二垩英与资源回收-Ⅰ考虑到二垩英生成的资源与能量回收基础研究

目前在日本,存在大量工业垃圾,包括各种塑料制品,ASR(汽车破碎垃圾),含有毒PCB(多氯联苯)的110变压器和PVC(聚氯乙稀)制品等.而来自城市垃圾焚烧炉的废气含有大量能量.因此,在充分考虑环境、避免二垩英生成的同时,安全回收来自工业垃圾、城市和/或工业垃圾焚烧炉的资源和能量是个非常重要的课题,这也将对抑制CO2排放作出贡献.正确地阐明焚烧过程中二垩英的生成机理及详细研究含少量二垩英的焚烧废气在冷却过程中大量形成二垩英的临界温度是项很重要的工作.解决这个问题可有效实现资源和能量的回收.本报告介绍日本在二垩英排放方面目前采取的对策和存在的问题以及大阪大学为阻止二垩英生成所做的基础研究工作.     

Basic study about cooperative movement between a human and an agent with entrainment

The use of an agent in the environment, as in medical treatment, welfare, the construction field, and the home, is examined. It is necessary for the agent to be able to work cooperatively with a human, and that may be a problem. Therefore, this study pays attention to the phenomenon that is called entrainment. This is the phenomenon where the rhythm of a certain person and the partner in the communication is synchronized. The purpose of this study is to perform a basic examination into applying an entrainment in order to realize cooperation in operations between a human and an agent. Since many human rhythms are expressed by a nonlinear oscillator, we simulated limited cycle oscillators, which are one of two nonlinear oscillators that cause interactions between agents, as the basic examination for this achievement. Consequently, entrainment of limited cycle oscillators with rhythms which differ has been checked in certain conditions. As a result, the possibility that cooperative movement could be gained was suggested.     

The evaluation of the emotion by near-infrared spectroscopy

Our purpose is to develop the technology for evaluating emotion objectively from the oxygenated hemoglobin within a brain. Nowadays, Japan is an aging society. The elderly people who need care will increase from now on increasingly. In the case of the person requiring the care who lost the function to convey an intention especially, the objective judgment to a physical and mental pain is required. Persons requiring care will also increase in number with the increase in this population. We gave subject stimulus of a comfortable or an uncomfortable sound and measured concentration of the oxygenated hemoglobin of a frontal lobe part by near-infrared spectroscopy. Based on the experimental result, a comfortable state or an uncomfortable state was distinguished by concentration of the oxygenated hemoglobin using the bayesian network. As a result, we were able to estimate the subject’s psychological condition.     

Effect of poly(vinyl acetate/vinyl alcohol) copolymer with a thiol end group as a steric stabilizer on dispersion polymerization of styrene

In dispersion polymerization of styrene in ethanol, effects of a reactive steric stabilizer, poly(vinyl acetate/vinyl alcohol) copolymer with a thiol end group (P(VAc/VA)-SH), were investigated. In the absence of the thiol end group, the dispersion coagulated at the middle stage of the polymerization, while in the presence of the thiol end group, the polymerization proceeded successfully to result in close to monodisperse particles. The reactive thiol group acts as a site of formation of the block copolymer, that is, polystyrene-b-P(VAc/VA), which is utilized as an effective dispersant. From the measurement on molecular weights during the course of polymerization, two polymerization loci were realized. Addition of butyl methacrylate to styrene affected markedly not only rate of polymerization but also particle size. © 1996 John Wiley & Sons, Inc.     

2-氨基-6-羟基-3,5-二硝基吡啶的合成探索

2-氨基-6-羟基-3,5-二硝基吡啶(AHDNP)是合成聚对苯亚乙基吡啶并咪 二唑(PPIO)重要前体.本文以2,6-二氯吡啶为原料经单硝化、单氨解、再硝化先合成中间体2-氨基-6-氯-3,5-二硝基吡啶(ACDNP),纯度为95.60%,总收率41.00%以上;最后在K₂CO₃的碱性水溶液中70℃条件下单水解,成功合成出AHDNP,提纯后总收率为82.07%,纯度为98.13%.AHDNP的结构经过FT-IR、MS、¹³C NMR 准确定性和表征.合成过程操作方便、产品质量优异、经济性良好及易于产业化,为进一步研发合成新型高性能材料PPIO及其新单体提供技术基础及中间体来源.     

Reduction and unusual recovery in the reversible hydrogen storage capacity of V1−xTix during hydrogen cycling

The effect of the vanadium content on the cyclic stability of V–Ti binary alloys was investigated. V_1−xTi_x, x = 0.2 and 0.5 samples were hydrogenated and dehydrogenated at 410 K and 553 K respectively, for more than 100 times. During hydrogen cycling, reduction in the reversible hydrogen storage capacity was clearly observed from both samples. No prominent V-effect was found. In fact, the reduction rates of two samples were similar; both samples showed a ∼25% reduction in the reversible hydrogen storage capacity after 100 cycles. In addition, the shape of the pressure–composition-isotherm (PCT) curves was significantly altered over the testing cycle period; the absorption and desorption plateaus got markedly inclined and the hysteresis became evidently smaller. We found that even after the hydrogen storage capacity of V_1−xTi_x was significantly reduced, at low enough temperature V_1−xTi_x was able to absorb hydrogen as much as it did at the first cycle. Furthermore, the reversible hydrogen storage capacity of V_0.8Ti_0.2 at 410 K was recovered to a certain degree after hydrogenating the sample at low temperatures.     

The development of pivot bearing with multiple degrees of freedom: 1st report: Prototype of pivot bearing with two degrees of freedom

This paper deals with the prototype of a new pivot bearing having two degrees of freedom. The idea of the pivot bearing is based on a continuous velocity joint (CVJ). The experimental axial stiffness and contact pressure are compared with those determined by theoretical analysis. Then, it is confirmed that the pivot bearing swings smoothly with a range of ±25°. Furthermore, the stiffness of the bearing increases as the swinging angle becomes larger. Therefore, this newly developed pivot bearing may be applied to a parallel mechanism, a joint of robot and so on.     

Group behavior of agents with an emotional model

Recently, there has been much interest in the study of the formation of groups of agents that cause interactions between agents and invent new functions. We gave some agents an action rule based on the interactions of human feelings by using a circumplex model. It had been decided that the parameters of feelings in this model should have only two axes. In this report, eight basic action dimensions and pure feelings on four corresponding axes were given to agents as a model of feelings and actions based on the multiple factor analysis theory of R. Plutchik, and the behavioral characteristics of the group of agents were examined.