Osmotic Dehydration of Tomato in Sucrose Solutions: Fick's Law Classical Modeling

ABSTRACT:  Osmotic dehydration of tomato was modeled by the classical Fick's law including shrinkage, convective resistance at the interface and the presence of water bulk flow. Tomato slices having 8 mm thickness were osmotically dehydrated in sucrose solutions at 50, 60, and 70 °Brix and at 35, 45, and 55 °C. Other experiments were done in a 70 °Brix sucrose solution at 35 °C with tomato slices of 4, 6, and 8 mm thickness and at different motion levels (velocities 0, 0.053, and 0.107 m/s). Tomato weight, water content, and °Brix of the products were measured as a function of processing time (20, 40, 80, 160, and 320 min). Results showed that temperature, concentration, thickness, and solution movement significantly influenced water loss and sucrose gain during the osmotic dehydration of tomato. The model predicted the modifications of soluble solid content and water content as a function of time in close agreement with the experimental data. Experimental Sherwood number correlations for sucrose and water were determined as Sh _s = 1.3 Re ^0.5 Sc _s^0.15 and Sh _w = 0.11 Re ^0.5 Sc _w^0.5, respectively. The effective diffusion coefficients of water (4.97 10⁻¹¹– 2.10 10⁻¹⁰ m²/s) and sucrose (3.18 10⁻¹¹– 1.69 10⁻¹⁰ m²/s) depended only on temperature through an Arrhenius-type relationship.     

Postharvest Ripening Characterization of Greenhouse Tomatoes

The determination of °Brix, pH, titratable acidity and antioxidant composition such as β-carotene, lycopene, and vitamin C was done in greenhouse “Savoura” tomatoes during maturation. The chromatic values L*, a*, b* were determined at the top surface of the tomato, and its strength-deformation curve was tested with a texturometer. Results pointed out that °Brix and titratable acidity did not change during postharvest, while β-carotene, lycopene, and vitamin C contents increased continuously toward the red stage of tomato. The colour values L*, a*, b*, and ratio a*/b* had a good correlation with the maturity stages. Also, a high correlation between lycopene content and (a*/b*) ratio was found, which was well represented with a second order polynomial function (r² = 0.95). This equation permits to appropriately estimate lycopene content of tomato as a function of its color, without any chemical analysis. During ripening, tomato texture changed from firm turgid to soft and the puncture deformation degree increased. Tomato firmness and chromatic values had a good correlation, and the lycopene content was a logarithm function of firmness (r² = 0.81). The strength in puncture test increased linearly with deformation until the bioyield point. The measured force was analyzed as the sum of the compression and the shear forces. The two force coefficients can be considered as tomato properties, independent of the puncture probe. These coefficients were found to decrease during tomato maturation.