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1.
The motional transition and heterogeneity of semi‐interpenetrating networks (SIPNs) based on polyurethane (PU) with carboxylic groups and methacrylic copolymer (PM) with tertiary amine groups were studied by the electron spin resonance (ESR) spin probe method. The concentration of functional groups in both prepolymers varied from 0 to 0.45 mmol g?1. Spin‐probed SIPNs show that the temperature‐dependent spectra are sensitive to polymer interactions imposed by functional groups. These interactions determine the free volume distribution in the matrix and temperature at which motional transition takes place. The fraction of free volume increases with functional group concentration and reaches its maximum at 0.25 mmol g?1. Further increases in the functional group concentration reduce the free volume. The results of the networks with strong interactions are discussed in terms of the interference of the plasticizing effect of the PU component and the formation of possible cluster cross‐links, which restricts segmental motions. Copyright © 2003 Society of Chemical Industry 相似文献
2.
Stanisic B.R. Verghese N.K. Rutenbar R.A. Carley L.R. Allstot D.J. 《Solid-State Circuits, IEEE Journal of》1994,29(3):226-238
This paper describes new techniques for the simulation and power distribution synthesis of mixed analog/digital integrated circuits considering the parasitic coupling of noise through the common substrate. By spatially discretizing a simplified form of Maxwell's equations, a three-dimensional linear mesh model of the substrate is developed. For simulation, a macromodel of the fine substrate mesh is formulated and a modified version of SPICE3 is used to simulate the electrical circuit coupled with the macromodel. For synthesis, a coarse substrate mesh, and interconnect models are used to couple linear macromodels of circuit functional blocks. Asymptotic Waveform Evaluation (AWE) is used to evaluate the electrical behavior of the network at every iteration in the synthesis process. Macromodel simulations are significantly faster than device level simulations and compare accurately to measured results. Synthesis results demonstrate the critical need to constrain substrate noise and simultaneously optimize power bus geometry and pad assignment to meet performance targets 相似文献
3.
4.
In the initial part the change of microstructure for steel X20 CrMoV 121 is discussed in terms of the distribution of carbide precipitates and its effects on accelerated creep resistance and hardness are presented. In the following, experimental results of microstructure and accelerated creep resistance are presented for the steels X20CrMoV 121 and P91 annealed for up to 8760 hours at 650°C and 750°C before the testing. A similar evolution of the distribution of carbide particles of a size above 102 nm is found for both steels, while the accelerated creep resistance is diminished much stronger for the steel X20CrMoV 121. This difference is due to a greater stability of NbC than that of VC precipitates, both related to the evolution of the chemical composition of complex chromium, molybdenum and iron carbide particles. 相似文献
5.
Because a study of the results reported for the chain dimensions of polydimethylsiloxane (PDMS), critical for the onset of this polymer's non-Newtonian flow behavior, obtained from the viscosity-molecular weight relationships available from the literature, clearly revealed that considerable differences exist between the reported data, a detailed analysis of these data was performed together with an additional examination of 10 new PDMS samples that were selected so as to have molecular weights that would fill the gaps observed in the polymer viscosity–chain length relationship constructed from the accepted literature data. The results obtained were analyzed by using several different procedures integrated into a recently described comparative method that could allow for determination of what is called the most realistic critical value, Zwc. The latter was determined as 930 PDMS main-chain atoms, which corresponds to this polymer's degree of polymerization of 464.5 and the weight-average molecular weight of 34,500. It is not only shown that after elimination of some clearly erroneous data points from the previously reported relationships the obtained critical chain-length values could very well fit the earlier relationships, but also that appropriate “master” relationships were constructed including 48 pairs of the old and 10 pairs of the new data points. It is suggested that this relationship be accepted as the best-fit viscosity–polymer chain-length dependence for PDMS, and it is pointed out that the obtained PDMS critical chain-length value ranks this polymer's macromolecules as the most flexible of the corresponding long-chain molecules presently known. © 1993 John Wiley & Sons, Inc. 相似文献
6.
Polystyrene-block-polybutadiene copolymers (SB) with 0.5 mass fraction of styrene were studied by electron spin resonance (ESR) of nitroxide spin probes. The influence of the block length (
and
) and the solvation power of casting solvents on the motional dynamics of spin probe were measured over a wide temperature range. Two nitroxide radicals as spin probes were selected: 2,2,6,6-tetramethyl-4-hydroxypiperidine-1-oxyl benzoate (BzONO) and 2,2,6,6-tetramethyl-4-hydroxypiperidine-1-oxyl (Tempol). Irrespective of the spin probe used two ESR spectral components differing in their motional properties above the phase transition of polybutadiene blocks (PB) were observed. The fast component was assigned to spin probes located in polybutadiene-rich domains and the slow component to spin probes in polystyrene-rich domains. The range of two spectral components and the phase transition of the slow ESR component, T5mT, depend on the block length. The influence of the interphase and accumulation of free volume in the interphase on the Tempol probe motion was investigated by changing copolymer morphology in the films casted from selective and nonselective solvents. The analysis of the motional heterogeneity from the ratio of the fast and slow motional component presents evidence that in the selective solvent for polystyrene (PS) blocks (2-butanone) the most irregular structure with a large interphase is formed. The difference in fast motion of spin probes indicates that the motional dynamic is related to the change of domain structure. 相似文献
7.
