Biodiversity and technological properties of yeasts from Turkish sourdough

Food Science and Biotechnology - In this study, yeasts were isolated and characterized from twelve traditional sourdough samples which belongs to Black Sea and Aegean regions of Turkey. Twenty six...     

Resuspension of soil as a source of airborne lead near industrial facilities and highways

Geologic materials are an important source of airborne particulate matter less than 10 microm aerodynamic diameter (PM10), but the contribution of contaminated soil to concentrations of Pb and other trace elements in air has not been documented. To examine the potential significance of this mechanism, surface soil samples with a range of bulk soil Pb concentrations were obtained near five industrial facilities and along roadsides and were resuspended in a specially designed laboratory chamber. The concentration of Pb and other trace elements was measured in the bulk soil, in soil size fractions, and in PM10 generated during resuspension of soils and fractions. Average yields of PM10 from dry soils ranged from 0.169 to 0.869 mg of PM10/g of soil. Yields declined approximately linearly with increasing geometric mean particle size of the bulk soil. The resulting PM10 had average Pb concentrations as high as 2283 mg/kg for samples from a secondary Pb smelter. Pb was enriched in PM10 by 5.36-88.7 times as compared with uncontaminated California soils. Total production of PM10 bound Pb from the soil samples varied between 0.012 and 1.2 mg of Pb/kg of bulk soil. During a relatively large erosion event, a contaminated site might contribute approximately 300 ng/m3 of PM10-bound Pb to air. Contribution of soil from contaminated sites to airborne element balances thus deserves consideration when constructing receptor models for source apportionment or attempting to control airborne Pb emissions.     

THE METHOD OF LINES SOLUTION OF THE DISCRETE ORDINATES METHOD FOR RADIATIVE HEAT TRANSFER IN ENCLOSURES

A radiation code based on the method of lines (MOL) solution of the discrete ordinates method (DOM) for transient three-dimensional radiative heat transfer in rectangular enclosures for use in conjunction with a computational fluid dynamics (CFD) code based on the same approach was developed. Assessment of the predictive accuracy of the code by benchmarking its steady-state solutions against exact solutions on one- and three-dimensional test problems shows that the MOL solution of the DOM provides accurate and computationally efficient solutions for radiative heat fluxes and source terms and can be used with confidence in conjunction with CFD codes for transient problems.     

Poly(methyl methacrylate)/POSS hybrid networks by type II photoinitiated free radical polymerization

A new strategy for organic–inorganic hybrid networks is presented through in‐situ Type II photoinitiated polymerization of methyl methacrylate with diethanolamino‐functionalized polyhedral oligomeric silsesquioxanes (POSS‐DEA). The diethanolamino groups are simply incorporated onto POSS nanoparticles by nucleophilic ring‐opening reaction of commercially available epoxycyclohexyl POSS and diethanol amine. The photoinitiated polymerization of methyl methacrylate in the presence of benzophenone as photosensitizer and POSS‐DEA as hydrogen donor leads to poly(methyl methacrylate) (PMMA)/POSS hybrid networks under UV light irradiation. The morphology and thermal properties of hybrid networks are investigated by using Fourier transform infrared spectroscopy, differential scanning calorimetry, thermogravimetric analysis, and transmission electron microscopy. The morphology results confirm that POSS cages are homogeneously distributed in PMMA matrix at the molecular levels, whereas the thermal analyses shows that the obtained hybrid networks have higher glass transition temperatures and better thermal stabilities compared to parent PMMA homopolymer. POLYM. COMPOS., 35:1614–1620, 2014. © 2013 Society of Plastics Engineers     

Electrical characterization of Au/Pd/n-GaN/Pd/Au device structure in the radio frequency range by simulation study

GaN based devices are highly promising optoelectronic devices for many years due to their useful applications in photovoltaic energy conversation, fiber optic communication and atmosphere monitoring. GaN based devices such as Schottky barrier, metal–semiconductor–metal and p-i-n structure have been fabricated and characterized so far. A proper understanding of the impedance or admittance spectroscopy result is crucial since it is a powerful tool to calculate the physical and electronic parameters of a device. In this study, temperature dependent dark current–voltage (I–V) and dark impedance spectra of n type GaN based metal–semiconductor–metal device have been studied with current–voltage and impedance spectra by simulation. All current–voltage characteristics exhibited good rectification behavior. The forward and reverse bias capacitance–voltage (C–V) characteristics of the Au/Pd/n-GaN/Pd/Au device were simulated at 2 MHz probing frequency. Nyquist plots of simulated device at 295 K are shown that two-barrier heights can be observable above critical threshold bias point. Frequency depended inverse dielectric loss tangent spectra of Au/Pd/n-GaN/Pd/Au device at different DC bias voltages also shows significant two peaks. This indicates that our simulation is extremely useful for determination of potential barrier numbers.     

