全文获取类型
收费全文 | 591篇 |
免费 | 44篇 |
国内免费 | 4篇 |
专业分类
电工技术 | 8篇 |
综合类 | 1篇 |
化学工业 | 173篇 |
金属工艺 | 5篇 |
机械仪表 | 16篇 |
建筑科学 | 20篇 |
能源动力 | 37篇 |
轻工业 | 95篇 |
水利工程 | 2篇 |
石油天然气 | 1篇 |
无线电 | 39篇 |
一般工业技术 | 137篇 |
冶金工业 | 28篇 |
原子能技术 | 3篇 |
自动化技术 | 74篇 |
出版年
2024年 | 7篇 |
2023年 | 14篇 |
2022年 | 19篇 |
2021年 | 22篇 |
2020年 | 21篇 |
2019年 | 25篇 |
2018年 | 28篇 |
2017年 | 31篇 |
2016年 | 22篇 |
2015年 | 17篇 |
2014年 | 26篇 |
2013年 | 81篇 |
2012年 | 59篇 |
2011年 | 49篇 |
2010年 | 27篇 |
2009年 | 27篇 |
2008年 | 15篇 |
2007年 | 23篇 |
2006年 | 16篇 |
2005年 | 18篇 |
2004年 | 20篇 |
2003年 | 6篇 |
2002年 | 10篇 |
2001年 | 3篇 |
2000年 | 2篇 |
1999年 | 5篇 |
1998年 | 3篇 |
1997年 | 6篇 |
1996年 | 12篇 |
1995年 | 6篇 |
1994年 | 3篇 |
1992年 | 1篇 |
1990年 | 2篇 |
1989年 | 3篇 |
1988年 | 2篇 |
1987年 | 4篇 |
1986年 | 1篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1970年 | 1篇 |
排序方式: 共有639条查询结果,搜索用时 15 毫秒
1.
In the present study, the effects of charge‐transfer complex formation and intramolecular fragmentation (side‐chain lactonization) in radical copolymerization of tert‐butyl vinyl ether (t‐BVE) with anhydrides of maleic (MA) and citraconic (CA) acids and the structure–thermal behavior relationships of the resulting copolymers were examined using the 1H‐NMR, FTIR, DSC, and TGA analysis methods. It was shown that copolymerization under the chosen conditions proceeded through intramolecular fragmentation with the formation of γ‐lactone units. Side‐chain fragmentation of t‐BVE–MA and t‐BVE–CA copolymers also was confirmed by TGA and DSC analysis. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 2455–2463, 2006 2006 相似文献
2.
Hatice Kaplan Can A. Lale Doan Zakir M. O. Rzaev Ayegül Hasegeli Uner Ali Güner 《应用聚合物科学杂志》2006,100(5):3425-3432
The ternary copolymerization of maleic anhydride (MA), vinyl acetate (VA), and acrylic acid (AA) [P(MA‐co‐VA‐co‐AA)], which is considered to be an acceptor–donor–acceptor system, was carried out in 1,4‐dioxane with benzoyl peroxide as an initiator at 70°C under a nitrogen atmosphere. Constants of complex formation for the monomer systems in the study were determined by UV–visible (hydrogen‐bonding complex) and 1H‐NMR (charge transfer complex) methods, respectively. The results show that polymerization of the P(MA‐co‐VA‐co‐AA) system proceeds by an alternating terpolymerization mechanism. It is shown that the synthesized copolymers have typical polyelectrolyte behavior, ability for reversible hydrolysis–anhydrization reactions, and semicrystalline structures. In these cases, including radical polymerization, and formation of semicrystalline structures, the hydrogen‐bonding effect plays a significant role. The in vitro cytotoxicities of the synthesized terpolymer and alternating copolymer were evaluated using Raji cells (human Burkitt lymphoma cell line). The antitumor activities of prepared anion‐active copolymers were studied using methyl–thiazol–tetrazolium colorimetric assay and 50% of the cytotoxic dose of each copolymer and terpolymer were calculated. Hydrolyzed P(MA‐co‐VA‐co‐AA) and P(MA‐alt‐AA) copolymers have sufficiently high antitumor activity, which depends on the amount of hydrogen‐bonding carboxylic groups and their regular distribution in the side chain of functional macromolecules. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 3425–3432, 2006 相似文献
3.
S. Yildirim R. G. Fuentes R. Evangelista Z. L. Nikoloy 《Journal of the American Oil Chemists' Society》2002,79(8):809-814
Two germ-separation methods, dry-milling and density separation by flotation, were evaluated for recovering recombinant β-glucuronidase
(rGUS) that accumulated primarily in the germ of transgenic corn. The dry-milling process consisted of (i) seed tempering,
(ii) degerming with a horizontal-drum degermer/dehuller, (iii) particle size fractionation with standard sieves, (iv) germ
and endosperm separation by roller milling and sifting, and (v) removal of hulls by aspiration. Sieves nos. 5, 6, and 7 retained
the majority of germ, and subfractions from these sieves were pooled as a germ-rich fraction. Mass balances showed that the
germ-rich fraction, which constituted 17% of the total dry-milled corn weight, contained 49% of rGUS activity and 64% of the
total recoverable oil. Germ fractionation by flotation was tested as a proof-of-concept method aimed at separating corn fractions
based on their difference in specific gravity (sp gr). The process consisted of impact-grinding of corn kernels followed by
density separation using 1.15 or 1.3 specific gravity sodium nitrate solution. The oil-containing germ fraction floated, whereas
the heavier endosperm fraction sedimented. The flotation method was simpler and resulted in higher enzyme recovery, that is,
the germ-rich fraction was 20% (w/w) of the initial corn weight, and accounted for 80% of rGUS activity and 77% of total oil.
