Synthesis,characterization and charge transport properties of Pr–Ni Co-doped SrFe2O4 spinel for high frequency devices applications

Ferrites are materials of interest due to their broad applications in high technological devices and a lot of research has been focused to synthesize new ferrites. In this regard, an effort has been devoted to synthesize spinel Pr–Ni co-substituted strontium ferrites with a nominal formula of Sr_1-xPr_xFe_2-yNi_yO₄ (0.0 ≤ x ≤ 0.1, 0.0 ≤ y ≤ 1.0). The cubic structure of pure and Pr–Ni co-substituted strontium ferrite samples calcinated at 1073 K for 3 h has been confirmed through X-ray diffraction (XRD). Average sizes of crystallites (18–25 nm) have been estimated from XRD analysis and nanometer particle sizes of synthesized ferrites have been further verified by scanning electron microscopy (SEM). SEM results have also shown that particles are mostly agglomerated and all the samples possess porosity. It has been observed that at 298 K, the values of resistivity (ρ) increase, while that of AC conductivity, dielectric loss, and dielectric constants decrease with increasing amounts of Pr³⁺ and Ni²⁺ ions. The values of dielectric parameters initially decrease with frequency and later become constant and can be explained on the basis of dielectric polarization. Electrochemical impedance spectroscopy (EIS) studies show that the charge transport phenomenon in ferrite materials is mainly controlled via grain boundaries. Overall, synthesized ferrite materials own enhanced resistivity values in the range of 1.38 × 10⁹–1.94 × 10⁹ Ω cm and minimum dielectric losses, which makes them suitable candidates for high frequency devices applications.     

Key-dependent side-channel cube attack on CRAFT

CRAFT is a tweakable block cipher introduced in 2019 that aims to provide strong protection against differential fault analysis. In this paper, we show that CRAFT is vulnerable to side-channel cube attacks. We apply side-channel cube attacks to CRAFT with the Hamming weight leakage assumption. We found that the first half of the secret key can be recovered from the Hamming weight leakage after the first round. Next, using the recovered key bits, we continue our attack to recover the second half of the secret key. We show that the set of equations that are solvable varies depending on the value of the key bits. Our result shows that 99.90% of the key space can be fully recovered within a practical time.     

Boosting the activity of FeOOH via integration of ZIF-12 and graphene to efficiently catalyze the oxygen evolution reaction

Transition metal oxyhydroxides have been used as promising electrocatalysts for water splitting however, their catalytic activity is restricted due to low surface area and poor conductivity. Herein, we report novel composite FeOOH@ZIF-12/graphene composite as electrocatalyst for water oxidation, whereby ZIF-12 provide extra surface for the FeOOH dispersion whilst graphene act as excellent electron mediator. The composite shows a low overpotential value of 291 mV to attain a current density of 10 mA cm^?2 and a low Tafel slope value of 78 mV dec^?1. The catalyst offers a maximum current density of 101 mA cm^?2, while it gives a turnover frequency (TOF) value of 0.031 s^?1 at an overpotential of 291 mV only. The excellent activity and remarkable stability of composite is attributed to highly conductive and porous support.     

Thermal and hydraulic performance of a modified two-stage evaporative cooler

The thermal and hydraulic performance of a modified two-stage evaporative cooler is evaluated. Variables considered are the mode of operation, packing thickness, mass flow rate of the water flowing to the precooler, and the mass flux of water flowing over the packing media. The effectiveness of the system increased with the increase of the mass flow rate of water flowing to the precooler, decreasing the mass flux of water flowing to the packing, and with the increase of the packing thickness. The effectiveness of the system with structured packing was higher than that with sheathy leaf base or natural fiber packing.The air-side pressure drop per unit length in the direction of air flow was nearly constant when the structured packing was used. For the sheathy leaf and natural fiber packings, the air pressure drop increased at a uniform rate as the mass flux of water flowing over the packing increased. The air pressure drop was lowest for the setup with the structured packing.     

Optimization Models for Layout and Pipe Design for Storm Sewer Systems

Optimization models are developed for simultaneously determining the pipe layout and the pipe design for storm sewer systems. The pipe design process includes computation of commercial diameters, slopes, and crown elevations for the storm sewer pipes. The optimization models aim to minimize the total costs of the layout and the pipe design for most of system elements. The optimization models are formulated as a 0–1 Integer Nonlinear Programming problem and solved using the General Algebraic Modeling System without the use of heuristic models which were characteristic of all previous models for the simultaneous determine of the pipe layout and pipe design of sewer networks. The models are based upon two different optimization approaches: (1) considers one or more commercial diameters of pipe connecting two manholes and (2) considers only one commercial diameter in a pipe connecting two manholes. The commercial diameters, pipe slopes, crown elevations, and total costs of the storm sewer system were compared for the two approaches using an example that illustrates the savings in cost by allowing multiple pipe sizes. The two new optimization modeling approaches developed herein can simultaneously determine the minimum cost pipe design (commercial diameters, slopes, and crown elevations) and pipe layout of storm sewer systems and satisfy all design constraints.

