钒氮微合金化高强度钢的研究及应用

根据国内外钒氮合金微合金化技术的发展状况,综述了钒氮微合金化的优越性和在高强度钢中的强化机制,并概述了钒氮微合金化在高强度钢中的研究开发和应用状况。     

Chevrel Phase Mo6T8 (T = S,Se) as Electrodes for Advanced Energy Storage

With the large‐scale applications of electric vehicles in recent years, future batteries are required to be higher in power and possess higher energy densities, be more environmental friendly, and have longer cycling life, lower cost, and greater safety than current batteries. Therefore, to develop alternative electrode materials for advanced batteries is an important research direction. Recently, the Chevrel phase Mo₆T₈ (T = S, Se) has attracted increasing attention as electrode candidate for advanced batteries, including monovalent (e.g., lithium and sodium) and multivalent (e.g., magnesium, zinc and aluminum) ion batteries. Benefiting from its unique open crystal structure, the Chevrel phase Mo₆T₈ cannot only ensure rapid ion transport, but also retain the structure stability during electrochemical reactions. Although the history of the research on Mo₆T₈ as electrodes for advanced batteries is short, there has been significant progress on the design and fabrication of Mo₆T₈ for various advanced batteries as above mentioned. An overview of the recent progress on Mo₆T₈ electrodes applied in advanced batteries is provided, including synthesis methods and diverse structures for Mo₆T₈, and electrochemical mechanism and performance of Mo₆T₈. Additionally, a briefly conclusion on the significant progress, obvious drawbacks, emerging challenges and some perspectives on the research of Mo₆T₈ for advanced batteries in the near future is provided.     

Phosphorus and phosphide nanomaterials for sodium-ion batteries

Sodium-ion batteries have received remarkable attention as next-generation high-performance electrochemical energy storage devices because of their cost effectiveness and the broad geographical distribution of sodium. As a critical component of sodium-ion batteries, anode materials, especially nanostructured anodes, have a significant effect on the electrochemical performance of sodium-ion batteries. Recent research indicates that phosphorus and metal phosphides show great promise as anode candidates for sodium-ion batteries because of their low cost and relatively high theoretical gravimetric and volumetric specific capacities. In this review, we systematically summarize recent research progress on state-of-the-art nanostructured phosphorus and phosphides, including the synthetic strategies, Na-storage mechanisms, and the relationship between the nanostructure and electrochemical performance. Moreover, we present an overview of future challenges and opportunities based on current developments.

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次同步谐振的机—电联合仿真方法

为了克服传统次同步谐振机电耦合仿真中仅采用简化的集中质块轴系模型而不能获取机组轴系细节扭矩动态的缺陷,设计了基于PSCAD和ANSYS软件的机—电联合仿真方法,建立了新的耦合机制,通过数据通信实现了两个软件间转速和转矩等接口信息的交换,从而可用复杂的连续质块模型替代原有的简化质块模型,使机电耦合动态分析更加完整和严谨,进而为深入的疲劳分析提供了基础数据。对印度某电厂机组出现的次同步谐振问题进行了实例分析,获得了轴系特定轴段的动态扭矩响应,验证了方法的可行性和有效性。     

锂离子电池安全添加剂的研究进展

锂离子电池具有高能量密度和良好的循环性能,是目前最为理想的动力电源储能体系。然而,由于大容量和高功率锂离子电池技术尚未成熟,存在安全隐患,导致其商业化应用受到了很大程度的限制。锂离子电池的安全问题主要有机械力破坏、异常充电、气体积聚和热失控等,本文分析了上述危险因素产生的原因以及抑制的方法。在这些增强电池安全性的方法中,使用安全添加剂是最为经济有效的手段,但要在电解液中找到一种对电池具有高安全性能且不牺牲其他性能的实用添加剂并不容易,未来同时具备多功能的添加剂将会是对电池性能提升最有希望的研究方向。本文分析了成膜添加剂、阻燃添加剂和防过充添加剂的作用机理,并对相关领域的发展方向进行了展望。     

锥齿轮测量新方法的误差分析

针对作者提出的一种新测量方法——通过一种特殊测量齿轮和被测量齿轮啮合来测量齿轮的误差，分析了由于该特殊测量齿轮而引起的测量系统误差，并对其进行补偿；同时针对该测量方法提出了新的误差表示方法——把误差表示为实际齿轮齿面上的点相对于理论齿面上的点的法向偏移量，该方法所表示的误差包含了锥齿轮所有误差信息。实验证明了该方法的可靠性。     

微小齿轮测量技术的现状与发展

综述了微小齿轮测量技术及其测量仪器的研究现状,分析了微小齿轮高效测量领域的关键技术,并展望了将整体误差测量技术用于微小齿轮测量的可能性。     

硫磺湿法成型过程中细粉硫生成率控制技术研究

普光天然气净化厂硫磺湿法成型机在生产过程中,成品硫磺颗粒中夹带了大量细粉硫。细粉硫粒径过小,在成型工艺循环水中富集后,将导致振动筛、水槽、冷却塔填料堵塞等问题,同时引起硫磺产品含水率升高。通过实验模拟液硫湿法成型过程,得出成型盘孔径和液硫入水高度是影响细粉硫生成率的关键因素,并提出在成型盘孔径为2.1mm、液硫入水高度为2cm时,细粉硫生成率最低,可为国内同类硫磺湿法成型装置降低细粉硫生成率提供参考。     

Nitrogen‐Doped Graphene Ribbon Assembled Core–Sheath MnO@Graphene Scrolls as Hierarchically Ordered 3D Porous Electrodes for Fast and Durable Lithium Storage

Graphene scroll is an emerging 1D tubular form of graphitic carbon that has potential applications in electrochemical energy storage. However, it still remains a challenge to composite graphene scrolls with other nanomaterials for building advanced electrode configuration with fast and durable lithium storage properties. Here, a transition‐metal‐oxide‐based hierarchically ordered 3D porous electrode is designed based on assembling 1D core–sheath MnO@N‐doped graphene scrolls with 2D N‐doped graphene ribbons. In the resulting architecture, porous MnO nanowires confined in tubular graphene scrolls are mechanically isolated but electronically well‐connected, while the interwoven graphene ribbons offer continuous conductive paths for electron transfer in all directions. Moreover, the elastic graphene scrolls together with enough internal voids are able to accommodate the volume expansion of the enclosed MnO. Because of these merits, the as‐built electrode manifests ultrahigh rate capability (349 mAh g^?1 at 8.0 A g^?1; 205 mAh g^?1 at 15.0 A g^?1) and robust cycling stability (812 mAh g^?1 remaining after 1000 cycles at 2.0 A g^?1) and is the most efficient MnO‐based anode ever reported for lithium‐ion batteries. This unique multidimensional and hierarchically ordered structure design is believed to hold great potential in generalizable synthesis of graphene scrolls composited with oxide nanowires for mutifuctional energy storage.