Flexible,Mechanically Stable,Porous Self-Standing Microfiber Network Membranes of Covalent Organic Frameworks: Preparation Method and Characterization

Covalent organic frameworks (COFs) show advantageous characteristics, such as an ordered pore structure and a large surface area for gas storage and separation, energy storage, catalysis, and molecular separation. However, COFs usually exist as difficult-to-process powders, and preparing continuous, robust, flexible, foldable, and rollable COF membranes is still a challenge. Herein, such COF membranes with fiber morphology for the first time prepared via a newly introduced template-assisted framework process are reported. This method uses electrospun porous polymer membranes as a sacrificial large dimension template for making self-standing COF membranes. The porous COF fiber membranes, besides having high crystallinity, also show a large surface area (1153 m² g⁻¹), good mechanical stability, excellent thermal stability, and flexibility. This study opens up the possibility of preparation of large dimension COF membranes and their derivatives in a simple way and hence shows promise in technical applications in separation, catalysis, and energy in the future.     

Tensile testing and fracture mechanism analysis of polyvinyl alcohol nanofibrous webs

A tensile properties testing study was conducted to understand the influence of thickness, cross-head speed (speed of testing), gauge length (GL; specimen test length), and sample shape on important tensile properties of polyvinyl alcohol (PVA) nanofiber webs. The effects of each testing parameter on load at break, extension at break, Young's modulus, and tensile stress–strain curve of PVA nanofiber webs are analyzed. The Welch two sample t-tests show the significant difference among tested data. Using interaction plots, two-way analysis of variance, and margin mean plots, the interaction effects among testing parameters have been analyzed. Of all the factors, cross-head speed, the interaction among GL, and sample thickness (GL: Thickness) and the interaction among GL, testing speed and sample thickness (GL: Speed: Thickness) have significant influence on the tensile properties of PVA nanofiber webs. Moreover, the hypothesized model of mechanism of tensile strain–stress curve of PVA nanofiber webs has been proposed. Based on the model, the tensile strain–stress curve can be split into three stages: linear elastic, partial break up, and complete breakage. This study will provide a better understanding of tensile testing parameters' effects and their interaction effects on the tensile properties of nanowebs.     

Olfactory discrimination of individual littermates in rats (Rattus norvegicus).

Tested the ability of 4 adult male Sprague-Dawley rats to use odors in discrimination among littermates living as a group. Ss were trained in a Y-maze to discriminate the presence of a littermate from its absence. Results from transfer of training in 3 subsequent testing periods indicated that the animals were capable of distinguishing among individuals when relatedness and familiarity were held constant, that this ability was not due to training, and that performance was based solely on odor cues. Results suggest that laboratory rats exhibit odor sensitivities conmensurate with very complex social processes. (17 ref) (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

What does the object decision task measure? Reflections on the basis of evidence from semantic dementia.

The authors investigated the impact of semantic knowledge on visual object analysis by assessing the performance of patients with semantic dementia on a different-views object matching test and on 2 object decision tests differing, for example, in whether the nonreal items were nonsense objects or chimeras of 2 real objects. On average, the patients scored normally on both the object matching and the object decision test including nonsense objects but were impaired on the object decision test including chimeras; this latter was also the only visual object test that correlated significantly with degree of semantic impairment. These findings demonstrate that object decision is not a single task or ability and that it is not necessarily independent of conceptual knowledge. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Alcohol consumption as a self-handicapping strategy in women.

Assessed whether women self-handicap with alcohol consumption prior to engaging in a social evaluation task, which may be more relevant to their self-esteem than the intellectual tasks used in past self-handicapping studies on substance use. 113 women (aged 19–32 yrs), who were evaluated as normal drinkers, performed either a solvable or an insolvable social judgment task and then received either success feedback or no feedback. Ss received access to alcoholic and nonalcoholic beverages while awaiting a retest. The study terminated before the retest. The self-handicapping hypothesis that noncontingent success would produce relatively greater alcohol consumption was not supported. Regardless of feedback, insolvable test Ss consumed more alcohol than did solvable test Ss. Findings suggest that the hypothesis may be limited as a general model of alcohol consumption in both sexes. (13 ref) (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Plastic deformation and fracture of binary TiAl-base alloys

