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排序方式: 共有623条查询结果,搜索用时 406 毫秒
1.
Jean-Louis Havet Myriam Billiau-Loreau Catherine Porte Alain Delacroix 《Journal of Automated Methods and Management in Chemistry》2002,24(4):111-119
Chemometric tools were used to generate the modelling of solvent e inverted exclamation markects on the N-alkylation of an isocyanuric acid salt. The method proceeded from a central composite design applied on the Carlson solvent classification using principal components analysis. The selectivity of the reaction was studied from the production of different substituted isocyanuric derivatives. Response graphs were obtained for each compound and used to devise a strategy for solvent selection. The prediction models were validated and used to search for the best selectivity for the reaction system. The solvent most often selected as the best for the reaction is the N,N-dimethylformamide. 相似文献
2.
3.
Jean-Louis Iehl Rodolphe Grac Luc le Gratiet Véronique Bardinal Rainer Buhleier Elena Bedel-Pereira Chantal Fontaine Michel Pugnet Jacques-Henry Collet 《电信纪事》1997,52(11-12):627-637
We study the transient gratings photogenerated in the picosecond regime in three families of structures, namely : - structures of thickness in the order of one micron, including quantum wells (GaAs/GaAlAs, CdTe/ CdZnTe). A transmission modulation due to the electric field has been observed. We show that, in accordance with our calculations, this modulation is screened faster than 10 ps at a fluence of a few µJ/cm2. - A structure including GalnAs/GalnAsP MQWS in a cavity. This structure shows a top diffraction efficiency of 2.5 × 10-2 at 1.55 µm for an energy of excitation in the order of 100 µJ/cm2. The diffraction efficiency exhibits several oscillations due to Fabry-Pårot effects. By introducing cavity effects in our model, we show that the diffraction efficiency is amplified by more than a factor 2 with respect to the no-cavity case. Calculations show that the diffraction efficiency may reach 6 × 10-2 around 1.625 µm, for a front mirror reflectivity of 90 %. - Structures including bulk GaAs microcavities. The risetime is lower or in the order of 1 ps while the diffraction efficiency attains 1 %, with an average power of 4 mW (i.e. an energy of 2 µJ/cm2/pulse), compatible with a commutation of packets at 80 MHz. 相似文献
4.
JY Cesbron H Agut B Gosselin D Candotti M Rapha?l F Puech M Grandadam P Debré A Capron B Autran 《Canadian Metallurgical Quarterly》1994,317(7):669-674
HIV induces a multi-organ infection with a dual tropism for both lymphocytes and monocytes/macrophages. The lung is a target both for HIV infection and HIV-related opportunistic infections. The SCID mouse has provided the opportunity to develop a small animal model for HIV infection. However, HIV-1 infection of the human fetal thymus and liver (SCID Liv/Thy) implanted in these mice occurred only after direct intraimplant injection of HIV-1 and the resultant HIV-1 infection was restricted to the human thymus. Here we report that human foetal lung can develop in SCID Liv/Thy mice resulting in the development of normal human alveolar and bronchiolar lung compartments which can be productively infected with cell-free HIV-1 virus, leading to a systemic and bifocal infection. This SCID-Hu model should be useful for studying AIDS physiopathology, human viruses with lung tropism and for helping to define gene therapy protocols in lung human cells in vivo. 相似文献
5.
Routing and wavelength assignment of scheduled lightpath demands 总被引:4,自引:0,他引:4
Kuri J. Puech N. Gagnaire M. Dotaro E. Douville R. 《Selected Areas in Communications, IEEE Journal on》2003,21(8):1231-1240
We present algorithms that compute the routing and wavelength assignment (RWA) for scheduled lightpath demands in a wavelength-switching mesh network without wavelength conversion functionality. Scheduled lightpath demands are connection demands for which the setup and teardown times are known in advance. We formulate separately the routing problem and the wavelength assignment problem as spatio-temporal combinatorial optimization problems. For the former, we propose a branch and bound algorithm for exact resolution and an alternative tabu search algorithm for approximate resolution. A generalized graph coloring approach is used to solve the wavelength assignment problem. We compared the proposed algorithms to an RWA algorithm that sequentially computes the route and wavelength assignment for the scheduled lightpath demands. 相似文献
6.
