炉外精炼过程中炉渣的有效控制

对连铸机浇铸之有前钢水的炉外处理技术，尤其是对炉渣的控制进行了研究，从而使钢的纯净度和连铸可浇性大大提高。     

雷达情报分析与应用课程的"三步三结合"教学模式

雷达情报分析与应用课程具有知识点多面广、理论性专、实践性强等特点.针对该课程的教学难点,提出了"三步三结合"教学模式,探讨了基于该教学模式的雷达情报分析与应用课程的教学设计,并进行了教学实践探索.教学实践结果表明,学员考核成绩有明显提升;该教学模式增加了教学内容的针对性和高阶性,缩短了课堂教学与岗位之间的距离,提高了实战化教学水平.这可为其他课程的教学改革提供参考.     

基于PCC-RBF网络的风电功率短期预测方法

风电功率预测对风电场安全平稳运行、电网调度具有重要意义。针对风电功率短期预测指标选择不合理、预测精确度偏低的问题,提出一种基于皮尔逊相关系数(PCC)和径向基函数(RBF)神经网络的风电功率短期预测方法。该方法利用PCC筛选出与风电功率密切相关的3个指标,即电流、温度、风速,然后以这3个指标作为预测模型的输入对风电功率进行RBF样本训练与短期预测。试验结果表明,所提的预测模型预测误差更小,预测精度更高,能够满足风电功率短期预测的要求,具有广泛的应用前景。     

模块化多电平变换器全桥型子模块优化均压控制方法

模块化多电平变换器(MMC)子模块(SM)的数量与直流侧电压成正比,当SM增加时,会导致MMC的开关损耗急剧增加,因此降低功率器件的开关频率一直是MMC的重要研究方向之一。采用最近电平逼近调制(NLM)方式,提出一种基于全桥型SM的改进均压排序法,旨在降低MMC中功率器件IGBT的开关频率,该方法实现相对简单,无需额外的控制器,且易于扩展。最后,通过在MATLAB/Simulink平台搭建了19个全桥SM的仿真模型,验证了该方法的有效性。验证了所提全桥型SM优化均压策略,可以有效避免IGBT不必要的反复投切,降低IGBT的开关损耗,同时对外部输出特性不会产生负面影响。     

改性石墨烯@聚苯胺/硅树脂复合涂层的制备及防腐蚀性能

先采用改进的Hummers法制备氧化石墨烯(GO),并使用N?(β?氨乙基)?γ?氨丙基三甲氧基硅烷(KH792)对其改性而得到改性石墨烯(KH792GO),再采用化学氧化法将苯胺直接聚合到KH792GO表面,制备出了分散性优异的改性石墨烯接枝聚苯胺(KH792GO@PANI).将KH792GO@PANI作为功能填料加入硅树脂(SiR)中并刷涂在Q235钢表面,得到KH792GO@PANI/SiR复合涂层.用傅里叶变换红外光谱(FTIR)和扫描电镜(SEM)表征了功能填料的结构和形貌,研究了功能填料对涂层疏水性能和腐蚀电化学行为的影响.结果显示:加入KH792GO@PANI的涂层表现出优异的防腐蚀性能,水接触角为105.63°,吸水率为2.65％.     

The Zinc-Sensing Receptor GPR39 in Physiology and as a Pharmacological Target

The G-protein coupled receptor GPR39 is abundantly expressed in various tissues and can be activated by changes in extracellular Zn²⁺ in physiological concentrations. Previously, genetically modified rodent models have been able to shed some light on the physiological functions of GPR39, and more recently the utilization of novel synthetic agonists has led to the unraveling of several new functions in the variety of tissues GPR39 is expressed. Indeed, GPR39 seems to be involved in many important metabolic and endocrine functions, but also to play a part in inflammation, cardiovascular diseases, saliva secretion, bone formation, male fertility, addictive and depression disorders and cancer. These new discoveries offer opportunities for the development of novel therapeutic approaches against many diseases where efficient therapeutics are still lacking. This review focuses on Zn²⁺ as an endogenous ligand as well as on the novel synthetic agonists of GPR39, placing special emphasis on the recently discovered physiological functions and discusses their pharmacological potential.     