Jeanne Volatron Florent Carn Jelena Kolosnjaj‐Tabi Yasir Javed Quoc Lam Vuong Yves Gossuin Christine Ménager Nathalie Luciani Gaëlle Charron Miryana Hémadi Damien Alloyeau Florence Gazeau 《Small (Weinheim an der Bergstrasse, Germany)》2017,13(2)
Proteins implicated in iron homeostasis are assumed to be also involved in the cellular processing of iron oxide nanoparticles. In this work, the role of an endogenous iron storage protein—namely the ferritin—is examined in the remediation and biodegradation of magnetic iron oxide nanoparticles. Previous in vivo studies suggest the intracellular transfer of the iron ions released during the degradation of nanoparticles to endogenous protein cages within lysosomal compartments. Here, the capacity of ferritin cages to accommodate and store the degradation products of nanoparticles is investigated in vitro in the physiological acidic environment of the lysosomes. Moreover, it is questioned whether ferritin proteins can play an active role in the degradation of the nanoparticles. The magnetic, colloidal, and structural follow‐up of iron oxide nanoparticles and proteins in lysosome‐like medium confirms the efficient remediation of potentially harmful iron ions generated by nanoparticles within ferritins. The presence of ferritins, however, delays the degradation of particles due to a complex colloidal behavior of the mixture in acidic medium. This study exemplifies the important implications of intracellular proteins in processes of degradation and metabolization of iron oxide nanoparticles. 相似文献
8.
The paper describes JessGUI, a graphical user interface developed on top of the Jess expert system shell. The central idea of the JessGUI project was to make building, revising, updating, and testing Jess-based expert systems easier, more flexible, and more user friendly. There are many other expert system building tools providing a rich and comfortable integrated development environment to expert system builders. However, they are all either commercial or proprietary products. Jess and JessGUI are open-source freeware, and yet they are well suited for building even complex expert system applications, both stand-alone and Web-based ones. An important feature of JessGUI is its capability of saving knowledge bases in XML format (in addition to the original Jess format), thus making them potentially easy to interoperate with other knowledge bases on the Internet. Jess and JessGUI are also used as practical knowledge engineering tools to support both introductory and advanced university courses on expert systems. The paper presents design details of JessGUI, explains its links with the underlying Jess knowledge representation and reasoning tools, and shows examples of using JessGUI in expert system development. It also discusses some of the current efforts in extending Jess/JessGUI in order to provide intelligent features originally not supported in Jess. 相似文献
9.
In this paper, an approximation of the optimal compressor function using the quadratic spline functions with 2L?=?8 segments is described. Since the quadratic spline with 2L?=?8 segments provides better approximation of the optimal compression function than quadratic spline with 2L?=?4 segments, capitalizing on the benefits of the obtained spline approximation, quantizer designing process is firstly performed for the so assumed number of segments and the Laplacian source of a unit variance. Then, to enhance the usability of the proposed model, the switched quantization technique is applied and a beneficial analysis is derived, providing insight in the robustness of the proposed quantizer performances with respect to the mismatch in designed for and applied to variances. Reached quality has been compared to another model from the literature, and it has been shown that the proposed model outperforms the previous model by almost 1.3?dB. 相似文献
10.
Effect of supercritical CO2 extraction process parameters on oil yield and pigment content from by‐product hemp cake 下载免费PDF全文
Krunoslav Aladić Senka Vidović Jelena Vladić Davor Balić Huska Jukić Stela Jokić 《International Journal of Food Science & Technology》2016,51(4):885-893
This research gives an insight into the possibility of exploiting the one of the food industry's by‐products – pressed hemp cake. The complete recovery of oil from pressed hemp cake was achieved. Residual oil that remained in cake after pressing was extracted with supercritical CO2 by applying different process parameters. Optimal extraction conditions were determined using response surface methodology. Total pigment contents of the oils obtained were determined. Extraction pressure had the most significant influence on yield and pigment content of extracted hemp cake oil. Depending on the pressure, the chlorophyll a content ranged from 101.11 to 378.28 mg kg?1 and chlorophyll b from 65.14 to 189.78 mg kg?1, while total carotene content was in the range from 33.58 to 132.67 mg kg?1. The remaining oil in pressed hemp cake after supercritical CO2 extraction was determined to be 0.56 ± 0.08% and the defatted cake was rich in proteins and fibre. 相似文献