7.
M. Bravin O. Buu A.C. Forbes S.A.J. Wiegers L. Puech P.E. Wolf 《Journal of Low Temperature Physics》1998,110(1-2):375-380
We present T
1
measurements performed in liquid and solid
3
He confined in sintered silver. In the liquid case, we find a close to linear relationship between T
1
and the applied magnetic field, similar to other (non metallic) systems, and up to higher frequencies (corresponding to 11 T) than previously reported. In the solid, the relaxation rate is found to increase spectacularly at large polarizations, which may indicate a polarization dependence of the exchange motion.
Now atNow at 相似文献
8.
L. Puech J. -M. Mignot P. Lejay P. Haen J. Flouquet J. Voiron 《Journal of Low Temperature Physics》1988,70(3-4):237-251
Low-temperature magnetostriction experiments have been performed on CeRu2Si2 single crystals in magnetic fields up to 15T. WhenH is applied parallel to the tetragonalc-axis, a very large expansion is observed in all lattice directions. A pronounced anomaly occurs at a field close to the metamagnetic threshold. The results are discussed with use of thermodynamic relations and support a very simple scaling behavior for the pressure dependence of the magnetization.Laboratoire associé à l'Université Scientifique, Technologique et Médicale de Grenoble. 相似文献
9.
Under reasonable assumptions, we show that He-filled Aerogels should exhibit a strong negative thermal expansion at the point : =–10–3/K. We observed an expansion smaller than 10–6/K across the transition. This very strong discrepancy can be related either to (i) specific elastic properties of the gels, (ii) the dependance of T on the pore size is drastically different of what could be expected. 相似文献
10.
Gruffat D De La Torre A Chardigny JM Durand D Loreau O Sébédio JL Bauchart D 《Lipids》2003,38(2):157-163
Hepatic metabolism of the two main isomers of CLA (9cis-11 trans, 10trans-12cisC18∶2) was compared to that of oleic acid (representative of the main plasma FA) in 16 rats by using the in vitro method of incubated liver slices. Liver tissue samples were incubated at 37°C for 17h under an atmosphere of 95% O2/5%CO2 in a medium supplemented with 0.75 mM of FA mixture (representative of circulating nonesterified FA) and with 55 μM [1-14C]9cis-11 trans C18∶2, [1-14C]10trans-12cis C18∶2, or [1-14C]oleate. The uptake of CLA by hepatocytes was similar for both isomers (9%) and was three times higher (P<0.01) than for oleate (2.6%). The rate of CLA isomer oxidation was two times higher (49 and 40% of incorporated amounts of
9cis-11 trans and 10trans-12 cis, respectively) than that of oleate (P<0.01). Total oxidation of oleate and CLA isomers into [14CO2] was low (2 to 7% of total oxidized FA) compared to the partial oxidation (93 to 98%) leading to the production of [14C] acid-soluble products. CLA isoemrs escaping from catabolism were both highly desaturated (26.7 and 26.8%) into conjugated
18∶3. Oleate and CLA isomers were mainly esterified into neutral lipids (30%). They were slowly secreted as parts of VLDL
particles (<0.4% of FA incorporated into cells), the extent of secretion of oleate and of 10trans-12 cis being 2.2-fold higher than that of 9cis-11 trans (P<0.02). In conclusion, this study clearly showed that both CLA isomers were highly catabolized by hepatocytes, reducing their
availability for peripheral tissues. Moreover, more than 25% of CLA escaping from catabolism was converted into conjugated
18∶3, the biological properties of which remain to be elucidated. 相似文献