Inactivation of Fusarium oxysporum Conidia in Soil with Gaseous Ozone – Preliminary Studies

ABSTRACT

In this study, the efficiency of gaseous ozone (O₃) injected in the soil as an oxidizing agent for the inactivation of F. oxysporum was evaluated under laboratory conditions. The results show the treatment reached an inactivation efficiency of 76% after an applied dose of 0.40 g O₃ kg ^?1 soil. This shows that the injection of O₃ can be a viable alternative to control pathogenic organisms in the soils. Nevertheless, it is clear that more studies on determining the effects of this treatment on soil quality are needed.     

Bending impact on the performance of a flexible Li4Ti5O12-based all-solid-state thin-film battery

The growing demand of flexible electronic devices is increasing the requirements of their power sources. The effect of bending in thin-film batteries is still not well understood. Here, we successfully developed a high active area flexible all-solid-state battery as a model system that consists of thin-film layers of Li₄Ti₅O₁₂, LiPON, and Lithium deposited on a novel flexible ceramic substrate. A systematic study on the bending state and performance of the battery is presented. The battery withstands bending radii of at least 14 mm achieving 70% of the theoretical capacity. Here, we reveal that convex bending has a positive effect on battery capacity showing an average increase of 5.5%, whereas concave bending decreases the capacity by 4% in contrast with recent studies. We show that the change in capacity upon bending may well be associated to the Li-ion diffusion kinetic change through the electrode when different external forces are applied. Finally, an encapsulation scheme is presented allowing sufficient bending of the device and operation for at least 500 cycles in air. The results are meant to improve the understanding of the phenomena present in thin-film batteries while undergoing bending rather than showing improvements in battery performance and lifetime.     

Stability properties of a higher order scheme for a GKdV-4 equation modelling surface water waves

This work is devoted to the study of a higher order numerical scheme for the critical generalized Korteweg-de Vries equation (GKdV with p=4) in a bounded domain. The KdV equation and some of its generalizations as the GKdV type equations appear in Physics, for example in the study of waves on shallow water. Based on the analysis of stability of the first order scheme introduced by Pazoto et al. (Numer. Math. 116:317–356, 2010), we add a vanishing numerical viscosity term to a semi-discrete scheme so as to preserve similar properties of stability, and thus able to prove the convergence in L ⁴-strong. The semi-discretization of the spatial structure via central finite difference method yields a stiff system of ODE. Hence, for the temporal discretization, we resort to the two-stage implicit Runge-Kutta scheme of the Gauss-Legendre type. The resulting system is unconditionally stable and possesses favorable nonlinear properties. On the other hand, despite the formation of blow up for the critical case of GKdV, it is known that a localized damping term added to the GKdV-4 equation leads to the exponential decay of the energy for small enough initial conditions, which is interesting from the standpoint of the Control Theory. Then, combining the result of convergence in L ⁴-strong with discrete multipliers and a contradiction argument, we show that the presence of the vanishing numerical viscosity term allows the uniform (with respect to the mesh size) exponential decay of the total energy associated to the semi-discrete scheme of higher-order in space with the localized damping term. Numerical experiments are provided to illustrate the performance of the method and to confirm the theoretical results.     

Physical Reasoning to Synchronize Electrical Signals and Related Diagnostics in Plasma Focus Devices

Plasma Focus (PF) devices as well as other similar pulsed discharge devices requires a variety of diagnostics for their proper control and optimization, including the voltage between electrodes, the time derivative of the discharge current, detection of X-rays and neutron emissions, and pulsed laser images (Shadow, Schlieren, interferograms). This article discusses the problem of the time reference of all these outputs and proposes specific techniques for synchronizing them based on sound physical grounds. The foundations of synchronization criterion are verified in several experiments on PF devices.     

Highly active Cu-ZnO catalysts for the WGS reaction at medium–high space velocities: Effect of the support composition

Cu-ZnO based catalysts are the benchmark materials for the low-temperature WGS reaction. However, they present a crucial drawback which limits their application in portable devices: they only work under very low space velocities. In this study, we have developed a series of multicomponent Cu-ZnO catalysts able to work at relatively high space velocities with outstanding activity and stability. Different reference supports have been utilised with CeO₂-Al₂O₃ being the most promising system. Overall, this work describes a strategy to design advanced Cu-based catalysts that can overcome the residence time restrictions in the WGS reaction.     

