全文获取类型
收费全文 | 126篇 |
免费 | 0篇 |
专业分类
电工技术 | 1篇 |
化学工业 | 49篇 |
金属工艺 | 3篇 |
能源动力 | 1篇 |
轻工业 | 10篇 |
石油天然气 | 5篇 |
无线电 | 9篇 |
一般工业技术 | 24篇 |
冶金工业 | 8篇 |
原子能技术 | 11篇 |
自动化技术 | 5篇 |
出版年
2024年 | 1篇 |
2022年 | 1篇 |
2021年 | 4篇 |
2019年 | 2篇 |
2018年 | 1篇 |
2016年 | 2篇 |
2015年 | 1篇 |
2014年 | 3篇 |
2013年 | 9篇 |
2012年 | 5篇 |
2011年 | 6篇 |
2010年 | 3篇 |
2009年 | 9篇 |
2008年 | 3篇 |
2007年 | 2篇 |
2006年 | 2篇 |
2005年 | 5篇 |
2004年 | 3篇 |
2003年 | 1篇 |
2000年 | 3篇 |
1999年 | 3篇 |
1998年 | 4篇 |
1997年 | 2篇 |
1996年 | 3篇 |
1991年 | 2篇 |
1990年 | 6篇 |
1989年 | 1篇 |
1988年 | 2篇 |
1987年 | 3篇 |
1986年 | 4篇 |
1985年 | 5篇 |
1984年 | 4篇 |
1983年 | 2篇 |
1982年 | 4篇 |
1981年 | 7篇 |
1980年 | 1篇 |
1979年 | 5篇 |
1978年 | 2篇 |
排序方式: 共有126条查询结果,搜索用时 15 毫秒
1.
Makoto Iida Masao Gotoh Hitoshi Yokono Yasushi Miyano 《Polymer Engineering and Science》1986,26(10):701-707
Flexural properties of moldings made by Reaction Injection Molding (RIM), which are structural foams consisting of high density skin and low density core, were investigated by three-point bending tests. Two failure modes were observed in bending tests of the moldings made by RIM, and they are classified as follows according to the density ratio of skin layer to core layer: the opposite side of the skin layer to which load was subjected failed by tensile stress: and the same side of the skin layer to which load was subjected failed by compressive stress, causing wrinkling or buckling. Then the conventional composite beam theory was applied to the former failure mode and Hoff s buckling theory to the latter, and equations were derived to predict the flexural properties of the structural foams, which involved buckling from the flexural properties of solid construction. In addition, it has been shown that there exists a density distribution that maximizes the flexural strength of the moldings made by RIM with a given overall density. The results obtained here should be useful to the optimum structural design of moldings made by RIM. 相似文献
2.
Masato Sakaguchi Tetsuro Yokono Yuzo Sanada Junkichi Shoma Hisatsugu Kashiwabara 《Fuel》1981,60(2):136-138
The ball-milling of coal with methylmethacrylate monomer was carried out under vacuum at 77 K and at room temperature and in air. The e.s.r. and i.r. spectra of ball-milled material showed that a copolymer of coal and methylmethacrylate was formed on the surfaces of coal created by ball-mining. Oxygen is an inhibitor to this process. 相似文献
3.
This study examines further the phenomena of the modification of coal carbonizations by organic additives. Anthracene, pyrene and chrysene modify the carbonization in a closed system of coking coals as observed from increases in the size of optical textures of resultant cokes. Weakly caking coals are unaffected. Chrysene is the most efficient modifier probably because of its lowest calculated free valence. The co-additives tetralin and hydrogenated anthracene oil further enhance the modification processes so obviating the necessity to use hydrogenated additives. Co-carbonizations of oxidized coking and caking coals with decacyclene are effective in removing the effects of mild oxidation. Increased rates of carbonization enhance the sizes of optical textures of resultant cokes. 相似文献
4.
High temperature, high pressure e.s.r. measurements of the hydrogenation reaction of Taiheiyo coal in the presence of catalysts were carried out to understand the stabilization of thermally and/or catalytically induced free radicals. A decrease in free radical concentration with increasing temperature was observed for ZnCl2 and SnCl2 · 2H2O catalysts at 10MPa under hydrogen gas. High pressure modified single-cell d.t.a. and p.d.a. equipment augmented the uniquely designed high temperature, high pressure e.s.r. cell. The hydrogenation reaction was monitored under the same experimental conditions as for e.s.r. From the results of the combination of high temperature, high pressure e.s.r. with high pressure d.t.a. and p.d.a., it was established that H2 molecules can react efficiently with free radicals from coal molecules created by the presence of ZnCl2 and SnCl2 · 2H2O catalysts. 相似文献
5.
