全文获取类型
收费全文 | 88536篇 |
免费 | 8865篇 |
国内免费 | 5212篇 |
专业分类
电工技术 | 6931篇 |
技术理论 | 4篇 |
综合类 | 7125篇 |
化学工业 | 12864篇 |
金属工艺 | 5089篇 |
机械仪表 | 6207篇 |
建筑科学 | 6773篇 |
矿业工程 | 2636篇 |
能源动力 | 2567篇 |
轻工业 | 7109篇 |
水利工程 | 2424篇 |
石油天然气 | 4609篇 |
武器工业 | 1035篇 |
无线电 | 10532篇 |
一般工业技术 | 8845篇 |
冶金工业 | 3368篇 |
原子能技术 | 1203篇 |
自动化技术 | 13292篇 |
出版年
2024年 | 318篇 |
2023年 | 1304篇 |
2022年 | 2697篇 |
2021年 | 3767篇 |
2020年 | 2857篇 |
2019年 | 2215篇 |
2018年 | 2572篇 |
2017年 | 2906篇 |
2016年 | 2637篇 |
2015年 | 3947篇 |
2014年 | 4956篇 |
2013年 | 5863篇 |
2012年 | 6868篇 |
2011年 | 7493篇 |
2010年 | 6770篇 |
2009年 | 6311篇 |
2008年 | 6501篇 |
2007年 | 6180篇 |
2006年 | 5520篇 |
2005年 | 4490篇 |
2004年 | 3144篇 |
2003年 | 2268篇 |
2002年 | 2087篇 |
2001年 | 1733篇 |
2000年 | 1552篇 |
1999年 | 1274篇 |
1998年 | 868篇 |
1997年 | 708篇 |
1996年 | 651篇 |
1995年 | 541篇 |
1994年 | 414篇 |
1993年 | 304篇 |
1992年 | 245篇 |
1991年 | 165篇 |
1990年 | 103篇 |
1989年 | 97篇 |
1988年 | 87篇 |
1987年 | 42篇 |
1986年 | 35篇 |
1985年 | 25篇 |
1984年 | 12篇 |
1983年 | 11篇 |
1982年 | 12篇 |
1981年 | 9篇 |
1980年 | 21篇 |
1979年 | 12篇 |
1977年 | 1篇 |
1974年 | 1篇 |
1959年 | 8篇 |
1951年 | 11篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
2.
Peiying Wang Juanli Zhao Yun Fan Wei Zhang Yuanyuan Cui Liangmiao Zhang Bin Liu Hongqiang Nian Yiran Li 《Ceramics International》2021,47(11):15023-15029
In this work, the composition-dependent point defect types and formation energies of RE2Hf2O7 (RE = La, Ce, Pr, Nd, Pm, Sm, Eu and Gd) as well as the oxygen diffusion behavior are systematically investigated by first-principles calculations. The possible defect reactions and dominant defect complexes under stoichiometric and non-stoichiometric conditions are revealed. It is found that O Frenkel pairs are the predominant defect in stoichiometric pyrochlore hafnates. Hf-RE cation anti-site defects, accompanied by RE vacancies and/or oxygen interstitials, are stable in the non-stoichiometric case of HfO2 excess. On the other hand, RE-Hf anti-site defects together with oxygen vacancies and/or RE interstitials are preferable in the case of RE2O3 excess. The energy barriers for the migration along the VO48f - VO48f pathway of pyrochlore hafnates were calculated to be between 0.81 eV and 0.89 eV. Based on these results, a defect engineering strategy is proposed and the pyrochlore hafnates investigated here are predicted to exhibit potential oxygen ionic conductivity. 相似文献
3.
Chenchen Zhou Jia Man Haibo Yu He Xia Luming Man Bin Qi Jianfeng Li 《Ceramics International》2021,47(8):10866-10872
Ceramic microparticles have great potentials in various fields such as materials engineering, biotechnology, microelectromechanical systems, etc. Morphology of the microparticle performs an important role on their application. To date, it remains difficult to find an effective and controllable way for fabricating nonspherical ceramic microparticles with 3D features. This work demonstrates a method that combines UV light lithography and single emulsion opaque-droplet-templated microfluidic molding to prepare the crescent-shaped ceramic microparticles. By tailoring the intensity of UV light and flow rate of fluid, the shapes of microparticles are accordingly tuned. Therefore, varieties of crescent-shaped microparticles and their variations have been fabricated. After sintering, the crescent-shaped alumina ceramic microparticles were obtained. Benefitting from the light absorption and scattering behavior of most ceramic nanoparticles, this system can serve as a general platform to produce crescent-shaped microparticles made from different materials, and hold great potentials for applications in microrobotics, structural materials in MEMS, and biotechnology. 相似文献
4.
Dong Liu Xia Ke Zhong-Ce Hu Yu-Guo Zheng 《Journal of Bioscience and Bioengineering》2021,131(5):518-524
5.
