Habitat quality–physicochemical water quality–littoral macroinvertebrate community nexus in Lugo Lake (Ethiopia): Priorities for sustainable water resources management

The integration of water quality characteristics with habplot-based habitat quality assessment score (HabQA) has received little attention in ecological quality assessment studies. This study investigated the macroinvertebrate community structure in relation with lake habitat quality and physicochemical water quality variables in Lugo Lake (Ethiopia). Twelve sampling sites (eight agricultural and four recreational) were included. The variation among macroinvertebrates data was significantly explained by HabQA score and soluble reactive phosphorus. The study revealed the greater importance of habitat quality characteristics in comparison with the other conventional physicochemical characteristics on macroinvertebrate community structure. We strongly recommend the use of HabQA system while studying macroinvertebrate community structure for a deeper understanding of the environmental functioning of tropical lakes. The results suggested the need to apply integrated and sustainable protection and management of the lake catchment (including wetlands) to enhance the ecological integrity and hence biodiversity of lakes.     

The geographic distribution of fluoride in surface and groundwater in Ethiopia with an emphasis on the Rift Valley

This paper analyzes the most extensive database on fluoride distribution in Ethiopia. Of the total 1438 water samples tested, 24.2% had fluoride concentrations above the 1.5 mg/l recommended optimum concentration recommended by WHO. Regionally, by far the highest fluoride levels were recorded in the Rift Valley, where 41.2% of all samples exceeded the 1.5 mg/l level. Only 1.0% of the samples from the central and northwestern highlands and 10.0% in the southeastern highlands exceeded 1.5 mg/l. Larger proportions of deep wells (50.0%) and hot springs (90.0%) than shallow wells (27.2%) and cold springs (12.6%) exceeded the 1.5 mg/l level. The highest fluoride concentrations were recorded for Rift Valley lakes Shala (264.0 mg/l) and Abijata (202.4 mg/l) and the lowest in Lake Tana, and rivers, wells and springs in the highlands. The fluoride concentrations of the Awash River, which originates in the highlands and flows through the Rift Valley, increase downstream, giving concern over the current diversion of high-fluoride water from Lake Beseka. Of the various flourosis prevention methods tried in Ethiopia, the treatment of surface water has been shown to be the most feasible and effective for towns and large commercial farms in the Rift Valley, although defluoridation methods should be considered for smaller rural communities.     

Ruthenium Nanoparticles on Cobalt‐Doped 1T′ Phase MoS2 Nanosheets for Overall Water Splitting

2D MoS₂ nanostructures have recently attracted considerable attention because of their outstanding electrocatalytic properties. The synthesis of unique Co–Ru–MoS₂ hybrid nanosheets with excellent catalytic activity toward overall water splitting in alkaline solution is reported. 1T′ phase MoS₂ nanosheets are doped homogeneously with Co atoms and decorated with Ru nanoparticles. The catalytic performance of hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) is characterized by low overpotentials of 52 and 308 mV at 10 mA cm^?2 and Tafel slopes of 55 and 50 mV decade^?1 in 1.0 m KOH, respectively. Analysis of X‐ray photoelectron and absorption spectra of the catalysts show that the MoS₂ well retained its metallic 1T′ phase, which guarantees good electrical conductivity during the reaction. The Gibbs free energy calculation for the reaction pathway in alkaline electrolyte confirms that the Ru nanoparticles on the Co‐doped MoS₂ greatly enhance the HER activity. Water adsorption and dissociation take place favorably on the Ru, and the doped Co further catalyzes HER by making the reaction intermediates more favorable. The high OER performance is attributed to the catalytically active RuO₂ nanoparticles that are produced via oxidation of Ru nanoparticles.     

Combining ability and heritability for vitamin C and total soluble solids in pepper (Capsicum annuum L.)

Twenty‐one F₁ hybrids and seven parental genotypes were used to assess combining ability and heritability for vitamin C and total soluble solids in pepper (Capsicum annuum L.). The mean squares for general (GCA) and specific (SCA) combining abilities were highly significant for the two traits, suggesting the importance of both additive and non‐additive gene effects. However, additive gene action was more important, as GCA estimates were much higher than SCA effects. Among the parental genotypes, ‘Mareko Shote’ and ‘PBC 142A’, and ‘PBC 142A’ were good general combiners for vitamin C and total soluble solids, respectively, and could be used to improve these traits in pepper breeding programmes for the accumulation of favourable genes. They also showed the highest per se performance (315.3 mg 100 g^?1 and 18.5 Brix, respectively) for the two quality traits. The narrow sense heritability estimate for vitamin C was relatively high (54.8%) indicating that the environment had a less pronounced effect on this trait. The heritability for total soluble solids was low (15%). Copyright © 2006 Society of Chemical Industry     