Assessment of gas radiative property models in the presence of nongray particles

In this study, a radiation code based on the method of lines solution of the discrete ordinates method for the prediction of radiative heat transfer in nongray gaseous media is developed by incorporation of two different spectral gas radiative property models, banded spectral line-based weighted sum of gray gases (banded SLW) and gray wide band (GWB) approximation in the presence of nongray absorbing–emitting–scattering particles. The aim is to introduce an accurate and CPU efficient spectral gas radiation model, which is compatible with spectral fuel/ash particle property models. Input data required for the radiation code and its validation are provided from two combustion tests previously performed in a 300 kWt atmospheric bubbling fluidized bed combustor test rig burning low calorific value Turkish lignite with high volatile matter/fixed carbon (VM/FC) ratio in its own ash. The agreement between wall heat fluxes and source term predictions obtained by global and banded SLW models reveal that global SLW model can be converted to an accurate wide band gas model (banded SLW) which can directly be coupled with spectral particle radiation. Furthermore, assessment of GWB approximation by benchmarking its predictions against banded SLW model shows that GWB gives reasonable agreement with a higher CPU efficiency when the particle absorption coefficient is at least in the same order of magnitude with the gas absorption coefficient.     

Investigation and scale-up of hot-melt coating of pharmaceuticals in fluidized beds

This study was performed to investigate and scale-up the hot-melt coating process in fluidized beds. A series of well-designed experiments was carried out in a pilot scale unit with 20 kg product capacity to investigate the effects of process variables on the efficiency of the coating of Cefuroxime Axetil with stearic acid. Results showed that the efficiency is at the highest when the fluidization air flow rate is adjusted by considering the changes in the amount of materials present in the unit as well as the changes in the terminal velocities of particles during the process.With the objective to scale-up the hot-melt coating process from pilot to production scale, a dynamic thermodynamic model based on conservation equations of mass and energy was developed. Predictive accuracy of the model was assessed by applying it to the pilot scale unit and comparing its predictions with the online measurements taken on the same unit. Results showed that the predictions of the model agree well with the measurements. Utilizing this model and taking several experiments performed in the pilot scale unit as a basis, scaling up of the hot-melt coating process was carried out. Comparisons of the model predictions with the measurements taken on the production scale unit (200 kg product capacity) revealed that the model is able to reproduce the product attributes and the outlet air temperatures across scales. Therefore, it proves to be a promising tool that can be used in the scale-up of the hot-melt coating processes in fluidized beds.     

Solution-Processed Polyfluorene:Naphthalenediimide–N-Doped TiO2 Hybrids for Ultraviolet Photodetector Applications

In this study, highly efficient ultraviolet (UV) photodetectors based on a solution-processed system are introduced. Nitrogen-doped TiO₂ nanoparticles are embedded in poly(9,9-dioctylfluorenyl-2,7-yleneethynylene) (PFE):N,N′-bis-n-butyl-1,4,5,8-naphthalenediimide (BNDI) (3:1 wt.%) blends. An UV- active layer of [(PFE:BNDI)(3:1):ammonium hydroxide-TiO₂] [9:1 wt.%] gave a photoresponsivity value of 545 ± 6.92 mA/W at ?4 V under 1 mW/cm² UV light at 365 nm, and this value was increased to 597 ± 9.22 mA/W on annealing the active layer at 60°C. The efficiencies obtained are strongly dependent on the nitrogen source nature, their donor–acceptor relationship, and the morphological interaction with the PFE:BNDI blend.     

A Thienothiophene-Based Cation Treatment Allows Semitransparent Perovskite Solar Cells with Improved Efficiency and Stability

Perovskite surface treatment with additives has been reported to improve charge extraction, stability, and/or surface passivation. In this study, treatment of a 3D perovskite ((FAPbI₃)_1−x(MAPbBr₃)_x) layer with a thienothiophene-based organic cation (TTMAI), synthesized in this work, is investigated. Detailed analyses reveal that a 2D (n = 1) or quasi-2D layer does not form on the PbI₂-rich surface 3D perovskite. TTMAI-treated 3D perovskite solar cells (PSCs) fabricated in this study show improved fill factors, providing an increase in their power conversion efficiencies (PCEs) from 17% to over 20%. It is demonstrated that the enhancement is due to better hole extraction by drift-diffusion simulations. Furthermore, thanks to the hydrophobic nature of the TTMAI, PSC maintains 82% of its initial PCE under 15% humidity for over 380 h (the reference retains 38%). Additionally, semitransparent cells are demonstrated reaching 17.9% PCE with treated 3D perovskite, which is one of the highest reported efficiencies for double cationic 3D perovskites. Moreover, the semitransparent 3D PSC (TTMAI-treated) maintains 87% of its initial efficiency for six weeks (>1000 h) when kept in the dark at room temperature. These results clearly show that this study fills a critical void in perovskite research where highly efficient and stable semitransparent perovskite solar cells are scarce.