Conjugated polymers with polar side chains in bulk heterojunction solar cell devices

Two polymers with polar side chains, namely poly[2,7‐(9,9‐dioctylfluorene)‐alt‐5,5‐(5',8'‐di‐2‐thienyl‐(2',3'‐bis(3''‐(2‐(2‐methoxyethoxy)ethoxy)phenyl)quinoxaline))] ( P1 ) and poly[2,7‐(9,9‐bis(2‐(2‐methoxyethoxy)ethyl)fluorene)‐alt‐5,5‐(5',8'‐di‐2‐thienyl‐(2',3'‐bis(3''‐(2‐(2‐methoxyethoxy)‐ethoxy)phenyl)quinoxaline))] ( P2 ), were synthesized for solar cell application. A series of bulk heterojunction solar cells were systematically fabricated and characterized by varying the electron‐acceptor materials, processing solvents and thickness of the active layer. The results show that P1 , with a higher molecular weight and good film‐forming properties, performed better. The best device showed an open circuit voltage of 0.87 V, a short circuit current of 6.81 mA cm^?2 and a power conversion efficiency of 2.74% with 1:4 polymer:[6,6]‐phenyl‐C71‐butyric acid methyl ester (PCBM[70]) mixture using o‐dichlorobenzene (o‐DCB) as processing solvent. P2 on the other hand showed a poorer performance with chlorobenzene as processing solvent, but a much improved performance was obtained using o‐DCB instead. Thus, an open circuit voltage of 0.80 V, short circuit current of 6.21 mA cm^?2 and an overall power conversion efficiency of 2.22% were recorded for a polymer:PCBM[70] mixing ratio of 1:4. This is presumably due to the improvement of the morphology of the active layer using o‐DCB as processing solvent. © 2013 Society of Chemical Industry     

Annual vegetation burns across the northern savanna region of Ghana: period of occurrence, area burns, nutrient losses and emissions

This study has assessed the seasonal occurrence of annual vegetation fires and defined inter-seasonally burned area for the different vegetation cover types across Ghana and the northern region of Ghana using 10-year (2001?C2010) remote sensing data. These values were used with fire induced elemental losses to estimate greenhouse gas emissions and net plant nutrient loss due to gross bush fire nutrient transfers and annual atmospheric nutrient depositions. About 21, 68, 10 and 1?% of annual burns across the northern region of Ghana take place in the months of November, December, January and February respectively. As much as 68?±?4 thousand km² (25?C32?%) and 37?±?2.6 thousand km² (46?C60?%) of dry land are annually burned across Ghana and the northern region of Ghana respectively, with 53?C56?% of the total annual burns across the country taking place in the northern region. About 10,100?C28,400 Gg of C, comprising 215?C4,700 thousand Gg of CO₂ equivalent (CO₂, CH₄) potential global warming green house gases and 48?C324 thousand Gg of local pollutants (CO, NO_x) are estimated to be released annually through bush fire occurrence across Ghana. Net negative balance for P between fire-induced nutrient transfers and, annual wet and dry nutrient deposits is of concern given the high P-sorbing mineral content of the soils. The temporal loss of P suggest an input source than wet and dry atmospheric P depositions for the sustenance of the ecosystem or predict a long term threat to regional food production.     

Review of the natural conditions and anthropogenic threats to the Ethiopian Rift Valley rivers and lakes

This review article considers the lakes found within the Ethiopian Rift Valley system and the rivers draining from the highlands towards them. The Ethiopian Rift Valley system extends in a north‐east–south‐west direction, bisecting the Ethiopian highlands. They differ in sizes and hydrological and hydrogeological settings. The lakes support a variety of flora and fauna, mainly fishes, reptiles, birds and mammals. The lakes and their feeder rivers, however, are currently being subjected to more human use pressure than previously experienced, attributable mainly to water abstractions for irrigation, household water supply and industrial activities in the catchments. Soil erosion, primarily attributable to the lack of soil conservation practices on farm lands, overgrazing and deforestation, along with unregulated irrigation practices, are generating large quantities of silt reaching the lakes. Improper utilization of water and land resources in the catchments, along with population growth and climate change impacts, is escalating the threats to the health of the lake and river ecosystems. As a result, some of the lakes exhibited reduced water levels and increased salinity. This article reviews the major environmental changes happening to these lakes and their feeder rivers. Visits were made to the area to update previous information while also consolidating the trends of change in the aquatic systems and the watersheds attributed to intense development practices.     

