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排序方式: 共有403条查询结果,搜索用时 15 毫秒
1.
Melt crystallization of isotactic polypropylene (iPP), containing crystallites of N,N′-dicyclohexyl-2,6-naphthalenedicarboxamide (DCNDCA) as a nucleating agent of the the β-phase iPP crystal, is carried out under a magnetic field (6 T) to obtain the alignment of the iPP crystal induced by magnetic alignment of DCNDCA. In a previous paper, DCNDCA was reported to undergo magnetic alignment in a liquid suspension. The obtained iPP sample exhibits alignment of the β-phase crystal with the c-axis aligned perpendicular to the magnetic field. The comparison of this alignment of iPP with the reported magnetic alignment of DCNDCA indicates that the β-phase crystal grows epitaxially on the DCNDCA crystal. The (330)β plane of the iPP crystal lies on the bc-plane of the DCNDCA crystal in which the direction of the c-axis of the iPP coincides with the direction of the b-axis of the DCNDCA crystal. 相似文献
2.
A film of polyamic acid is formed by vapor deposition polymerization of pyromellitic dianhydride (PMDA) and 4,4′-diaminodiphenyl ether (ODA). We have taken ESR spectrum during the polymerization process and compared it with the ESR spectrum of films obtained from solution polymerization. In the intermediate polymers during vapor deposition polymerization, the amide bond (? CONH? ) is coplanar with the benzene ring and two protons in the PMDA molecule. This intermediate polymer has one unpaired electron that interacts with the two nitrogen nuclei equally. On the other hand, in the polymer obtained by solution polymerization, the amide bond and the benzene ring of PMDA are not coplanar. In this polymer, too, some of the molecules have an unpaired electron that seems to have almost no coupling with NH groups. These results imply that the polymer formation via vapor deposition proceeds through different intermediates and different molecular configurations from that via the solution process. 相似文献
3.
4.
K Kohno JA Palha K Miyakawa MJ Saraiva S Ito T Mabuchi WS Blaner H Iijima S Tsukahara V Episkopou ME Gottesman K Shimada K Takahashi K Yamamura S Maeda 《Canadian Metallurgical Quarterly》1997,150(4):1497-1508
Amyloid fibrils derived from the Japanese, Portuguese, and Swedish types of familial amyloidotic polyneuropathy all consist of a variant transthyretin (TTR) with a substitution of methionine for valine at position 30 (TTR Met 30). In an attempt to establish an animal model of TTR Met-30-associated homozygous familial amyloidotic polyneuropathy and to study the structural and functional properties of human TTR Met 30, we generated a mouse line carrying a null mutation at the endogenous ttr locus (ttr-/-) and the human mutant ttr gene (6.0-hMet 30) as a transgene. In these mice, human TTR Met-30-derived amyloid deposits were first observed in the esophagus and stomach when the mice were 11 months of age. With advancing age, amyloid deposits extended to various other tissues. Because no significant difference was detected in the onset, progression, and tissue distribution of amyloid deposition between the ttr-/- and ttr+/+ transgenic mice expressing 6.0-hMet 30, endogenous normal mouse TTR probably does not affect the deposition of human TTR Met-30-derived amyloid in mice. TTR is a tetramer composed of four identical subunits that binds thyroxine (T4) and plasma retinol-binding protein. The introduction of 6.0-hMet 30 into the ttr-/- mice significantly increased their depressed serum levels of T4 and retinol-binding protein, suggesting that human TTR Met 30 binds T4 and retinol-binding protein in vivo. The T4-binding ability of human TTR Met 30 was confirmed by the analysis of T4-binding proteins in the sera of ttr-/- transgenic mice expressing 6.0-hMet 30. The T4-binding studies also demonstrated the presence of hybrid tetramers between mouse and human TTR subunits in the ttr+/+ transgenic mice expressing 6.0-hMet 30. 相似文献
5.
We observed electron-beam-induced sintering of amorphous silica in oxidized submicrometer silicon particles and analyzed the nature of mass transport in linear and triangular particle assemblies. The movement of silica around the rigid crystalline cores occurs rapidly and fills the necks, but the relative core positions in the sintered product depends on the initial geometry of the confined oxide. However, a thin layer of silica remains stable against the flow. 相似文献
6.
