Nanolayer CrAlN/TiSiN coating designed for tribological applications

With the goal to produce a hard and tough coating intended for tribological applications, CrAlN/TiSiN nanolayer coating was prepared by alternative deposition of CrAlN and TiSiN layers. In the first part of the article, a detailed study of phase composition, microstructure, and layer structure of CrAlN/TiSiN coating is presented. In the second part, its mechanical properties, fracture and tribological behavior are compared to the nanocomposite TiSiN coating. An industrial magnetron sputtering unit was used for coating deposition. X-ray photoelectron spectroscopy, energy dispersive X-ray spectroscopy, X-ray diffraction, scanning electron microscopy, and transmission electron microscopy were used for compositional and microstructural analysis. Mechanical properties and fracture behavior were studied by instrumented indentation and focused ion beam techniques. Tribological properties were evaluated by ball-on-disk test in a linear reciprocal mode. A complex layer structure was found in the nanolayer coating. The TiSiN layers were epitaxially stabilized inside the coating which led to formation of dislocations at interfaces, to introduction of disturbances in the coating growth, and as a result, to development of fine-grained columnar microstructure. Indentation load required for the onset of fracture was twice lower for the nanolayer CrAlN/TiSiN, compared to the nanocomposite TiSiN coating. This agrees very well with their mechanical properties, with H³/E² being twice higher for the TiSiN coating. However, the nanolayer coating experienced less severe damage, which had a strong impact on tribological behavior. A magnitude of order lower wear rate and four times lower steady state friction coefficient were found for the nanolayer coating.     

Evaluation of microbial toxins,trace elements and sensory properties of a high-theabrownins instant Pu-erh tea produced using Aspergillus tubingensis via submerged fermentation

Theabrownins (TB) are polymeric phenolic compounds associated with the multiple bioactivities of Pu-erh tea, a post-fermented Chinese dark tea. High-TB instant Pu-erh tea was produced via a novel submerged fermentation (SF) using Aspergillus tubingensis and compared with samples produced commercially via the conventional solid-state fermentation (SSF). Viable microorganisms and microbial toxins, especially aflatoxins B₁, G₁, B₂, G₂, cyclopiazonic acid, fumonisins B₁, B₂, B₃ and ochratoxin A, were below the detection limit in all samples. Fewer microbial metabolites were found in SF instant tea compared with the SSF teas. Based on an adult consuming 1 g of instant Pu-erh tea daily, the dietary intake of investigated elements was below the safe limits recommended by various authorities. Tasters viewed the instant tea infusions as very mild, smooth, mellow and full. This suggested that submerged fermentation using A. tubingensis offers a speedy and safe alternative to commercial production of instant Pu-erh tea.     

An adaptive method based on the improved LPA-ICI algorithm for MRI enhancement

Various diseases are diagnosed using medical imaging used for analysing internal anatomical structures. However, medical images are susceptible to noise introduced in both acquisition and transmission processes. We propose an adaptive data-driven image denoising algorithm based on an improvement of the intersection of confidence intervals (ICI), called relative ICI (RICI) algorithm. The 2D mask of the adaptive size and shape is calculated for each image pixel independently, and utilized in the design of the 2D local polynomial approximation (LPA) filters. Denoising performances, in terms of the PSNR, are compared to the original ICI-based method, as well as to the fixed sized filtering. The proposed adaptive RICI-based denoising outperformed the original ICI-based method by up to 1.32 dB, and the fixed size filtering by up to 6.48 dB. Furthermore, since the denoising of each image pixel is done locally and independently, the method is easy to parallelize.     

Production of stable amorphous form by means of spray drying

Spray drying is a very useful method for manufacturing of amorphous solid materials. This is mainly due to the possibility of fast solvent evaporation that leads to a rapid transformation of solution to a solid state. Besides evaporation kinetics, there are various process parameters that influence physical and chemical characteristics of such obtained material. The possibility of obtaining a stable amorphous structure of the active pharmaceutical ingredient in a spray dryer was examined. A solution of the hydrochloride crystalline structure of the active pharmaceutical ingredient in a mixture of water and acetonitrile was dried at different temperatures and flowrates of nitrogen used for atomization, as well as the flowrates of the solution. The influence of the process conditions on the properties of the product was analyzed. The final dried products were characterized and identified with a variety of analytical and physical methods. The results showed that a stable amorphous structure of the high purity active pharmaceutical ingredient is obtained, and that the optimal conditions of the process are defined. The amorphous structure is stable at temperatures below 200°C when it is transformed into a new crystal structure. Conditions of high relative air humidity lead to partial transformation.     