To obtain fundamental information about hydrogen transfer, the relationships between hydrogen donor ability and chemical structure of model compounds representing donor solvents is studied using gas chromatography,1H n.m.r. and computing calculation methods. The order of the model compounds in terms of the ability as donor solvent to release hydrogen is: decalin < tetralin < 1,2-dihydronaphthalene < < 1,4-dihydronaphthalene. This trend closely correlates with the difference in binding energies of the hydroaromatic compounds and their radicals, determined by intermediate neglect of differential overlap (INDO) calculation. Electron spin resonance spectroscopy (e.s.r.) confirms that radical species are created after heat-treatment of the donor compounds. The ability of model compounds representing coal to accept hydrogen is assessed from a comparison of the1H n.m.r. spectra. It is established that donor and acceptor efficacies are dependent upon chemical structure. 相似文献
6.
Keitaro Enami 《Engineering Fracture Mechanics》2005,72(7):1089-1105
It has been recognized that ductility of prestrained steel is inferior to that without prestrain, and the critical equivalent plastic strain of ductile fracture initiation is inversely related to stress triaxiality. In this paper, the effects of compressive and tensile prestrain on ductile fracture initiation in steels are investigated quantitatively by adopting the relationship between stress triaxiality and critical equivalent plastic strain. It is found that compressive prestrain leads to cleavage cracking and reduces ductility. In the case of the TMCP steel, compressive prestrain up to 30% does not decrease the ductility, accompanied by no evidence of cleavage cracks. However, in the case of SM490B steel, 30% compressive prestrain leads to cleavage cracking and reduces ductility significantly. 相似文献
7.
Dr. Masanobu Nagano Takumi Oguro Ryo Sawada Dr. Toru Yoshitomi Prof. Keitaro Yoshimoto 《Chembiochem : a European journal of chemical biology》2021,22(23):3341-3347
Dysregulation of tumor necrosis factor-α (TNFα), a pro-inflammatory cytokine, causes several diseases, making it an important therapeutic target. Here, we identified a novel DNA aptamer against human TNFα using in vitro selection, which included a high exclusion pressure process against non-binding and weak binders through microbead-assisted capillary electrophoresis (MACE) in only three rounds. Among the 15 most enriched aptamers, Apt14 exhibited the highest inhibitory activity for the interaction between TNFα and its cognate receptor in mouse L929 cells. For further improving the bioactivity of the aptamer, dimerization programed by hybridization was evaluated, resulting in the Apt14 dimer exhibited a twofold higher binding affinity and stronger inhibition compared to the monomer counterpart. Rapid identification of bioactive aptamers using MACE in combination with facile dimerization by hybridization accelerates the discovery of novel bioactive aptamers, paving the way toward replacing current monoclonal antibody therapy with the less expensive and non-immunogenic aptamer therapy. 相似文献
8.
Based on the subsite structure of an α-amylase from Bacillus subtilis, production of glucose from a substrate maltohexaose in the amylase-catalyzed reaction was theoretically predicted as a function of time. The theoretical time course was found consistent with the experimental results, which were obtained by the determination of a product glucose with a commercial assay-kit. Hence, glucose, product from a substrate maltohexaose, will be a useful probe for the amylase-catalyzed reaction. 相似文献
9.
Using maltohexaose G6 as a substrate, a convenient analytical method for amylase-catalyzed hydrolytic reaction was developed by application of an enzymatic assay-kit (glucose oxidase-peroxidase) to measurement of glucose, produced on the reaction: G6→G5 + G. The initial velocity was confirmed to be proportional to the initial concentration of amylase, examined, ∼ 100 μm. The new method was found in a good correlation with the Nelson and Somogyi method. Rate assay was also examined: The initial velocity is proportional to the enzyme concentration, ∼ 30 μm. Hence, this enzymatic assay method is recognized to be convenient and useful for the measurement of α-amylase. 相似文献
10.
Masatake Ohnishi Atsuko Higuchi Setsuko Todoriki Keitaro Hiromi Wmikio Ohgushi Akiyoshi Wada 《Starch - St?rke》1990,42(7):273-276
Using the pH-jump (neutral to above 11) for Tyr-OH ionization as a probe, two glucoamylases from Rhizopus niveus and Rhizopus delemar were found to be caused the change in conformation, which is in a kinetically single step. The pH titration at pHs below 12 was carried out on a multidimensional correlation spectrophotometer. Correlations among the spectrophotometric properties: fluorescence, absorption and circular dichroism are almost identical for the two enzymes. These results suggest that conformational characteristics of the niveus enzyme is almost the same as that of the delemar one. 相似文献