OXIDIZABLE COUPLING AGENTS: INTRODUCTION OF SURFACE FUNCTIONALITY

The synthesis and grafting to glass or quartz of alkylalkoxysilane coupling agents (RSi(OR') 3 ) that are susceptible/responsive to oxidation is described. Hydrosilylation of the inexpensive polyolefin squalene occurred efficiently once or twice with the silane HMe 2 SiOSiMe 2 (CH 2 ) 2 Si(OEt) 3 to give a silane coupling agent 3 that possesses several alkene groups. Once grafted to a silica surface Q-Sq using traditional means, the coupling agent was oxidized and further processed in several different ways. First, epoxidation using soluble peracids led to polyepoxides that could be further hydrolyzed to give polyalcohol surfaces Q-Sq-PAA-H 2 O . Alternatively, ozonolysis with gaseous O 3 led to the ozonides Q-Sq-O 3 , which could be decomposed to give either aldehyde/ketone Q-Sq-O 3 -redu , or ketone/carboxylic acid groups Q-Sq-O 3 -H 2 O 2 , respectively, bound to the surface. The aldehyde/ketone groups were characterized by condensation with dinitrophenylhydrazine to give the highly colored hydrazones Q-Sq-O 3 -redu-DNPH . These studies demonstrate the ready portability of organic chemistry to silica (or related) surfaces using judiciously chosen silane coupling agents and the possibility of controlling surface functionalization by postgrafting oxidation.     

Effect of pH and zeta potential of Pickering stabilizing magnetite nanoparticles on the features of magnetized polystyrene microspheres

Styrene as a monomer was emulsified in water using several magnetite nanoparticles concentration and pH values. Emulsified styrene drops were used as templates for polymerization, in presence of water soluble free radical initiator, and formation of composite particles. Styrene template drops stabilization was verified by light as well as scanning electron microscopy imaging, which ensured the participation of the particles in building up a mechanical barrier to stop oil drops coalescence. Furthermore, the produced polystyrene composites were strongly attracted to an external magnet. The difference in particles size as a function of pH was elucidated using zeta potential measurements, which indicated dominance of pH on the hydrophilicity of the particles and consequently the extent of emulsification, which in turn affected the size of the obtained microspheres. Under some circumstances, capsules were formed instead of particles. Thereby, it can be concluded that the magnetic microspheres are optimally formed at pH 2.3 independently of the magnetite content used.     

Material flow analysis and integration of watersheds and drain systems: II. Integration and solution strategies with application to ammonium management in Bahr El-Baqar drain system

The objective of this paper is to develop a systematic methodology for mass integration in drain systems and watersheds. Mass integration is a holistic approach to the tracking, transformation, and allocation of species and streams. The watershed and drain system is first discretized into reaches. The MFA model developed in part I of this work (Simulation and Application to Ammonium Management in Bahr El-Baqar Drain System) is used to describe the environmental phenomena that affect the fate and transport of targeted species and the operators that characterize the system inputs and outputs as they relate to the surroundings. Next, we develop an integration framework which encompasses sources, sinks, and interception technologies to aid in the development for nitrogen-management strategies. The simulation model was transformed into a synthesis model by introducing optimization variables and including models for the potential management strategies. The problem of minimizing negative environmental impact subject to technical, social, economic, and regulatory constraints was posed as a nonlinear optimization program whose solution identified and synthesized the most effective solution strategies. These mathematical models and management strategies were coded into a computer-aided tool using LINGO programming platform. The program can be readily modified to address a variety of cases. Tradeoffs and sensitivity analysis were established using the devised model. The devised framework was applied to an Egyptian drain system (Bahr El-Baqar) along with the outfall to Lake Manzala. The results of the case study provide solution strategies for nitrogen management along with their technical, economic, and environmental implications.     

Tribological Performance of UHMWPE/GNPs Nanocomposite Coatings for Solid Lubrication in Bearing Applications

Ultra-high molecular weight polyethylene (UHMWPE)/ graphene nanoplatelets (GNPs) nanocomposite coatings were developed to reduce friction and wear in the absence of liquid lubrication. UHMWPE nanocomposite powders with different loadings (0.25, 1, and 2 wt.%) of GNPs were prepared and electrostatic spraying technique was then used to deposit the nanocomposite powders on aluminum alloy to form a thin coating. Friction and wear tests were conducted on the coatings against a flat-end pin, made of hardened tool steel to determine the best loading of GNPs. That was further tested to investigate the effect of sliding speed and contact pressure on its tribological properties and to establish coating operating limits. Results showed that UHMWPE nanocomposite coating reinforced with 1 wt.% GNPs showed the best tribological performance. It reduced wear rate by about 51% as compared to the pristine UHMWPE coating. The coating sustained a maximum sliding speed of 1 m/s at a contact pressure of 4 MPa equivalent to a pressure and velocity (PV) value of 4 MPa.m/s.     