含硫氰酸盐、硫化物固体废物中总氰化合物测定方法

实验建立了含硫氰酸盐、硫化物固体废物中总氰化合物的测定方法,采用硝酸银滴定法、异烟酸-吡唑啉酮分光光度法分别测定总氰化合物含量高、低的样品。通过条件实验优化了前处理方式、称样量和干扰去除方法。该方法测定结果的相对标准偏差为0.43%～1.33%,加入标准物质回收率为91.5%～101.5%,精密度和准确度良好,符合测定要求。     

Cooperative effect of crystallization temperature and NaF addition in the formation process and hydrothermal stability of MCM-48 mesoporous molecular sieve

The hydrothermal stability of MCM-48 was conveniently and effectively improved by increasing the crystallization temperature and directly adding NaF to the synthesis gel. The crystallization temperature varied from 373 K to 403 K. The influences of NaF addition, crystallization temperature and crystallization time on the formation process and hydrothermal stability of MCM-48 were systematically studied here to solve the problem of poor reproducibility. Results from XRD patterns indicated that the crystallization temperature and crystallization time were very critical factors for the improvement of the hydrothermal stability besides NaF addition. The formation process of MCM-48 was significantly accelerated and the pore structure ordering was also greatly improved by increasing the crystallization temperature and F⁻/Si ratio. A high hydrothermally stable MCM-48 mesoporous molecular sieve was obtained after being crystallized at 393 K for 36 h in the presence of NaF, which endured the hydrothermal treatment in boiling water at least for 4 days. However, only an amorphous product was obtained when the crystallization temperature was further increased to 403 K. Results from Si MAS NMR, N₂ adsorption isotherms, TEM, Raman spectra and XRD patterns manifested that the improved stability of MCM-48 was attributed to the high silicates condensation degree and the excellent pore structure ordering. The possible reason for the successful formation of hydrothermally stable MCM-48 sample by controlling the crystallization temperature, time and F⁻/Si ratio was explained here.     

Investigation of bio-ethanol steam reforming over cobalt-based catalysts

The catalytic performance of cobalt catalysts supported on γ-Al₂O₃, TiO₂, ZrO₂ were studied for bio-ethanol steam reforming (BESR) reaction. The supported catalysts (10 wt%Co) were prepared by impregnation and characterized through Thermogravimetric analysis (TGA), H₂ chemisorption, laser Raman Spectroscopy, Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS), and temperature-programmed reaction (TPRxn). The metallic cobalt sites were found to correlate with the BESR reaction activity. The reaction and H₂ chemisorption showed that ZrO₂ supported catalyst showed the best dispersion and best catalytic activity. Over the 10% Co/ZrO₂ catalyst, using a H₂O:EtOH:inert molar ratio of 10:1:75 and a GHSV = 5000 h⁻¹, 100% ethanol conversion and a yield of 5.5 mol H₂/mol EtOH were obtained at 550 °C and atmospheric pressure.     

汛限水位动态控制在石门水库主汛期调度中的应用研究

在汛限水位静态控制的运行方式下常导致水库汛期不敢蓄水,汛后库水位却常常达不到正常蓄水位,极大地限制了水库兴利效益,造成水资源浪费。以石门水库为例,针对其静态汛限水位运行的现状,分析该运行方式下对水库兴利效益的影响,提出采用汛限水位动态控制的方法来提高水资源利用率。实际调度中,结合石门水库天气、水文等预报信息,采用预蓄预泄方法,分析汛限水位动态控制的上下限,给出了动态控制的调度策略,并以"20110728"洪水对比了两种调度方式。结果表明:当预报降雨或洪水偏小时,可抬高汛限水位最高至617.5 m,拦蓄洪尾,有效增加水库的蓄水量;当预报降雨或洪水偏大时,可降低汛限水位最低至610.0 m,腾空库容,迎接洪水。