Model discrimination procedures are useful tools for selection of the best mathematical models to be used to represent a specific chemical process. The present paper presents and discusses a new sequential discrimination procedure, which makes use of model probabilities and concentrates the efforts on models with higher probabilities. Model probabilities are determined based on simple statistical arguments. Four numerical examples illustrate the application of the proposed discrimination procedure. The obtained results indicate that the new procedure is able to discriminate kinetic models with fewer experiments when compared to other procedures and also indicates when model discrimination is not possible and, thus, when the sequential design must be halted. Furthermore, the speed of the proposed discrimination procedure can be controlled by tuning a design parameter which reflects the analyst's mood (confidence) towards the discrimination problem and allows for increase or decrease of the number of experiments required for model discrimination during the sequential procedure. 相似文献
Mathematical simulation has been widely used in biomedical and biological sciences. In the case of the surface electromyographic (SEMG) activity, some models have been proposed aiming to study muscle contraction strategies that are used during different tasks and conditions. Most of SEMG simulators are based on energy modulation of a Gaussian noise. This work proposes a novel simulator in which the user-defined parameters are associated with the motor units (MUs) recruitment and their firing rate. Comparison between the mean spectrum of real SEMG signals collected in isometric contraction of the muscle biceps brachii and the mean spectrum obtained from simulated SEMG signals showed a good agreement, pointing the proposed simulator seems to be capable to generate consistent electromyographic signals in time and frequency domains and that can be used in many studies, in particular in the evaluation of automatic methods aimed to detect muscular contraction. 相似文献
The development of complex information systems calls for conceptual models that describe aspects beyond entities and activities.
In particular, recent research has pointed out that conceptual models need to model goals, in order to capture the intentions
which underlie complex situations within an organisational context. This paper focuses on one class of goals, namely non-functional
requirements (NFR), which need to be captured and analysed from the very early phases of the software development process.
The paper presents a framework for integrating NFRs into the ER and OO models. This framework has been validated by two case
studies, one of which is very large. The results of the case studies suggest that goal modelling during early phases can lead
to a more productive and complete modelling activity. 相似文献
The purpose of this work is the design of metal-zeolite nanocomposite catalysts for Fischer–Tropsch synthesis, containing ruthenium nanoparticles, uniformly distributed in the hierarchical BEA zeolites. The use of ruthenium avoids the formation of inert hardly reducible inert metal silicates and metal aluminates. Carbon nanotubes with supported metal oxide nanoparticles play the role of sacrificial template, which allows creating mesoporosity and bringing metallic functionality inside the zeolite matrix. Both mesoporosity and larger micropores of the BEA zeolite facilitate the localization of metal nanoparticles within the zeolite structure and diffusion of the reacting molecules. Compared to the conventional zeolite supported metal catalysts, the synthesized hierarchical ruthenium-zeolites exhibited much higher activity and lower methane selectivity in Fischer–Tropsch synthesis.
We explicitly construct global strict Lyapunov functions for rapidly time-varying nonlinear control systems. The Lyapunov functions we construct are expressed in terms of oftentimes more readily available Lyapunov functions for the limiting dynamics which we assume are uniformly globally asymptotically stable. This leads to new sufficient conditions for uniform global exponential, uniform global asymptotic, and input-to-state stability of fast time-varying dynamics. We also construct strict Lyapunov functions for our systems using a strictification approach. We illustrate our results using several examples. 相似文献
Thin liquid sheets occur in several practical applications. In curtain coating, a thin liquid sheet is formed and falls freely over a considerable height before it impinges onto a moving substrate. Precision curtain coating was developed for multi layer photographic films but its use has expanded to many different applications. One of the important limits of this process is the stability of the liquid curtain, which may define the minimal thickness that can be coated at a given web speed.The condition at which a low viscosity Newtonian liquid curtain breaks was first derived based on a simple balance between inertial and capillary forces. There is a critical flow rate below which the curtain becomes unstable. For viscoelastic liquids, the normal stress related to the stretching of polymer molecules as the liquid accelerates down the curtain changes the force balance. Here, the critical condition at which a viscoelastic liquid curtain breaks was determined as a function of the rheological properties of the liquid. The results show that high extensional viscosity liquids create more stable curtains. Liquid additives could be used to push the limits of curtain flow rates to smaller values and consequently to widen the operability window of the process. 相似文献
The use of bran and whole grain flour changes dough rheology and causes difficulties in manufacturing bakery products. The aim of this study was to analyse the influence of substituting refined wheat flour (WF) by wheat bran (WB; 5%, 10%, 20%, 30% and 40%) or whole grain wheat flour (WGWF; 10%, 20%, 30%, 40% and 50%) on dough rheological properties and pan bread quality characteristics. The addition of WB and WGWF increased water absorption and resistance to extension and decreased stability, extensibility and peak viscosity. Effects with WB were more pronounced. The presence of WB or WGWF increased crumb moisture content, firmness and hardness and decreased specific volume of pan bread. It is important to set new farinographic and extensographic standards when using WB and WGWF, allowing for a correct correlation between rheology and quality characteristics of bakery products, as the same standards used for WF are not valid. 相似文献
This paper exploits a universal current-based definition of the threshold voltage (VT) and discusses some direct methods to measure it. The consistency, accuracy, and sensitivity of the extraction procedures to second-order effects are examined through numerical simulations and experimental measurements. In addition to three procedures based on dc current measurements we propose an automatic VT-extractor circuit which allows the direct determination of the threshold voltage with minimum influence of second-order effects. 相似文献