Air–steam leakage through cracks in concrete walls

In the context of a severe accident in a PWR nuclear plant, the evaluation of the leakage through the containment wall remains a key point of the safety analysis. Here we calculate the leakage of an air steam mixture through a traversing crack taking into account condensation. A 40 h test has been performed on a representative concrete slab with measurements of crack openings and flow rates. The CAST3M code enables us to simulate this test by making thermo-mechanical calculations and calculation of the leakage flow rate. Thermo-mechanical calculations provide data needed by the leakage calculations which are not measurable in the experiment. These are the internal crack profiles (variation of the opening with the curvilinear coordinate of the crack inside the concrete slab). Thermo-mechanical calculations are difficult to perform because boundary conditions of the test are complicated. Leakage calculations are performed with various hypotheses for the internal cracks profiles. A coefficient is applied on the friction factor to take into account additional complexity of the crack geometry.     

Energy and resources as production factors in process industries

It is shown that, when the mean productivity of some factors, such as energy or materials, is upperly bounded (a condition usually arising in energy production or in the process industries where energy takes part in physico-chemical processes), the production function may not be convex and, under some further conditions, is concave. Consequences of this model on the economics of energy savings are examined, and it is shown that energy savings may be considered at three levels: in the short run, by action on labour factors: in the medium run, by investment and action on labour factors; in the long run, by technological innovation, investment in new technologies and action on labour factors. Empirical findings along these lines are thus confirmed.     

Plastic flow of polypropylene (PP) and PP-based blend

The evolution with temperature of the deformation mechanisms responsible for yielding in polypropylene (PP) and a PP-based blend is correlated to the molecular mobilities associated to glass transitions processes occurring in these materials. It is shown that the elementary local deformation event remains the same throughout the whole temperature range and that the onset of mobility only affects the average internal stress field \(\bar \sigma \) _i in which this thermally activated event takes place.     

A study of the apparatus function of a grid Fabry-Perot interferometer used as a F.I.R. spectrometer: Computing of the spectrum

Influences of various parameters on the apparatus function of a F.I.R. grid Fabry-Perot spectrometer are analysed. A pseudo-deconvolution method allowing an improvement of experimental results is tested by simulation and then applied to data concerning the isotopic HCl doublet at 41 cm^?1.     

Structures and morphologies of cast and plastically strained polyamide 6 films as evidenced by confocal Raman microspectroscopy and atomic force microscopy

Both confocal Raman microspectroscopy and atomic force microscopy (AFM) have been undertaken to study the crystalline and the morphological aspects of cast PA 6 films at a sub-microscopic scale. The percentages of the different crystalline structures present within PA 6 cast films, i.e. the monoclinic α, the pseudo-hexagonal β, and the monoclinic γ, have been measured by confocal Raman microspectroscopy. In cast films, the prevailing structure is the β one. AFM has been used to characterize the morphology of the PA 6 films. Simultaneously, the deformed state has been considered as well. Our main interest has been to follow the evolution of the percentage of each crystalline structure as a function of the plastic deformation mechanisms which are responsible of the yielding of PA 6 films: shear banding for temperatures T lower than 160 °C and formation of fibrils for      

An efficient and generic extension to ITK to process arbitrary shaped regions of interest

The paper describes a software method to extend ITK (Insight ToolKit, supported by the National Library of Medicine), leading to ITK++. This method, which is based on the extension of the iterator design pattern, allows the processing of regions of interest with arbitrary shapes, without modifying the existing ITK code. We experimentally evaluate this work by considering the practical case of the liver vessel segmentation from CT-scan images, where it is pertinent to constrain processings to the liver area. Experimental results clearly prove the interest of this work: for instance, the anisotropic filtering of this area is performed in only 16 s with our proposed solution, while it takes 52 s using the native ITK framework. A major advantage of this method is that only add-ons are performed: this facilitates the further evaluation of ITK++ while preserving the native ITK framework.     

Experimental Evidence for Seed Metabolic Allometry in Barrel Medic (Medicago truncatula Gaertn.)

Seed size is often considered to be an important trait for seed quality, i.e., vigour and germination performance. It is believed that seed size reflects the quantity of reserve material and thus the C and N sources available for post-germinative processes. However, mechanisms linking seed size and quality are poorly documented. In particular, specific metabolic changes when seed size varies are not well-known. To gain insight into this aspect, we examined seed size and composition across different accessions of barrel medic (Medicago truncatula Gaertn.) from the genetic core collection. We conducted multi-elemental analyses and isotope measurements, as well as exact mass GC–MS metabolomics. There was a systematic increase in N content (+0.17% N mg⁻¹) and a decrease in H content (–0.14% H mg⁻¹) with seed size, reflecting lower lipid and higher S-poor protein quantity. There was also a decrease in ²H natural abundance (δ²H), due to the lower prevalence of ²H-enriched lipid hydrogen atoms that underwent isotopic exchange with water during seed development. Metabolomics showed that seed size correlates with free amino acid and hexoses content, and anticorrelates with amino acid degradation products, disaccharides, malic acid and free fatty acids. All accessions followed the same trend, with insignificant differences in metabolic properties between them. Our results show that there is no general, proportional increase in metabolite pools with seed size. Seed size appears to be determined by metabolic balance (between sugar and amino acid degradation vs. utilisation for storage), which is in turn likely determined by phloem source metabolite delivery during seed development.     

Kinetic study of hydrogen sulfide absorption in aqueous chlorine solution

Hydrogen sulfide (H₂S) is currently removed from gaseous effluents by chemical scrubbing using water. Chlorine is a top-grade oxidant, reacting with H₂S with a fast kinetic rate and enhancing its mass transfer rate. To design, optimize and scale-up scrubbers, knowledge of the reaction kinetics and mechanism is requested. This study investigates the H₂S oxidation rate by reactive absorption in a mechanically agitated gas–liquid reactor. Mass transfer (gas and liquid sides mass transfer coefficients) and hydrodynamic (interfacial area) performances of the gas–liquid reactor were measured using appropriated physical or chemical absorption methods. The accuracy of these parameters was checked by modeling the H₂S absorption in water without oxidant. A sensitivity analysis confirmed the robustness of the model. Finally, reactive absorption of H₂S in chlorine solution for acidic or circumneutral pH allowed to investigate the kinetics of reaction. The overall oxidation mechanism could be described assuming that H₂S is oxidized irreversibly by both hypochlorite anion ClO⁻ (k = 6.75 × 10⁶ L mol⁻¹ s⁻¹) and hypochlorous acid ClOH (k = 1.62 × 10⁵ L mol⁻¹ s⁻¹).