The sodium nitrate solution did not have an adverse effect on the enzyme activity. 相似文献
4.
Due to a lot of robot manipulators application in industry, low noise degree is very important criteria for robot manipulator's joints. In this paper, joint noise problem of a robot manipulator with five joints is investigated both theoretically and experimentally. The investigation is consisted of two steps. First step is to analyze the noise of joints using a hardware and software. The hardware is a part of noise sensors. The second step; according to experimental results, some neural networks are employed for finding robust neural noise analyzer. Five types of neural networks are used to compare each other. From the results, it is noted that the proposed RBFNN gives the best results for analyzing joint noise of the robot manipulator. 相似文献
5.
H. AskariZ. Saadatnia D. YounesianA. Yildirim M. Kalami-Yazdi 《Computers & Mathematics with Applications》2011,62(10):3894-3901
Approximate periodic solutions for the Helmholtz-Duffing oscillator are obtained in this paper. He’s Energy Balance Method (HEBM) and He’s Frequency Amplitude Formulation (HFAF) are adopted as the solution methods. Oscillation natural frequencies are analytically analyzed. Error analysis is carried out and accuracy of the solution methods is evaluated. 相似文献
6.
Hub location problems deal with finding the location of hub facilities and with the allocation of demand nodes to these located hub facilities. In this paper, we study the single allocation hub covering problem over incomplete hub networks and propose an integer programming formulation to this end. The aim of our model is to find the location of hubs, the hub links to be established between the located hubs, and the allocation of non-hub nodes to the located hub nodes such that the travel time between any origin–destination pair is within a given time bound. We present an efficient heuristic based on tabu search and test the performance of our heuristic on the CAB data set and on the Turkish network. 相似文献
7.
In the first part of this article, we analyze the relation between local image structures (i.e., homogeneous, edge-like, corner-like or texture-like structures) and the underlying local 3D structure (represented in terms of continuous surfaces and different kinds of 3D discontinuities) using range data with real-world color images. We find that homogeneous image structures correspond to continuous surfaces, and discontinuities are mainly formed by edge-like or corner-like structures, which we discuss regarding potential computer vision applications and existing assumptions about the 3D world. In the second part, we utilize the measurements developed in the first part to investigate how the depth at homogeneous image structures is related to the depth of neighbor edges. For this, we first extract the local 3D structure of regularly sampled points, and then, analyze the coplanarity relation between these local 3D structures. We show that the likelihood to find a certain depth at a homogeneous image patch depends on the distance between the image patch and a neighbor edge. We find that this dependence is higher when there is a second neighbor edge which is coplanar with the first neighbor edge. These results allow deriving statistically based prediction models for depth interpolation on homogeneous image structures. 相似文献
8.
The dielectric constant and the dielectric loss of tantalum pentoxide (Ta2O5) thin films, produced by sol-gel spin-coated process on Corning glass substrates, have been investigated in the frequency range of 20-105 Hz and the temperature range of 183-403 K, using ohmic Al electrodes. The frequency and temperature dependence of relaxation time has also been determined. The capacitance and loss factor were found to decrease with increasing frequency and increase with increasing temperature. The activation energy values were evaluated and a good agreement between the activation energy values obtained from capacitance and dielectric loss factor measurements were observed. 相似文献
9.
This paper reports the presence of Al- O- Al linkages in an aluminosilicate glass where Si/Al = 1 by using 2D17O triple quantum MAS NMR technique (3Q MASNMR). The experiments were performed at external magnetic fields of 8.4 and 14.4T.
Despite17OMAS NMR spectra of the sample in both fields do not give much information about the different kinds of linkages in the sample,
3Q MAS NMR spectrum shows clear evidence that there are some amounts of Al-O-Al linkages in the sample giving two completely
resolved peaks. These two peaks were attributed to the Si-O-Al and Al-O-Al linkages on the basis of their chemical shifts
and, quadrupolar coupling constants which are quite sensitive to the local structure. 相似文献
10.
Ekrem Kalkan 《Bulletin of Engineering Geology and the Environment》2012,71(1):99-103
Granular soil was stabilized using different proportions of silica fume–lime and fly ash–lime and compacted at optimum water
content. Compaction, compressive strength and California Bearing Ratio tests were undertaken which confirmed that the use
of waste materials and lime mixtures improved the strength properties of the crushed granular soils. 相似文献