The state of water in water-swollen poly(vinyl alcohol-co-itaconic acid) membranes, having various water contents from 0.31 to 0.83, was investigated by d.s.c. measurements and compared with those in water-swollen poly(vinyl alcohol) membranes. The amount of freezing water in the membranes was estimated by use of a relationship between the phase transition temperature and the enthalpy of the crystallization of supercooled water. The melting temperature of the water in the membranes immersed in urea and NaCl 0–2 mol l?1 aqueous solutions was also determined by d.s.c. analysis. The present study proposes a method for estimating the solubilities of urea and NaCl in both of the freezing and the non-freezing water using the melting point depression of the freezing water in the membranes immersed in the solute solution. 相似文献
7.
Poly(ethylene phthalate) (PEP) and poly(ethylene phthalate–co‐ethylene terephthalate) were used to improve the brittleness of the cycloaliphatic epoxy resin 3,4‐epoxycyclohexylmethyl 3,4‐epoxycyclohexane carboxylate (Celoxide 2021?), cured with methyl hexahydrophthalic anhydride. The aromatic polyesters used were soluble in the epoxy resin without solvents and effective as modifiers for toughening the cured epoxy resin. For example, the inclusion of 20 wt % PEP (MW, 7400) led to a 130% increase in the fracture toughness (KIC) of the cured resin with no loss of mechanical and thermal properties. The toughening mechanism is discussed in terms of the morphological and dynamic viscoelastic behaviors of the modified epoxy resin system. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 388–399, 2002; DOI 10.1002/app.10363 相似文献
8.
Hoshiaki Iijima Osamu Taguchi Ken-Ichi Hirano 《Metallurgical and Materials Transactions A》1977,8(6):991-995
Interdiffusion coefficient
in cobalt-manganese alloys has been determined by Matano's method in the temperature range between 1133 and 1423 K on (pure
Co)-(Co-30.28 at. pct Mn alloy) and (pure Co)-(Co-51.76 at. pct Mn alloy) couples. This, ∼D, has been found to increase with the increase of manganese content. However, the activation energy (∼Q) and frequency factor (
0) show a maximum at about 10 at. pct Mn. The concentration dependence of
and
has been discussed taking into account the thermodynamic properties of the alloy. The difference in
between the ferro- and paramagnetic phases in Co-5 at. pct Mn alloy has been found to be 24 kJ/mol, which is larger, than
that for the diffusion of Mn54 in this alloy. Further it has been found that the Kirkendall marker moves toward manganese-rich side, showing that manganese
atoms diffuse faster than cobalt atoms. From the marker shift, the intrinsic diffusion coefficients,D
Co andD
Mn, at 33 at. pct Mn have been determined as follows:D
Co=0.22×10−4 exp(−263 kJ mol−1/RT) m2/s, andD
Mn=0.98×10−4 exp(−229 kJ mol−1/RT) m2/s. 相似文献
9.
T. Goto N. Wakamatsu H. Kamemizu M. Iijima Y. Doi Y. Moriwaki 《Journal of materials science. Materials in medicine》1991,2(3):149-152
The sintering mechanism of hydroxyapatite (HAp) by addition of lithium phosphate (Li3PO4) has been investigated. Using the X-ray diffraction method, HAp was confirmed to decompose into -Ca3(PO4)2 (-TCP) by addition of Li3PO4. The measurement of shrinkage rate by the isothermal firing made it clear that the densification process at the initial stage of sintering took place in the presence of liquid phase. Furthermore, the examination of the phase diagram on the binary system -TCP-Li3PO4 revealed that there was an eutectic point at 1010°C in the composition of 60 wt% Li3PO4. From these evidences, we concluded that -TCP produced by the decomposition of a part of HAp has formed the liquid phase by reacting with Li3PO4 above 1010°C, and that this liquid phase has largely promoted the densification by the rearrangement of HAp particles at the initial stage of sintering. 相似文献
10.
A method of leak detection, based on high-temperature resistant microphones, was originally developed in JNC to detect leakages with flow rates from 1 m3/h to 500m3/h. The development performed on Fugen is focused on detection of a small leakage at an early stage. Specifically, for the inlet feeder pipes the leak rate of 0.2gpm (0.046m3/h) has been chosen as a target detection capability. Evaluation of detection sensitivity was carried out in order to check the capability of the method to satisfy this requirement. The possibility of detecting and locating a small leakage has been demonstrated through the research. 相似文献