Conducting carbon/polymer composites as a catalyst support for proton exchange membrane fuel cells

Carbon/poly(3,4‐ethylene dioxythiophene) (C/PEDOT) composites are synthesized by in situ chemical oxidative polymerization of EDOT monomer on carbon black in order to decrease carbon corrosion that occurred in carbon‐supported catalysts used in proton exchange membrane fuel cell. The effects of different dopants including polystyrene sulfonic acid, p‐toluenesulfonic acid and camphorsulfonic acid with the addition of ethylene glycol or dimethyl sulfoxide on the properties of the composites are investigated. The synthesized composites are characterized by X‐ray diffraction, Fourier transform infrared spectroscopy, thermogravimetric analysis, surface area analysis and scanning electron microscope. Electrical conductivity is determined by using the four‐point probe technique. Electrochemical oxidation characteristics of the synthesized C/PEDOT composites are investigated by cyclic voltammetry by applying 1.2 V for 24 h. The composite prepared at 25 °C with p‐toluenesulfonic acid and ethylene glycol shows the best carbon corrosion resistance. Platinum‐supported catalyst by using this composite was prepared using microwave irradiation technique, and it was seen that the prepared catalyst did not significantly lose its hydrogen oxidation and oxygen reduction reaction activities after electrochemical oxidation. Copyright © 2013 John Wiley & Sons, Ltd.     

A hybrid discrete particle swarm optimization for vehicle routing problem with simultaneous pickup and delivery

Vehicle routing problem (VRP) is an important and well-known combinatorial optimization problem encountered in many transport logistics and distribution systems. The VRP has several variants depending on tasks performed and on some restrictions, such as time windows, multiple vehicles, backhauls, simultaneous delivery and pick-up, etc. In this paper, we consider vehicle routing problem with simultaneous pickup and delivery (VRPSPD). The VRPSPD deals with optimally integrating goods distribution and collection when there are no precedence restrictions on the order in which the operations must be performed. Since the VRPSPD is an NP-hard problem, we present a heuristic solution approach based on particle swarm optimization (PSO) in which a local search is performed by variable neighborhood descent algorithm (VND). Moreover, it implements an annealing-like strategy to preserve the swarm diversity. The effectiveness of the proposed PSO is investigated by an experiment conducted on benchmark problem instances available in the literature. The computational results indicate that the proposed algorithm competes with the heuristic approaches in the literature and improves several best known solutions.     

Symmetric positive solutions of fourth order integral BVP for an increasing homeomorphism and homomorphism with sign-changing nonlinearity on time scales

In this paper, we consider the eigenvalue problems for fourth order integral boundary value problems on time scales for an increasing homeomorphism and homomorphism with sign changing nonlinearities. By using a fixed point index theorem, we give the existence of eigenvalue intervals in which there exist one symmetric positive solution to the problem. An example is also given to demonstrate the main results.     

Evaluation of ISSR markers for genetic diversity analysis in Anatolian water buffaloes

BACKGROUND: The utilisation of molecular markers has increased in molecular research recently. Inter‐simple sequence repeat (ISSR) markers allow the analysis of genomes without preliminary sequence information, since random primers are used. The purpose of the present study was to evaluate ISSR markers for assessing the genetic diversity of indigenous Anatolian Water Buffaloes reared in Afyon, Konya and Sivas provinces of Turkey, with a view to conservation of the gene resources. RESULTS: The 11 ISSR primers chosen for the analysis revealed a total of 110 bands, of which 76 (69.09%) were polymorphic. Also, genetic similarity, polymorphic information content (PIC), resolving power (R_p) and mean resolving power (R_p ), heterozygosity (H) and Shannon index (I) were calculated as 0.9479–0.9562, 0.35 ± 0.20, 2.73, 0.27, 0.18 ± 0.07 and 0.28 ± 0.11, respectively. CONCLUSION: The ISSR markers were found to be promising for assessing the genetic diversity in buffalo populations. Potential genetic parameters such as PIC, R_p, R_p , H and I were effectively used in this study. Copyright © 2011 Society of Chemical Industry     

