Production of hydrogen over bimetallic Pt–Ni/δ-Al2O3: I. Indirect partial oxidation of propane

Indirect partial oxidation (IPOX) of propane was studied over bimetallic 0.2 wt.% Pt–15 wt.% Ni/δ-Al₂O₃ catalyst in the 623–743 K temperature range. The unreduced and reduced forms of the catalyst were characterized by ESEM–EDAX and X-ray diffraction (XRD). In the IPOX tests, the effects of steam to carbon ratio (S/C), carbon to oxygen ratio (C/O₂) and residence time (W/F (g_cat h/mol HC)) on the hydrogen production activity, selectivity and product distribution were studied in detail. The effect of temperature program applied (increasing from 623 to 743 K, ITP; decreasing from 743 to 623 K, DTP) during reaction was also tested. The results showed that the Pt–Ni bimetallic system has superior performance characteristics compared to the monometallic catalysts reported in literature. The reason is thought to be the utilization of the catalyst particles as micro heat exchangers during IPOX; the heat generated by Pt sites during exothermic total oxidation (TOX) being readily transferred through the catalyst particles acting as micro heat exchangers to the Ni sites, which promote endothermic steam reforming (SR). The optimal conditions were found as S/C = 3, C/O₂ = 2.70 and W/F = 0.51 g_cat h/mol HC for IPOX of propane on the basis of high hydrogen productivity and selectivity between 623 and 748 K for the experimental conditions tested. The thermo-neutral points obtained showed the sustainability of reaction in terms of energy.     

The effect of fibre orientation of the dry sliding wear of borsic-reinforced 2014 aluminium alloy

The effect of fibre orientation on the dry sliding wear of continuous B(SiC) fibre reinforced aluminium alloy composites was investigated using a pin-on-disc wear testing machine. The metal-matrix composites (MMC) samples were tested in the normal (N), parallel (P) and antiparallel (AP) orientations sliding against a steel counter disc at a fixed speed of 1 m s^–1 under loads of from 12 to 60 N.The results showed that for the matrix alloy and MMCs, the average wear increased linearly with load. Wear of the MMCs was insensitive to fibre content but for composites with fibre contents at or above the minimum of 16 vol% used for this work, the wear rate was about 18% of that of the unreinforced matrix. Fibre orientation had a minor effect on wear rate; the N orientation gave the lowest wear rate with the AP orientation slightly higher and the P orientation significantly higher.The average coefficients of friction of the MMCs in N and AP orientations decreased linearly with increased wear rate and non-linearly with increased load, but the P orientation was insensitive to either variable.It was concluded from these results and a metallographic examination that the mechanism of wear of MMCs was essentially oxidative wear of the matrix. The hard fibres modified this to slightly different degrees depending on their orientation relative to the wear surface and sliding direction.     

Thermodynamic analysis of solar photovoltaic cell systems

The thermodynamic characteristics of solar photovoltaic (PV) cells are investigated from a perspective based on exergy. A new efficiency is developed that is useful in studying PV performance and possible improvements. Exergy analysis is applied to a PV system and its components, and exergy flows, losses and efficiencies are evaluated. Energy efficiency is seen to vary between 7% and 12% during the day. In contrast, exergy efficiencies, which incorporate the second law of thermodynamics and account for solar irradiation exergy values, are lower for electricity generation using the considered PV system, ranging from 2% to 8%. Values of “fill factors” are determined for the system and observed to be similar to values of exergy efficiency.     

Oxidation behavior of single-crystal Al2O3-fiber-reinforced Ni3Al-based composites