An integrated project of entrepreneurship and innovation in engineering education

This paper presents a new line of project based learning in the School of Engineering of University of Minho: the Innovation and Entrepreneurship Integrated Project (IEIP). Four groups, each one composed of students from different engineering integrated master courses – Mechanical, Industrial Electronics and Computers, Polymer, Industrial Management – compete against each other in developing or improving commercial products manufactured by actual industries. There have been so far five editions of the IEIP, with five different companies and five diverse products, however, all these products included components that required knowledge from all the engineering courses involved. Only with the cooperation between the students of the various courses that compose each multidisciplinary team, the success is attainable. As each student has to deal with various engineering scopes, students’ technical skills are greatly enlarged and they acquire a multidisciplinary knowledge that was not possible in another way. Their soft skills like project management, teamwork, communication ability and personal development, which are valuable requisites for their future employers, are also improved. The participating industries also take advantage of the project: the groups competing against each other act as a multiskilled work force, actually making proposals capable of improving their products, their efficiency, and reducing costs.     

Iterative Heuristic Response Surface Method for Transmission Expansion Planning

Transmission expansion planning has become a central challenge in the design of competitive electricity markets. The underlying optimization/decision problem exhibits a high level of complexity, being nonconvex, dynamic, and nonlinear, with multiple objective functions and a wide range of uncertainties. In this paper we propose a methodology for handling the expansion problem that involves a novel adaptation of an iterative optimization method based on response surface models already used successfully in the design and manufacture of integrated circuits. It is implemented in a distributed environment using Web services, and is validated and compared with a genetic algorithm based methodology. An application of the proposed methodology to the Chilean Central Interconnected System is then presented and analyzed. The results demonstrate its potential in the fields of risk analysis and decision support systems in power markets.     

Coarsening of particles connected by dislocations

This work theoretically reinvestigates the coarsening of particles controlled by diffusion through a dislocation network, when the dislocation spacing of the network is larger than the maximum particle size and the volume fraction of the particles vanishes. Both a three-dimensional network and a plane one, such as that which might be encountered at a low-angle grain boundary, are treated. It is considered here that the number of dislocation pipes for diffusion increases with distance away from the particle. Under certain reasonable assumptions, at ^1/4 steady-state coarsening kinetics is found. The origin of the differences between the present kinetic results (t^1/4) and those predictions previously reported in the specialized literature (t ^1/5), for similar dislocation geometries, are discussed. The effect of the dislocation annihilation phenomenon on the growth kinetics is also examined qualitatively.     

Fungal fucoidanase production by solid-state fermentation in a rotating drum bioreactor using algal biomass as substrate

Fucoidanase enzymes able to degrade fucoidan were produced by solid-state fermentation (SSF). The fermentation assays were initially carried out in a laboratory-scale rotating drum bioreactor, and two fungal strains (Aspergillus niger PSH and Mucor sp. 3P) and three algal substrates (untreated, autohydrolyzed, and microwave processed seaweed Fucus vesiculosus) were evaluated. Additionally, fermentations were carried out under rotational (10 rpm) and static conditions in order to determine the effect of the agitation on the enzyme production. Agitated experiments showed advantages in the induction of the enzyme when compared to the static ones. The conditions that promoted the maximum fucoidanase activity (3.82 U L^?1) consisted in using Mucor sp. 3P as fungal strain, autohydrolyzed alga as substrate, and the rotational system. Such conditions were subsequently used in a 10 times larger scale rotating drum bioreactor. In this step, the effect of controlling the substrate moisture during the enzyme production by SSF was investigated. Moreover, assays combining the algal substrate with an inert support (synthetic fiber) were also carried out. Fermentation of the autohydrolyzed alga with the moisture content maintained at 80% during the fermentation with Mucor sp. 3P gave the highest enzyme activity (9.62 U L^?1).     

Fully adaptive multiresolution schemes for strongly degenerate parabolic equations with discontinuous flux

A fully adaptive finite volume multiresolution scheme for one-dimensional strongly degenerate parabolic equations with discontinuous flux is presented. The numerical scheme is based on a finite volume discretization using the Engquist–Osher approximation for the flux and explicit time-stepping. An adaptive multiresolution scheme with cell averages is then used to speed up CPU time and meet memory requirements. A particular feature of our scheme is the storage of the multiresolution representation of the solution in a dynamic graded tree, for the sake of data compression and to facilitate navigation. Applications to traffic flow with driver reaction and a clarifier–thickener model illustrate the efficiency of this method.