A nanofabrication method for the production of ultra-dense planar metallic nanowire arrays scalable to wafer-size is presented. The method is based on an efficient template deposition process to grow diverse metallic nanowire arrays with extreme regularity in only two steps. First, III–V semiconductor substrates are irradiated by a low-energy ion beam at an elevated temperature, forming a highly ordered nanogroove pattern by a “reverse epitaxy” process due to self-assembly of surface vacancies. Second, diverse metallic nanowire arrays (Au, Fe, Ni, Co, FeAl alloy) are fabricated on these III–V templates by deposition at a glancing incidence angle. This method allows for the fabrication of metallic nanowire arrays with periodicities down to 45 nm scaled up to wafer-size fabrication. As typical noble and magnetic metals, the Au and Fe nanowire arrays produced here exhibited large anisotropic optical and magnetic properties, respectively. The excitation of localized surface plasmon resonances (LSPRs) of the Au nanowire arrays resulted in a high electric field enhancement, which was used to detect phthalocyanine (CoPc) in surface-enhanced Raman scattering (SERS). Furthermore, the Fe nanowire arrays showed a very high in-plane magnetic anisotropy of approximately 412 mT, which may be the largest in-plane magnetic anisotropy field yet reported that is solely induced via shape anisotropy within the plane of a thin film.
The Dutch company Chess develops a wireless sensor network (WSN) platform using an epidemic communication model. One of the greatest challenges in the design is to find suitable mechanisms for clock synchronization. In this paper, we study a proposed clock synchronization protocol for the Chess platform. First, we model the protocol as a network of timed automata and verify various instances using the Uppaal model checker. Next, we present a full parametric analysis of the protocol for the special case of cliques (networks with full connectivity), that is, we give constraints on the parameters that are both necessary and sufficient for correctness. These results have been checked using the proof assistant Isabelle. We report on the exhaustive analysis of the protocol for networks with four nodes, and we present a negative result for the special case of line topologies: for any instantiation of the parameters, the protocol will eventually fail if the network grows. 相似文献
Arrays of chemical vapor sensors based on graphene field effect transistors functionalized with single-stranded DNA have been demonstrated. Standard photolithographic processing was adapted for use on large-area graphene by including a metal protection layer, which protected the graphene from contamination and enabled fabrication of high quality field-effect transistors (GFETs). Processed graphene devices had hole mobilities of 1,640 ± 250 cm2.V-1.s-1 and Dirac voltages of 15 ± 10 V under ambient conditions. Atomic force microscopy was used to verify that the graphene surface remained uncontaminated and therefore suitable for controlled chemical functionalization. Single-stranded DNA was chosen as the functionalization layer due to its affinity to a wide range of target molecules and π-π stacking interaction with graphene, which led to minimal degradation of device characteristics. The resulting sensor arrays showed analyte- and DNA sequence-dependent responses down to parts-per-billion concentrations. DNA/GFET sensors were able to differentiate among chemically similar analytes, including a series of carboxylic acids, and structural isomers of carboxylic acids and pinene. Evidence for the important role of electrostatic chemical gating was provided by the observation of understandable differences in the sensor response to two compounds that differed only by the replacement of a (deprotonating) hydroxyl group by a neutral methyl group. Finally, target analytes were detected without loss of sensitivity in a large background of a chemically similar, volatile compound. These results motivate further development of the DNA/graphene sensor family for use in an electronic olfaction system. 相似文献
In this study, a series of castor oil based polyurethane/organically modified montmorillonite (OMMT) clay nanocomposite coatings have been successfully prepared by effective dispersing of OMMT nano-layers in polyurethane matrix through an ultrasonication assisted process. Effectiveness of ultrasonication process in de-agglomeration of clay stacks in castor oil dispersions was evaluated by optical microscopy and sedimentation test. Structure of nanocomposite coatings was investigated by wide angle X-ray diffraction (WAXD) and Fourier-transform infrared spectroscopy (FT-IR). The anticorrosive properties of nanocomposite coatings were characterized by electrochemical impedance spectroscopy (EIS), Tafel polarization study, water absorption and pull-off adhesion tests. The experimental results showed that PU/OMMT nanocomposite coatings were superior to the neat PU in corrosion protection effects. Also, it was observed that the corrosion protection of polyurethane organoclay nanocomposite coatings is improved as the clay loading is increased up to 3 wt.%. 相似文献
This work treats the problem of dynamic modeling and state space approximation for robotic manipulators with flexibility. Case studies are planar manipulators with a single flexible link together with clamped-free ends and tip mass conditions. In this paper, complete dynamic modeling of the flexible beam without premature linearization in the formulation of the dynamics equations is developed, whereby this model is capable of reproducing nonlinear dynamic effects, such as the beam stiffening due to the centrifugal and the Coriolis forces induced by rotation of the joints, giving it the capability to predict reliable dynamic behavior. On the other hand, in order to show the joint flexibility effects on the model dynamic behaviors, manipulator with structural and joint flexibility is considered. Thus, a reliable model for flexible beam is then presented. The model is founded on two basic assumptions: inextensibility of the neutral fiber and moderate rotations of the cross sections in order to account for the foreshortening of the beam due to bending. To achieve flexible manipulator control, the standard form of state space equations for a flexible manipulator system (flexible link and actuator) is very important. In this study, finite difference method for discretization of the dynamic equations is used and the state space equations of the flexible link with tip mass considering complete dynamic of the system are obtained. Simulation results indicated substantial improvements on dynamic behavior and it is shown that the joint flexibility has a considerable effect on the dynamic behavior of rotating flexible arm that should not be simply neglected. The effects of tip mass is proved to be increasing the elastic deformations?? amplitudes and increasing stability. 相似文献
An easy method for green and low-temperature (40 °C) reduction of graphene oxide (GO) by increasing the antioxidant activity of green tea polyphenols (GTPs) in the presence of iron was developed. The reduction level (obtained by X-ray photoelectron spectroscopy) and electrical conductivity (obtained by current–voltage measurement) of the GO sheets reduced by GTPs in the presence of iron were comparable to those of hydrazine-reduced GO and much better than those of the GO reduced by only GTPs (in the absence of iron) at reduction temperatures of 40–80 °C. Raman spectroscopy indicated that application of GTPs in the presence of iron, in contrast to hydrazine, resulted in better recovering of the sp2-hybridized structure of the sheets. The lasting water dispersion of the polyphenolic-reduced GO sheets in the presence of iron was assigned to π–π adsorption of Fe2+-polyphenol radicals on surface of the reduced sheets. A mechanism describing the role of iron in the reduction of the GO by epicatechin gallate and epigallocatechin gallate of green tea was also proposed. 相似文献