The path towards healthier societies,environments, and economies: a broader perspective for sustainable engineered nanomaterials

Clean Technologies and Environmental Policy - Economic value is no longer adequate by itself as a proxy for the value-added benefits (VAB) assumed to be generated by emerging technologies such as...     

Speech compression exploiting linear prediction coefficients codebook and hamming correction code algorithm

In this paper, a replacement algorithm for Linear Prediction Coefficients (LPC) along with Hamming Correction Code based Compressor (HCDC) algorithms are investigated for speech compression. We started with an CELP system with order 12 and with Discrete Cosine Transform (DCT) based residual excitation. Forty coefficients with transmission rate of 5.14 kbps were first used. For each frame of the testing signals we applied a multistage HCDC, we tested the compression performance for parities from 2 to 7, we were able to achieve compression only at parity 4. This rate reduction was made with no compromise in the original CELP signal quality since compression is lossless. The compression approach is based on constructing dynamic reflection coefficients codebook, this codebook is constructed and used simultaneously using a certain store/retrieve threshold. The initial linear prediction codec we used is excited by a discrete cosine transform (DCT) residual, the results were tested using the MOS and SSNR, we had acceptable ranges for the MOS (average 3.6), and small variations of the SSNR (±5 db).     

Content of antinutritional factors and HCl-extractability of minerals from white bean (Phaseolus vulgaris) cultivars: Influence of soaking and/or cooking

White bean seeds were subjected to soaking in distilled water for 1, 2 and 3 days. In order to perform complete processing, the seeds were cooked until soft. Effects of soaking and/or cooking of white bean seeds on antinutritional factors, mineral contents and HCl-extractability were studied. Phytic acid and polyphenol contents of all cultivars were reduced. Soaking alone and soaking, followed by cooking, reduced mineral contents of the cultivars, but HCl-extractability was significantly (P ? 0.01) improved to varying extents, depending on cultivar type. Soaking and/or cooking treatment was thus found to be an effective technique and caused further improvement in the availability of both major and trace minerals in white bean.     

Effect of chymotrypsin digestion followed by polysaccharide conjugation or transglutaminase treatment on functional properties of millet proteins

Millet protein was solubilized by chymotrypsin; the soluble protein was conjugated to galactomannan under controlled conditions (60 °C, 76% RH) or polymerised by transglutaminase (TGase). SDS–PAGE patterns showed that the conjugated and polymerised proteins had higher molecular mass bands above the stacking gel. SDS–PAGE patterns also indicated that the digest was conjugated to galactomannan and polymerised by TGase. The free amino groups (OD₃₄₀) of the conjugated and polymerised digest were greatly reduced. Although the chymotrypsin digest was considerably insoluble between pH 2.0 and 5.0, galactomannan conjugate was completely soluble at all levels of pH. TGase polymer was slightly insoluble at pH 4.0. Galactomannan conjugate resisted heat-induced aggregation, even after heating at 90 °C for 20 min, while TGase polymer resisted heat-induced aggregation up to 70 °C, after which its solubility started to decline. The emulsifying properties of the conjugate and the polymerized proteins were greatly improved, compared to the native and chymotrypsin digests.     

Material flow analysis and integration of watersheds and drainage systems: I. Simulation and application to ammonium management in Bahr El-Baqar drainage system

This paper is aimed at developing a systematic and generally applicable methodology for material flow analysis in drainage systems and watersheds. In particular, this research has focused on developing a mathematical framework and application for the management of nitrogenous species (primarily ammonium ions). Nitrogen compounds are among the most important species contributing to ecological cycles. Indeed, the environmental and biological aspects of water systems and their surrounding systems are highly impacted by nitrogen compounds as they contribute to the quality, nutrition, and toxicity of these systems. A material flow model was developed to deal primarily with the water phase while including pertinent information on the solid and air phases as they interface with the water medium. Both spatial and discrete temporal dimensions were included to account for nitrogen flow and transformation. The model includes the various environmental phenomena that influence the fate and transport of targeted species (e.g., volatilization, precipitation, sedimentation, uptake by biota, adsorption, chemical and biochemical reactions, etc.). Furthermore, the model includes material flow analysis operators (or transfer functions) that characterize the system inputs and outputs as they relate to the surroundings. The aforementioned material flow analysis tools were combined in a computer-aided modeling platform to provide a complete material flow analysis and yield useful insights on the transport and fate of targeted species. The simulation results shed light on the system performance. Actual data for an Egyptian drainage system (Bahr El-Baqar) along with the outfall to Lake Manzala were used to illustrate the usefulness and applicability of the developed model. Comparison with the measured data confirmed the validity and fidelity of the model.