Influence of Whey Protein Addition and Feed Moisture Content on Chosen Physicochemical Properties of Directly Expanded Corn Extrudates

Production of extrudates from cereals is an often-used technological process in today’s world food industry. Extrudates from corn flour produced using the twin-screw extrusion process and enriched with whey protein concentrate represent high-quality source of proteins and fats. Whey protein concentrate (WPC) as a valuable source of proteins and minerals is one of the highest-quality components for possible extrudate enrichment. In this paper, the influence of various WPC addition and some extrusion process parameters such as feed moisture content ( Q_{\textH\text2 \textO} Q_{{{\text{H}}_{\text{2}} {\text{O}}}} ) on physicochemical properties of directly expanded corn flour extrudates manufactured in twin-screw co-rotating extruder was investigated. Whey protein concentrate was added in the following ratios 7.5%, 15% and 22.5% and water in 10.08, 12.18 and 14.28 L/h. Final composition of products is determined with measuring of protein, fat and water shares, water absorption index (WAI) and water solubility index (WSI). With added WPC and with increase of water volume flow, there was a significant rise in total protein, fat and water content in final products, as well as lowering of WSI and rising of WAI indexes. The statistical analysis of the obtained data shows that the lowest WSI and the highest WAI had samples with the largest share of WPC (22.5%) and water volume flow of 14.28 L/h. Colour is measured for each sample, and results were represented with hue angle (H), chroma (C) and lightness (L) values. Process parameters, WPC and Q_{\textH\text2 \textO} Q_{{{\text{H}}_{\text{2}} {\text{O}}}} influence the increase of saturation of C and lightness of L colour value, while H value stays unchanged. Mean value of H was 90.14 ± 1.06, which corresponds to dominance of yellow colour of samples.     

Modeling the energy potential of biomass – H2RES

Modeling biomass as a renewable energy source poses many challenges with respect to feedstock variability, which are difficult to account for. It is found that at the preliminary stages of energy planning, heating value and moisture content of the feedstock are the most important factors. In addition, the effects of harvesting, transportation and storage are found to be significant even though they are often overlooked. Using the gathered information a biomass module for energy planning is created and integrated to H₂RES, a renewable energy planning program. Using this excel based software, a case study for a wood processing factory is performed, using the waste wood as feedstock. Comparing various scenarios, it is concluded that using a combination of solid oxide fuel cells, solar panels and steam turbines can satisfy the factories energy requirements with excess sold to the grid.     

The effect of pulsating potential electrolysis on the porosity of metal deposits

Measurements of the porosity of nickel deposits on steel, obtained by pulsating potential electrolysis, have been performed. The porosity of the nickel deposits and the effective overpotentials have been determined as a function of frequency of pulsating potential for selected values of effective current densities. A qualitative discussion of the effect of pulsating potential on the porosity of metal deposits has been presented and the optimum electrolysis conditions have been established.Presented at the 19th meeting of the Serbian Chemical Society, Beograd, January 1975.     

Electrical properties and chemical compatibility of PZT thick film on Ni substrates

The characteristics of Pb(Zr,Ti)O₃(PZT) thick films that were printed and fired on Ni substrates were studied. The dielectric characteristics of samples sintered at 850°C on Ni substrates could not be measured due to the formation of a NiO layer at the Ni/PZT interface. The scanning electron microscope and energy dispersive X-ray analysis of cross-sections of the PZT thick films on Ni substrates, and of a mixture of PZT and NiO powders, fired at 850°C, did not indicate the formation of secondary phases. However, the transmission electron microscopy showed around 8% solid solubility of NiO in the PZT. A new structure with a prefired, Au thick-film layer was designed in order to prevent the diffusion of the NiO to the PZT layer during sintering. The dielectric properties of the PZT layers printed and fired on the Ni substrates with the prefired Au electrode were significantly better than those of the layers on the uncoated substrate, the dielectric losses decreased from 0.23 to 0.05.     

Variable neighborhood search algorithm for heterogeneous traveling repairmen problem with time windows

The focus of this paper is generalized traveling repairman problem (TRP), a special case of the well known and well studied traveling salesman problem (TSP). Because of its specific objective function, that minimizes the sum of overall time all clients wait for until the end of a service, TRP has great applicability potential in client oriented practical problems. Therefore it has been known in literature as traveling deliveryman problem, minimum latency problem and cumulative capacitated vehicle routing problem. However, most studies that have treated TRP related problems have implied that only one repairman is present in the system and/or that all clients are available for service at the beginning of the planning horizon. In this paper we consider a TRP with a heterogeneous fleet of repairmen serving a set of clients whose arrival times are distributed over a planning horizon, i.e. heterogeneous TRPTW (hetTRPTW). For the hetTRPTW we present a mixed integer linear programming model, and a heuristic algorithm based on a variable neighborhood search (VNS) framework. Additionally, we propose a reduction strategy for neighborhoods in the VNS algorithm and test efficiency of implemented algorithms on four benchmark sets of problem instances. Results show that proposed algorithms could be used in real systems for solving small and moderate problem instances.