ADDUCT FORMATION OF β-DIKETONATO LANTHANOIDS(III) WITH CARBOXYLIC ACIDS HAVING HYDROXYL AND METHOXYL GROUPS

Adduct formation of 2-thenoyltrifluoroacetonato(tta) lantha-num(III), europium(III), and ytterbium(I II) with α-pheny 1 1 actic, α-methoxy phenyl acetic, salicylic, and o-methoxy benzoic acids in chloroform has been studied by solvent extraction technique. It has been found that 1anthanoid(111) chelates form more stable adducts with these carboxylic acids in the sequence: Yb(tta)₃ < Eu(tta) ₃ < La(tta) ₃. The adduct formation constants as well as the separation factors obtained as the ratio of the constants between a pair of metals are the largest for α-phenyl lactic acid among these acids. The characteristics with α-phenyl 1actic acid would be caused by the action as bidentate unlike benzoic acid derivatives which work as monodentates owing to the internal complexa-tion through hydrogen bonding.     

α-HYDROXYCARBOXYLIC ACID AS ADDUCT FORMING LIGAND FOR EXTRACTION OF LANTHANIDE(III)

Lanthanide(lII) chelates with 1,1,1 -trif luoro-5,5-dimethyl-2,4-hexanedione form adducts with benzilic acid, an a-hydroxycar-boxylic acid, in chloroform. The order of. the adduct formation constants in magnitude is: La^m> Eu^m> Yb^m although it is known that the stability constant of lanthanide(III) complexes with α-hydroxycarboxylic acids in aqueous solutions increases with increasing atomic number.     

Microstrip Band Pass Filter of GHz Region Employing Aerosol-Deposited Alumina Thick Films

The miniaturized 10 GHz microstrip band-pass filter was successfully fabricated on the alumina thick films grown on Cu substrates at room temperature by aerosol deposition method and using the newly developed pattern electroplating procedure and electromagnetic analysis. The relative dielectric permittivity and loss tangent of the aerosol-deposited alumina thick films on Cu were 9.9 and 0.089, respectively. The resistivity of the electroplated Cu line was determined to be 2 × 10^{? 8} Ω m. The very good agreement was shown between results simulated using a 3-dimensional electromagnetic analysis and the actual measured data.     

Lactic Acid Fermentation of Saccharified Solution from Rice Flour

For the preparation of a tasty fermented beverage from rice flour, suitable amylases and lactic acid bacteria were explored and selected. A glucoa-mylase from Rhizopus commercially named as gluczyme formed less reducing sugars from gelatinized rice flour than glucoamylase from As-pergillus. However, saccharified solution prepared by gluczyme was well utilized by a lactic acid bacterium isolated from a kefir, which is considered to be a bacterium closely related to Leuconostoc mesenteroides. The substances such as amino acids formed by some contaminating enzymes like protease in gluczyme are presumed to stimulate the growth of the kefir-bacterium and contribute to the formation of a favorable fermented beverage.