A series of single-crystal Al₂O₃-fiber-reinforced Ni3Al-based intermetallic matrix composites were fabricated by pressure casting. The matrices employed were binary Ni₃Al, Ni₃Al-0.5 at. pct Cr, and Ni₃Al-0.34 at. pct Zr. The development of microstructure upon oxidation in air at either 1100 °C or 1200 °C was investigated by optical, scanning, and transmission electron microscopy. In air-oxidized binary Ni₃Al, some of the fibers were fully or partially covered with a layer of oxide. A weak fiber/matrix bond in this system, which led to fiber debonding during composite processing, is believed to be responsible for the ingress of O into the composite and oxidation of the matrix in the debonded regions at the fiber/matrix interface. Addition of Cr to Ni₃Al resulted in an almost threefold increase in fiber/matrix bond strength. No oxidation of the interface was observed. A thick layer of oxide was formed around all the fibers when the composite was thermally cycled prior to isothermal annealing. Addition of Zr to Ni₃Al resulted in the formation of a layer of ZrO₂ on the surface of the fibers during composite processing. The ZrO₂ layer provided a fast path for the diffusion of O, which led to the formation of a rootlike oxide structure around the fibers. The rootlike structure consisted of a network of Al₂O₃-covered ZrO₂.     

The IFR/DFR property of the forward recurrence-time distribution

When a failure or replacement process is modeled as a renewal process, the residual life of the unit in use at a given time is generally referred to as the forward recurrence time (RT). Distributional properties of this random variable are critically important in many applications. This paper investigates the extent to which the failure-rate function monotonicity of a life distribution is inherited by the forward RT distribution at time s of its renewal process. For DFR life distributions, the forward RT distribution is also DFR for every s⩾0. However, the corresponding property does not necessarily hold for IFR life distributions. The forward RT distribution is IFR in the limit as s→0 and as s→∞. For IFR Weibull life distributions, we demonstrate numerically that the forward RT distribution is IFR for small s. As s is increased, it alternates between being IFR and non-IFR in an interesting cyclical pattern, and remains IFR beyond a large enough s     

Film morphology and reaction rate for the CVD of tungsten by the WF6—SiH4 reaction

Journal of Electronic Materials - Low pressure chemical vapor deposition (LPCVD) of tungsten (W) by SiH4 reduction of WF6 on Si(100) surfaces was studied in a single-wafer, cold-wall reactor over a...     

3D Printing of Polyvinylidene Fluoride Based Piezoelectric Nanocomposites: An Overview

Recently, polyvinylidene fluoride (PVDF) based nanocomposites have attracted much attention for next-generation wearable applications such as promising piezoelectric energy harvesters (nanogenerators), energy storage devices, sensing devices, and biomedical devices due to their high flexibility, and high dielectric and piezoelectric properties. 3D printing technology, PVDF based piezoelectric nanocomposites, the studies based on 3D printing of PVDF based piezoelectric nanocomposites by inkjet printing and fused deposition modeling, and enhancements of energy harvesting and storage performance of nanocomposites by structural design are comprehensively overviewed here. An insight is provided into 3D printing techniques, structure and properties of PVDF based polymers, various nanofillers and production methods for nanocomposites, solutions to enhance β phase (crystallinity) of PVDF, and improvements of nanocomposites’ breakdown strength, discharged energy density, and piezoelectric power output by mentoring structural design.     

Use of ultrasonic energy in reactive dyeing of cellulosic fabrics

The use of ultrasonic energy in dyeing cotton fabrics with monochlorotriazine and vinylsulphone reactive dyes has been studied spectrophotometrically. The dyeings carried out conventionally and by the use of ultrasonic techniques were compared in terms of percentage exhaustion, total amount of dye transferred to the washing bath after dyeing, fastness properties and colour values of the dyed materials. Overall results have shown that the use of ultrasound in reactive dyeing of cellulosic fabrics can result in energy savings, less water consumption, increased depth of colour and better process conditions.     

Salt and pepper noise filtering with fuzzy-cellular automata

A new image denoising algorithm is proposed to restore digital images corrupted by impulse noise. It is based on two dimensional cellular automata (CA) with the help of fuzzy logic theory. The algorithm describes a local fuzzy transition rule which gives a membership value to the corrupted pixel neighborhood and assigns next state value as a central pixel value. The proposed method removes the noise effectively even at noise level as high as 90%. Extensive simulations show that the proposed algorithm provides better performance than many of the existing filters in terms of noise suppression and detail preservation. Also, qualitative and quantitative measures of the image produce better results on different images compared with the other algorithms.