The mechanical behavior of binary TiAl alloys containing 46 to 60 at. pct Al has been studied in bulk materials preparedvia rapid solidification processing. Bending and tensile tests were carried out at room temperature as a function of Al concentration. A few alloys were also tested from liquid nitrogen temperature to ∼ 1000°C. Deformation substructures were studied by analytical transmission electron microscopy and fracture modes by scanning electron microscopy (SEM). It was found that both microstructure and composition strongly affect the mechanical behavior of TiAl-base alloys. A duplex structure, which contains both primary y grains and transformedγ/α ₂ lamellar grains, is more deformable than a single-phase or a fully transformed structure. The highest plasticities are observed in duplex alloys containing 48–50 at. pct Al after heat treatment in the center of theγ + α phase field. The deformation of these duplex alloys is facilitated by 1/2[110] slip and {111} twinning, but very limited superdislocation slip occurs. The twin deformation is suggested to result from a lowered stacking fault energy due to oxygen depletion or an intrinsic change in chemical bonding. Other factors, such as grain size and grain boundary chemistry and structure, are important from a fracture point of view. The results on the deformation and fracture modes as a function of test temperature are also discussed.     

Drug use, violence, and victimization among White American, Mexican American, and American Indian dropouts, students with academic problems, and students in good academic standing.

Problem-prone behaviors of White American, Mexican American, and American Indian high school dropouts, students in good academic standing, and students in poor academic standing were surveyed. Generally, dropouts were most involved with drugs, perpetration of violence, and victimization by violence, students in poor standing were the next most involved, and students in good standing were least involved. Ethnicity did not interact with academic status, suggesting that differences between dropouts and students were similar across ethnic groups. Some ethnicity and gender main effects were found. Findings were related to R. Jessor's (see record 1992-23064-001) theory of problem-prone behaviors, to peer cluster theory, and to intervention design. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Predicting future clinical adjustment from treatment outcome and process variables.

General issues relating to the use of outcome and process data from the treatment of antisocial children to predict future childhood adjustment are examined. For outcome measures, it was assumed that variables based on direct observation of child behavior would provide a better predictor of long-term adjustment than would ratings by participant adults. Long-term adjustment measures consisted of police arrest and out-of-home placement data collected 2 years after treatment termination. Observation data collected at termination predicted future police arrest, but parent and teacher ratings did not. It was also hypothesized that measures of the processes thought to produce the changes in child antisocial behavior would serve as predictors of future adjustment. The data supported this hypothesis. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Interfacial effects of surface-active agents under zinc pressure leach conditions

Liquid sulfur-zinc sulfate solution interfacial tensions and liquid sulfur-zinc sulfate solution-zinc sulfide (marmatite) contact angles were measured in the absence and presence of surface-active agents. Interfacial tensions measured varied between 54 ± 1 mN/m in the surfactant-free system and 20 ± 1 mN/m in the presence of a surfactant. The liquid sulfur-zinc sulfide mineral-zinc sulfate solution contact angle varies between 80 ± 5 deg, in the absence of any surfactant, and 148 ± 5 deg, depending on the surfactant used. The surface-active agents were used as dispersants for sulfur in bench-scale zinc pressure-leaching experiments. The observed extent of zinc extraction depends on the surfactant and varies from 40 to 96 pct.     

Solubility of some transition metal oxides in cryolite-alumina melts: Part II. Solubility of TiO2

The solubility of TiO₂ in cryolite-alumina melts at 1020 °C was measured; it decreased with increasing alumina concentration up to ∼3.5 wt pct total oxide and then increased at higher alumina concentrations. The solubility was found to be 3.1 wt pct Ti in cryolite, and 2.7 wt pct Ti in an alumina-saturated melt. Modeling indicated that the most probable titanium species are TiOF₂ and Na₂TiO₃, which coexist in the solution; the former dominates at low alumina concentrations and the latter at high alumina concentrations. Additional unknown amounts of fluoride may also be associated with these species. Determination of the solubility of TiO₂ in alumina-saturated melts as a function of temperature showed that the solubility increased from 1.9 wt pct Ti at 975 °C to 2.8 wt pct Ti at 1035 °C, the apparent partial molar enthalpy of dissolution of TiO₂ being 88±4 kJ mol⁻¹.