A fog-based security framework for intelligent traffic light control system

Multimedia Tools and Applications - The world is facing many problems including that of traffic congestion. To highlight the issue of traffic congestion worldwide specially in urban areas and to...     

Matching-Pursuits Dissimilarity Measure for Shape-Based Comparison and Classification of High-Dimensional Data

In this paper, a new matching pursuits dissimilarity measure (MPDM) is presented that compares two signals using the information provided by their matching pursuits (MP) approximations, without requiring any prior domain knowledge. MPDM is a flexible and differentiable measure that can be used to perform shape-based comparisons and fuzzy clustering of very high-dimensional, possibly compressed, data. A novel prototype based classification algorithm, which is termed the computer aided minimization procedure (CAMP), is also proposed. The CAMP algorithm uses the MPDM with the competitive agglomeration (CA) fuzzy clustering algorithm to build reliable shape based prototypes for classification. MP is a well known sparse signal approximation technique, which is commonly used for video and image coding. The dictionary and coefficient information produced by MP has previously been used to define features to build discrimination and prototype based classifiers. However, existing MP based classification applications are quite problem domain specific, thus making their generalization to other problems quite difficult. The proposed CAMP algorithm is the first MP based classification system that requires no assumptions about the problem domain and builds a bridge between the MP and fuzzy clustering algorithms. Experimental results also show that the CAMP algorithm is more resilient to outliers in test data than the multilayer perceptron (MLP) and support-vector-machine (SVM) classifiers, as well as prototype-based classifiers using the Euclidean distance as their dissimilarity measure.     

水声网络全双工定向碰撞避免媒体接入控制协议

近年来水声网络(UAN)技术飞速发展,但仍然面临诸多严峻挑战,能量效率成为水声网络的首要考虑因素。此外,水声信道传播时延大且可用带宽受限,严重制约了水声通信技术的可靠性和有效性,进而限制了水声网络的整体性能。定向通信技术可以有效改善上述情况,通过波束聚焦能力将声波能量聚集在一定角度范围内,获得比全向通信更高的通信范围和信噪比,提升整个网络的能耗效率和空间复用率。但该技术需要对目的节点的位置具备先验知识,且会面临“聋节点”问题,因此该文提出一个水声网络全双工定向碰撞避免(FDDCA)媒体接入控制(MAC)协议,通过装备两个分别处于不同工作频带的全向换能器和定向换能器解决“聋节点”问题,并通过降低节点的冲突域解决了“暴露终端”问题。仿真结果表明,与水下Aloha(UW-Aloha)和时隙地面多址接入(S-FAMA)协议相比,FDDCA在多汇聚节点的网络拓扑下吞吐量分别提升了140%和400%,网络能效上节省了90%和94%。     

Recent developments in catalyst synthesis using DBD plasma for reforming applications

The catalyst has a significant role in gas processing applications such as reforming technologies for H₂ and syngas production. The stable catalyst is requisite for any industrial catalysis application to make it commercially viable. Several methods are employed to synthesize the catalysts. However, there is still a challenge to achieve a controlled morphology and pure catalyst which majorly influences the catalytic activity in reforming applications. The conventional methods are expansive, and the removal of the impurities are major challenges. Nevertheless, it is not straightforward to achieve the desired structure and stability. Therefore, significant interest has been developed on the advanced techniques to take control of the physicochemical properties of the catalyst through non-thermal plasma (NTP) techniques. In this review, the systematic evolution of the catalyst synthesis using NTP technique is elucidated. The emerging DBD plasma to synthesized and effective surface treatment is reviewed. DBD plasma synthesized catalyst performance in reforming application for H₂ and syngas production is summarised. Furthermore, the status of DBD plasma for catalyst synthesis and proposed future avenues to design environmentally suitable and cost-effective synthesis techniques are discussed.     

Conducting polymers inducing catalysis: Enhanced formic acid electro-oxidation at a Pt/polyaniline nanocatalyst

Research is moving rapidly to sustain convenient energy resources fulfilling the global climate legislations. Herein, a novel catalyst of platinum nanoparticles (PtNPs) dispersed onto polyaniline (PANi) is recommended for formic acid electro-oxidation (FAO); the fundamental anodic reaction in direct formic acid fuel cells (DFAFCs). The catalyst's preparation scheme allows a sequential electrodeposition of fibril PANi and spherical PtNPs (ca. 65 nm in size) on a glassy carbon (GC) substrate and permits a precise control over the deposition sequence and loading. Interestingly, incorporation of PANi into the catalyst's ingredients can significantly (ca. 16 times) improve the catalytic activity of the catalyst towards FAO by shifting the mechanism towards the desirable dehydrogenation pathway and mitigating the undesirable poisoning dehydration pathway. The catalytic efficiency is tuned by manipulating the deposition order and loading of different catalyst's ingredients. Several techniques are employed to confirm the successful deposition of the catalyst and to evaluate its morphology, composition and crystal structure. While PtNPs are essential for FA adsorption, PANi improves the dispersion of PtNPs and mediates FAO to facilitate the charge transfer and mitigate CO poisoning. A promising catalytic stability is achieved in a long continuous (150 CVs) electrolysis experiment.     

