to few sentences from the target speaker and forming the GMM for one of his/her vowels. The results from the appraisal of the proposed method for voice conversion clarifies that this method has the ability to efficiently realize the speech features of the target speaker. It can also provide results comparable to the ones obtained through the parallel-corpus-based approaches. 相似文献
This paper presents a new model for networked control systems (NCSs) under transmission control protocol (TCP) as a multiple‐delay system by considering both sensor to controller and controller to actuator delays. An analytical TCP model has been considered for the network part, and an active queue management (AQM) controller is designed to regulate the desired queue length, which ensures holding the network induced delay and its variation within their lower bounds. The model is assumed to possess structured uncertainties due to the stochastic nature of the network. Robust stability and stabilization conditions are derived in terms of linear matrix inequalities (LMIs) by applying the Lyapunov‐Krasovskii stability criterion. Illustrative examples are presented and it has been shown that the proposed method will obtain less conservative results compared to the existing approaches in the literature. 相似文献
A novel poly(vinyl chloride)-based 2,3,5,6,8,9-hexahydro-1,4,7,10-benzotetra oxacyclododecine-12-carbaldehyde-12-(2,4-dinitrophenyl)hy (PBC) with sodium tetraphenyl borate (NaTPB) as an anion excluder, benzyl acetate (BA), acetophenon (AP) and o-nitrophenyloctyl ether (NPOE) as plasticizing solvent mediators was prepared and investigated as a beryllium selective sensor. The best performance was observed with the membrane having the PVC–NaTPB–NPOE–PBC composition 30%:3%:62%:5%, which worked well over a very wide concentration range (1.0×10−7 M to 1.0×10−1 M). The sensor exhibits a Nernstian slope of 29.9 mV per decade of Be2+ activity. The detection limit of the sensor is 7.0×10−8 M (630 ppt). The proposed electrode shows excellent discriminating ability toward Be2+ ion with regard to alkali, alkaline earth, transition and heavy metal ions. It was successfully applied to the determination of beryllium in a mineral sample. 相似文献
H.264/Advanced Video Coding (H.264/AVC) is one of the video compression standards that is 50% more efficient than previously introduced standards. Given that the H.264/AVC standard is considered and used in a variety of video applications, it is essential to provide a suitable solution for video encryption with good security, high encryption speed, and to prevent bitrate increases. In this paper, we propose a method selective encryption of H.264/AVC for the digital rights management (DRM) applications. In this method, discrete cosine transform (DCT) coefficients, which affect the texture and content of the H.264/AVC video during compression, are encrypted after the zigzag scanning and based on Context-Adaptive Binary Arithmetic Coding (CABAC). The experimental results and encryption efficiency analysis demonstrate that the proposed method with the format compliance has good security and high encryption speed and it can prevent the bitrate from rising and is thus usable in industrial and the DRM applications.
In this study, barium-doped lanthanum manganite, La0.8Ba0.2MnO3, was synthesized via a mechano-thermal route employing high energy ball milling and subsequent heat treatment. The structural evolution, morphology and thermal behaviour of the powders were evaluated using XRD, FESEM, and DTA/TGA, respectively. DTA/TGA results showed that the calcination temperature of the carbonates significantly decreased by increasing the milling time. The results revealed that single phase perovskite was formed at 900 °C in a milled sample for 2 h and this temperature decreased to 600 °C by increasing the milling time to 30 h. The mean crystallite size also decreased from 32 to 20 nm by increasing the milling time from 2 to 30 h. The reaction sequence of La0.8Ba0.2MnO3 formation via the mechano-thermal route is proposed using XRD and DTA/TGA results. FESEM micrographs showed that the mean particle size of the perovskite phase is increased slightly from 30 to 40 nm by increasing the heat treatment temperature from 600 to 900 °C. 相似文献
One of the main applications of time alignment is parallel corpus based voice conversion. In the literature, various methods such as dynamic time warping (DTW) and hidden Markov model have been suggested for time alignment of two speech signals. In this paper, we introduce some modifications to DTW in order to decrease the time alignment error. These modifications are refinement, which is done by exerting a threshold, normalization, and comparisons between the preceding and the following frames to make sound correspondence between two different parallel corpus-based speakers’ speeches. Evaluation of this approach which has been done on some corpus sentences indicates a significant improvement of time alignment. At least about 4% and in some cases 15% decrease of error in comparison with DTW has been achieved. 相似文献
Oil sludge is obtained from the contaminated site of Bahregan area in the Persian Gulf in Iran. Chemotaxis was used for the isolation of alkane-degrading bacteria from oil sludge and the alk genes were determined with specific primers. bac1 identified in Thalassospira was selected as a powerful strain for biodegradation of oil sludge. Biodegradation of oil sludge by bac1 in the presence of nanoparticles was investigated by GC-MS analysis. Synergistic effect of Fe2O3 and Fe3O4 nanoparticles on bacteria increases the biodegradation of oil sludge and produces cyclosiloxane compound which is used in the field of medicine; however, the Thalassospira reduced its toxicity in the environment. 相似文献
The crack nucleation behavior of rough surfaces in line contact is investigated by means of a thermodynamically based continuum damage mechanics technique. The deterministic approach is employed to investigate the effect of roughness on the surface tractions and contact stresses. In order to treat the effect of high stress gradients, a special averaging technique, proposed previously for the case of smooth surface, is adopted in this study. The predictions of the crack nucleation life are compared with the relevant experimental data in the literature and indicate the validity of the analysis. 相似文献