Treatment of ureteral stones: comparison of extracorporeal shock wave lithotripsy and endourologic alternatives

Demographic data, personal and familial characteristics, as well as DSM-III-R-based psychiatric diagnoses were collected in 369 adolescents and young adults aged between 15 and 29 years, referred to an Emergency Department for psychological problems. In total, 60% of them were suicide attempters. Separations before the age of 12 years and depression in the family emerged as the main features distinguishing the suicidal group from the psychiatric control group. Fifty per cent of suicide attempters were repeaters. Fostering during childhood, suicide attempts and depression in the family were found to be risk factors for repeated self-attempts. These results support the view that significant levels of dysfunction, together with increased psychiatric morbidity, especially suicidal behaviour, characterize the families of young self-attempters.     

The pharmacology of local anesthetics

As practitioners of dentistry we are truly fortunate to have these wonder agents which we tend to use like water everyday. It is estimated that over 11,000,000 cartridges of local anesthetics are administered every year in Ontario. The incredible safety record speaks for itself. However, we must caution ourselves that a local anesthetic is a drug and as such demands our ongoing skill, care and judgment for each individual case.     

Asymmetry of happiness and sadness in effects on memory in normal college students: Comment on Hasher, Rose, Zacks, Sanft, and Doren.

Research suggests that, whereas induced happiness tends to facilitate the recall of positive material, induced mild sadness often does not facilitate the recall of negative material symmetrically. These results are compatible with those reported by L. Hasher et al (see record 1986-03061-001) but also suggest that their failure to observe effects of mild depression on recall should not be overgeneralized to conclude that affective states other than mild sadness have negligible effects on cognitive processes. Possible mediators of these phenomena are discussed, and their potential relevance to the understanding of clinical depression and of the cognitive representation of various affective states is considered. (19 ref) (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Affect, accessibility of material in memory, and behavior: A cognitive loop?

Conducted 2 studies to investigate the effect of good mood on cognitive processes. In Exp I, which was conducted in a shopping mall, a positive feeling state was induced by giving Ss a free gift; good mood, thus induced, was found to improve Ss' evaluations of the performance and service records of products they owned. In Exp II, with 47 undergraduates, affect was induced by having Ss win or lose a computer game in a laboratory setting; Ss who had won the game were better able to recall positive material in memory. Results are discussed in terms of the effect that feelings have accessibility of cognitions. In addition, the nature of affect and the relationship between good mood and behavior (such as helping) are discussed in terms of this proposed cognitive process. (38 ref) (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Spatial assessment of site suitability for solar desalination plants: a case study of the coastal regions of Turkey

Clean Technologies and Environmental Policy - Many countries, especially in arid and semiarid regions, suffer from water scarcity because of the decline in the existing freshwater reserves by...     

Four‐band electromagnetic energy harvesting with a dual‐layer metamaterial structure

A four‐band metamaterial harvester for harvesting 0.9 GHz, 1.8 GHz, 2.6 GHz, and 5.8 GHz signals is proposed by a dual‐layer structure. 0.9 GHz and 1.8 GHz bands are harvested by the resistors in front layer, whereas harvesting of 2.6 GHz is achieved by the resistors in second layer. All resistors in front and back layer contribute to harvesting at 5.8 GHz. Numerical calculations are verified by two different full‐wave electromagnetic solvers based on finite‐integration and finite‐element techniques. Power dissipation ratios at 0.9 GHz, 1.8 GHz, 2.6 GHz and 5.8 GHz frequencies concentrated at the resistors are found as 82.3%, 82.8%, 74.6%, and 83.6%, respectively, by the finite‐integration‐based solver. Besides, the finite‐element method‐based solver results in harvesting efficiencies of 79.6%, 93.4%, 73.7%, and 93.8%. The efficiency of the harvester is investigated for different oblique incidences. The proposed metamaterial harvester can be a good candidate for multi‐band absorption and harvesting applications.