     

Gurum Seeds: A Potential Source of Edible Oil

Cucurbitaceae family seeds are mostly discarded as agro-industrial wastes. Gurum (Citrullus lanatus var. colocynthoide) is an underutilized wild cucurbit plant, closely related to desert watermelon, which is grown abundantly in some African countries. Gurum seeds can play a significant role in health and nutrition due to their high oil content. This review describes the nutritional composition of gurum seeds and their oil profile. Gurum seeds are a good source of oil (27–35.5%), fiber (26–31%), crude protein (15–18%), and carbohydrates (14–17%). Gurum seeds oil is extracted by supercritical CO₂ (SFE), screw press, and solvent extraction techniques. The gurum seeds oil is composed of unsaturated fatty acids with a high proportion of linoleic acid (C18:2) and oleic acid (C18:1). Gurum seeds oil contains various bioactive compounds, such as tocopherols, phytosterols, and polyphenols. It is reported that solvent extraction gives a higher yield than the screw press and SFE, but the SFE is preferred due to safety issues. More studies are required for producing better quality gurum seeds oil by using novel extraction techniques that can increase oil yield.     

Enhanced halftone-based secure and improved visual cryptography scheme for colour/binary Images

Visual Cryptography (VC) is gaining attraction during the past few years to secure the visual information in the transmission network. It enables the visual data i.e. handwritten notes, photos, printed text, etc. to encrypt in such a way that their decryption can be done through the human visual framework. Hence, no computational assistance is required for the decryption of the secret images they can be seen through naked eye. In this paper, a novel enhanced halftoning-based VC scheme is proposed that works for both binary and color images. Fake share is generated by the combination of random black and white pixels. The proposed algorithm consists of 3 stages i.e., detection, encryption, and decryption. Halftoning, Encryption, (2, 2) visual cryptography and the novel idea of fake share, make it even more secure and improved. As a result, it facilitates the original restored image to the authentic user, however, the one who enters the wrong password gets the combination of fake share with any real share. Both colored and black images can be processed with minimal capacity using the proposed scheme.

     

Biomathematical study of time-dependent flow of a Carreau nanofluid through inclined catheterized arteries with overlapping stenosis

Journal of Central South University - This work is concerned with the analysis of blood flow through inclined catheterized arteries having a balloon (angioplasty) with time-variant overlapping...     

Recent warming of Tonle Sap Lake,Cambodia: Implications for one of the world’s most productive inland fisheries

Tonle Sap Lake in Cambodia is arguably the world's most productive freshwater ecosystems, as well as the dominant source of animal protein for the country. The rapid rise of hydropower schemes, deforestation, land development and climate change impacts in the Mekong River Basin, however, now represent serious concerns in regard to Tonle Sap Lake's ecological health and its role in future food security. To this end, the present study identifies significant recent warming of lake temperature and discusses how each of these anthropogenic perturbations in Tonle Sap's floodplain and the Mekong River Basin may be influencing this trend. The lake's dry season monthly average temperature increased by 0.03°C/year between 1988 and 2018, being largely in synchrony with warming trends of the local air temperature and upstream rivers. The impacts of deforestation and agriculture development in the lake's floodplain also exhibited a high correlation with an increased number of warm days observed in the lake, particularly in its southeast region (agriculture R² = .61; deforestation R² = .39). A total of 79 dams, resulting in 72 km³ of volumetric water capacity, were constructed between 2003 and 2018 in the Mekong River Basin. This dam development coincided with a decreasing trend in the number of dry season warm days per year in the lower Mekong River, while Tonle Sap Lake's number of dry season warm days continued to increase during this same period. The present study revealed that Tonle Sap Lake's temperature trends are highly influenced by temperature trends in the local climate, agriculture development and deforestation of the lake's watershed. Although there were no noticeable impacts observed from upstream dam development in the Mekong River Basin, local‐to‐regional agricultural and land management of the lake's watershed appear to be effective strategies for maintaining a stable thermal regime in the lake in order to facilitate maximum ecosystem health.