Progress on Epoxy/Polyamide and Inorganic Nanofiller-Based Hybrids: Introduction,Application, and Future Potential

An efficient method to obtain better properties of epoxy-based nanocomposites is to introduce thermoplastic polymer such as polyamide into thermosetting resin. Combined effect of both polymers provides extra-bonding sites for nanofiller dispersion. This review mainly covers inorganic nanofiller dispersed epoxy/polyamide nanocomposite and their applications. To understand interaction between thermoset epoxy and thermoplastic polyamide, knowledge of structure, synthesis, and categorization is worth important. Addition of inorganic nanofiller such as layered silicate and metal oxide results in enhanced thermomechanical, physiochemical, and anticorrosive properties of resultant nanocomposite. These nanocomposites have applications as protective coatings, adhesives, insulators in electrical devices, and in aerospace industries.     

Bioaugmentation of floating treatment wetlands for the remediation of textile effluent

This pilot study evaluated the effects of bacterial augmentation on the efficiency of floating treatment wetlands (FTWs) to remediate textile wastewater. Two wetland plants, Phragmites australis and Typha domingensis, were used to develop FTWs, which were then augmented with a bacterial consortium of three strains (Acinetobacter junii, Pseudomonas indoloxydans, and Rhodococcus sp.). Results showed that both plant species removed colour, organic matter, toxicity, and heavy metals from textile wastewater and their removal efficiency was further enhanced by augmentation with bacteria. The maximum removal efficiencies of colour, COD and BOD after an 8‐day period were 97, 87 and 92%, respectively, by FTWs carrying P. australis inoculated with the bacterial consortium. Furthermore, the same combination showed 87–99% reduction of heavy metals in the textile wastewater as well. These results indicate that FTWs can be used for the treatment of textile effluent and their working efficiency can be improved by plant‐bacterial synergism.     

Aerosol assisted chemical vapour deposited (AACVD) of TiO2 thin film as compact layer for dye-sensitised solar cell

Compact TiO₂ has been introduced onto the surface of an indium tin oxide glass slide (ITO), using an aerosol-assisted chemical vapour deposition method. This serves as a blocking layer for a dye-sensitised solar cell (DSSC). The thickness of the compact TiO₂ could be controlled by deposition time. X-ray diffraction and Raman spectroscopy analyses reveal that the compact TiO₂ is made up of mixed anatase and rutile phases. The field emission scanning electron microscopy image displays a pyramidal morphology of the compact TiO₂. A layer of P25 paste was then smeared onto the compact TiO₂-modified ITO, using the doctor's blade method. A post-treatment procedure was applied to remove the contaminants from the prepared hybrid film, by immersing in a hydrochloric acid solution. The photoelectrochemical measurements and J–V characterisation of the hybrid film show an approximately fourfold increase in photocurrent density generation (114.22 µA/cm²), and approximately 25% enhancement of DSSC conversion efficiency (4.63%), compared to the acid-treated P25 paste alone (3.68%).     

Investigation of improved dielectric and thermal properties of ternary nanocomposite PMMA/MXene/ZnO fabricated by in-situ bulk polymerization

Electric power system applications demand for high-temperature dielectric materials. The improved performance of polymer nanocomposites requires improvement in their thermal conductivity & stability, dielectric stability and processing technique. However, they often lose their dielectric properties with a rise in temperature. Here, we offer a solution by incorporating electrically conducting material (MXene) and semiconducting inorganic nanoparticles (ZnO NPs) into an insulating PMMA polymer matrix to maintain high dielectric constant, both at the room and high temperature. Therefore, to achieve desirable thermal and dielectric properties is the main objective of the present study based on the homogeneous distribution of the nanofillers by in-situ bulk polymerization assisted by strong sonication in the corresponding polymer. The introduction of MXene and ZnO NPs into the PMMA not only acquires a substantial increment in the dielectric constant, to attain a value 437, with minimum energy loss of 0.36 at 25 Hz, but also improves the thermal conductivity of PMMA up to 14 times by causing the reduction of thermal resistance, which is actually responsible for the poor thermal conductivity of amorphous pure PMMA polymer. More importantly, hybrid PMMA/4:2 wt% MXene:ZnO nanocomposite leads to an excellent thermal stability. Moreover, further characterization of the synthesized nanocomposites by FTIR, SEM and XRD leads to the evaluation of strong interaction of ternary components with PMMA matrix.