Superlattice of parahydrogen physisorbed on graphite surface

We examine the zero-temperature stability of 1/3- and 1/4-coverage superlattices and the liquid phase of parahydrogen physisorbed on graphite by calculating variational ground state energies. A general anisotropic hydrogen-substrate interaction that can be used for both para- and orthohydrogen is first derived by lattice summation. The single-hydrogen Schrödinger equation is solved. Potential parameters are chosen so that the eigenvalue spectrum can be fitted to experimental data. The eigenfunctions are used to form single-particle elements for the many-body wave function. For finite-coverage monolayers of adsorbed hydrogen, the trial wave function is chosen as a product of a properly symmetrized single-particle element and a Feenberg-Jastrow correlating factor. The energies of the liquid and superlattice phases are calculated within the same formalism. We find at 1/3 coverage a stable triangle superlattice. At 1/4 coverage, however, the submonolayer remains in the two-dimensional liquid phase.Work supported in part by National Science Foundation Grant DMR 80-08816.     

Environmental and economic prospects of biomaterials in the automotive industry

Clean Technologies and Environmental Policy - This study provides an overview of the application of biomaterials in automotive industries and their economic and environmental implications. It also...     

Late Health Effects of Partial Body Irradiation Injury in a Minipig Model Are Associated with Changes in Systemic and Cardiac IGF-1 Signaling

Clinical, epidemiological, and experimental evidence demonstrate non-cancer, cardiovascular, and endocrine effects of ionizing radiation exposure including growth hormone deficiency, obesity, metabolic syndrome, diabetes, and hyperinsulinemia. Insulin-like growth factor-1 (IGF-1) signaling perturbations are implicated in development of cardiovascular disease and metabolic syndrome. The minipig is an emerging model for studying radiation effects given its high analogy to human anatomy and physiology. Here we use a minipig model to study late health effects of radiation by exposing male Göttingen minipigs to 1.9–2.0 Gy X-rays (lower limb tibias spared). Animals were monitored for 120 days following irradiation and blood counts, body weight, heart rate, clinical chemistry parameters, and circulating biomarkers were assessed longitudinally. Collagen deposition, histolopathology, IGF-1 signaling, and mRNA sequencing were evaluated in tissues. Our findings indicate a single exposure induced histopathological changes, attenuated circulating IGF-1, and disrupted cardiac IGF-1 signaling. Electrolytes, lipid profiles, liver and kidney markers, and heart rate and rhythm were also affected. In the heart, collagen deposition was significantly increased and transforming growth factor beta-1 (TGF-beta-1) was induced following irradiation; collagen deposition and fibrosis were also observed in the kidney of irradiated animals. Our findings show Göttingen minipigs are a suitable large animal model to study long-term effects of radiation exposure and radiation-induced inhibition of IGF-1 signaling may play a role in development of late organ injuries.     

The changing face of the Ethiopian rift lakes and their environs: call of the time

The Ethiopian rift is characterized by many perennial rivers, and a chain of lakes that vary in size, and hydrological and hydrogeological settings. The water resources of the Rift lakes are one of the focal points for large‐scale development in Ethiopia over the last few decades. Some of the lakes and their influent rivers are used for irrigation, soda abstraction, fish farming and recreation, and also support a wide variety of endemic birds and wild animals. Ethiopia's major mechanized irrigation farms and commercial fishery are confined within the Rift region. A few of the lakes have shrunk in surface area because of excessive water abstractions, while others have expanded because of increased surface run‐off and groundwater inflows from percolated irrigation water. Excessive land degradation, deforestation and over‐irrigation have changed the hydrological setting of a few Rift lakes. Human activities, in combination with changes in climate and geology, have influenced the hydrological setting and the water quality of the lakes, with the salinity and major ion composition dramatically changed in some of them. This study tries to address the challenges associated with development of these surface‐water resources, focusing on environmental problems arising over the past few decades on three lakes (Abiyata, Beseka and Ziway) situated along the tectonically active Rift floor. The methods utilized in this study include field hydrological and hydrogeological mapping, supported by aerial photographs and satellite imagery interpretations, as well as hydrometeorological and hydrochemical data analysis, and catchment hydrological modeling. A converging‐evidence approach was adapted to reconstruct the temporal and spatial variations of the lake water levels and surface areas. The study results revealed that the major changes in the Rift Valley are related primarily to recent improper use of water from the large rivers draining the Rift Valley floor and the lake catchments, and from direct lake water abstractions aggravated intermittently by climatic and land use changes. These changes represent grave environmental consequences on the fragile Rift ecosystem that demands urgent intervention in the context of an integrated, basin‐wide water management approach. This study emphasizes lake water level changes and human influences on these changes. It also assesses human interactions and water quality changes, including land use changes and environmental repercussions on the lakes, as well as providing recommendations on how these issues should be addressed.