Degradation of Lake Ziway,Ethiopia: A study of the environmental perceptions of school students

Lake Ziway in Ethiopia is a freshwater lake supporting multitude uses, including irrigation, fishing, water supply and recreation. However, the lake is being degraded primarily because of various land‐ and water‐use activities in its watershed. Recognizing these human impacts on the lake's water quality and quantity, the perceptions of school students were surveyed under the belief that the future of the lake is largely dependent on this younger generation. The goal of this study was to better understand how students actually recognize the extent to which various human activities impact the water quantity and quality of Lake Ziway. As major stakeholders in their communities, the perceptions of school students from four high schools regarding the changes to the lake over time were investigated. Students were contacted by purposive sampling, based on criteria of student academic performances, and their proximity to the lake. Their perceptions were studied on the basis of an interview survey. The majority of students indicated that high levels of human activities, especially water abstractions and water pollution, were the main lake impacts. Students believe there is a lack of sustainable utilization and protection of the lake. They suggested coordinated activities among all lake stakeholders in the participation and decision‐making process to properly manage the lake. Provision of awareness to both local administrations and local communities, concern for establishing an appropriate regulatory body and allocating a sufficient budget, and strict controls on flower farm practices in the lakeshore, also was considered to be of high priority as a means of conserving the sustainability of the lake. The result derived from this survey has important implications for facilitating improved school curricula, and for federal, regional and district level water resource management authorities, in setting priorities and developing policies for the sustainability of Lake Ziway.     

Direct LIGA service for prototyping: status report

Since the early 1990s a variety of applications ranging from precision metallic, ceramic, or polymeric parts to complex devices for micro-fluidic and micro-optic applications have been discussed with the assumption that LIGA can either make a significant contribution or is the sole technology able to make these products. The question today is, have individual LIGA groups or even the entire LIGA community achieved this goal? Despite major investments, a lot of hard work from many students and researchers, and some promising “prototypes”, a true mass product made by direct LIGA, i.e., using X-ray lithography and electroplating, has still not entered the market. This paper will briefly present the current status of direct-LIGA technology and discuss some examples of commercialization efforts as well as prospects for high-volume production.     

Coexistence of Superconductivity and Spin Density Wave (SDW) in Ferropnictide Ba<Subscript>1−<Emphasis Type="Italic">x</Emphasis></Subscript>K<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>Fe<Subscript>2</Subscript>As<Subscript>2</Subscript>

This work focuses on the theoretical investigation of the coexistence of superconductivity and spin density wave (SDW) in ferropnictide Ba_1?x K _x Fe₂As₂. By developing a model Hamiltonian for the system and by using quantum field theory Green’s function formalism, we have obtained mathematical expressions for superconducting transition temperature (T _C), spin density wave transition temperature (T _sdw), superconductivity order parameter (Δ_Sc), and spin density wave order parameter (Δ_sdw). By employing the experimental and theoretical values of the parameters in the obtained expressions, phase diagrams of superconducting transition temperature (T _C) versus superconducting order parameter (Δ_Sc) and spin density wave transition temperature (T _sdw), versus spin density wave order parameter (Δ_sdw) have been plotted. By combining the two phase diagrams, we have demonstrated the possible coexistence of superconductivity and spin density wave (SDW) in ferropnictide Ba_1?x K _x Fe₂As₂.     

Behaviour of well-mixed zones (WMZs) in an imperfectly mixed ventilated room

In this paper the behaviour of 3D well-mixed zones (WMZs) of temperature is studied using numerically generated data. A WMZ of temperature is a 3D zone of improved mixing whereby an acceptably low spatial temperature difference occurs. Here it was anticipated to set a criterion to define a WMZ that takes into account the comfort and health of building occupants. It was found that WMZs are irregular in shape and unpredictable in size in imperfectly mixed ventilated rooms. Furthermore airflow exchange between the considered WMZ and its surrounding was quantified. The results of the analysis show the potential of computational fluid dynamics (CFD) in quantifying the shape, size and volume of WMZs that may not be possible to perform using experimental methods because of the practical limitation of placing thousands of sensors inside a ventilated room.     

Experimental data set for validation of heat,air and moisture transport models of building envelopes

This paper reports experimental studies on heat, air and moisture (HAM) transfer through a full scale light weight building envelope wall under real atmospheric boundary conditions. The main objective of the article is to generate informative data so that it can be used for numerical validation of HAM models. The considered wall is a multilayered structure built up from outside to inside of external board, vented cavity, fibreboard sheathing, mineral wool between wooden studs and interior finishing. The global wall has a surface area of (1.80 × 2.68) m²; and is subdivided into three vertical parts. The parts differ from each other by the applied interior finishing. Between the different layers of each part and on the surfaces of the wall humidity, temperature and heat flux sensors are placed in a 3D matrix. At the outer surface of the wall, the applied sheathing is a bituminous wood board. In the board nine removable specimens are included. By regularly weighing the fibreboard samples, their moisture content could be quantified. Using data collected over a total time span of about two years, insight about the hygrothermal behaviour of the different envelope parts is obtained and at the same time a well-documented data set is generated that can be used for hygrothermal envelope model validation purposes.