Tongling Xia Yue Qi Xilei Dai Jinyu Liu Can Xiao Ruoyu You Dayi Lai Junjie Liu Chun Chen 《Indoor air》2021,31(6):2020-2032
To evaluate the separate impacts on human health and establish effective control strategies, it is crucial to estimate the contribution of outdoor infiltration and indoor emission to indoor PM2.5 in buildings. This study used an algorithm to automatically estimate the long-term time-resolved indoor PM2.5 of outdoor and indoor origin in real apartments with natural ventilation. The inputs for the algorithm were only the time-resolved indoor/outdoor PM2.5 concentrations and occupants’ window actions, which were easily obtained from the low-cost sensors. This study first applied the algorithm in an apartment in Tianjin, China. The indoor/outdoor contribution to the gross indoor exposure and time-resolved infiltration factor were automatically estimated using the algorithm. The influence of outdoor PM2.5 data source and algorithm parameters on the estimated results was analyzed. The algorithm was then applied in four other apartments located in Chongqing, Shenyang, Xi'an, and Urumqi to further demonstrate its feasibility. The results provided indirect evidence, such as the plausible explanations for seasonal and spatial variation, to partially support the success of the algorithm used in real apartments. Through the analysis, this study also identified several further development directions to facilitate the practical applications of the algorithm, such as robust long-term outdoor PM2.5 monitoring using low-cost light-scattering sensors. 相似文献
6.
Dr. Yibin Zhang Dr. Shuai Xia Shulin Wan Tessa E. Steenwinkel Tara Vohs Prof. Rudy L. Luck Prof. Thomas Werner Prof. Haiying Liu 《Chembiochem : a European journal of chemical biology》2021,22(13):2282-2291
Abnormal levels of glutathione, a cellular antioxidant, can lead to a variety of diseases. We have constructed a near-infrared ratiometric fluorescent probe to detect glutathione concentrations in biological samples. The probe consists of a coumarin donor, which is connected through a disulfide-tethered linker to a rhodamine acceptor. Under the excitation of the coumarin donor at 405 nm, the probe shows weak visible fluorescence of the coumarin donor at 470 nm and strong near-infrared fluorescence of the rhodamine acceptor at 652 nm due to efficient Forster resonance energy transfer (FRET) from the donor to the acceptor. Glutathione breaks the disulfide bond through reduction, which results in a dramatic increase in coumarin fluorescence and a corresponding decrease in rhodamine fluorescence. The probe possesses excellent cell permeability, biocompatibility, and good ratiometric fluorescence responses to glutathione and cysteine with a self-calibration capability. The probe was utilized to ratiometrically visualize glutathione concentration alterations in HeLa cells and Drosophila melanogaster larvae. 相似文献
7.
8.
In this study, a kind of Ni-based superalloy specially designed for additive manufacturing (AM) was investigated. Thermo-Calc simulation and differential scanning calorimetry (DSC) analysis were used to determine phases and their transformation temperature. Experimental specimens were prepared by laser metal deposition (LMD) and traditional casting method. Microstructure, phase constitution and mechanical properties of the alloy were characterized by scanning electron microscopy (SEM), transmission scanning electron microscopy (TEM), X-ray diffraction (XRD) and tensile tests. The results show that this alloy contains two basic phases, γ/γ', in addition to these phases, at least two secondary phases may be present, such as MC carbides and Laves phases. Furthermore, the as-deposited alloy has finer dendrite, its mean primary dendrite arm space (PDAS) is about 30-45 μm, and the average size of γ' particles is 100-150 nm. However, the dendrite size of the as-cast alloy is much larger and its PDAS is 300-500 μm with secondary and even third dendrite arms. Correspondingly, the alloy displays different tensile behavior with different processing methods, and the as-deposited specimen shows better ultimate tensile stress (1,085.7±51.7 MPa), yield stress (697±19.5 MPa) and elongation (25.8%±2.2%) than that of the as-cast specimen. The differences in mechanical properties of the alloy are due to the different morphology and size of dendrites, γ', and Laves phase, and the segregation of elements, etc. Such important information would be helpful for alloy application as well as new alloy development. 相似文献
9.
Wenlong Song Shoujun Wang Yang Lu Xuan Zhang Zixiang Xia Kai Sun Guangming Xin 《Ceramics International》2021,47(9):12631-12640
To enhance the tribological performance of Si3N4/TiC ceramics, MoS2/PTFE composite coatings were deposited on the ceramic substrate through spraying method. The micrographs and basic properties of the MoS2/PTFE coated samples were investigated. Dry sliding friction experiments against WC/Co ball were performed with the coated ceramics and traditional ones. These results showed that the composite coatings could significantly reduce the friction coefficient of ceramics, and protect the substrate from adhesion wear. The primary tribological mechanisms of the coated ceramics were abrasive wear, coating spalling and delamination, and the tribological property was transited from slight wear to serious wear with the increase of load because of the lower surface hardness and shear strength. The possible mechanisms for the effects of MoS2/PTFE composite coatings on the friction performance of ceramics were discussed. 相似文献
10.
为了提升大型载货车、专用车用变速箱分离机构分离性能,满足大离合器盘分离需求,设计出一种分离机构.该机构通过机械原理实现放大输入端推力来满足离合器摩擦片分离.该分离机构结构简单、成本低廉,值得推广. 相似文献