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1.
Patrick R. Taylor Ph.D. Milton Manrique Ph.D. 《JOM Journal of the Minerals, Metals and Materials Society》1996,48(6):43-45
Due to several inherent advantages, plasma processing technology may become a very useful tool in the production of new materials. An increasing research effort based on experimental as well as theoretical investigations has been invested in this area for the synthesis of advanced materials. In describing the thermal-plasma processing technique, this article employs examples from research at the Plasma Processing Laboratory at the University of Idaho. 相似文献
2.
Under carefully chosen conditions, solidification theory may be applied to solid-state transformations, and this has been
done here for composition-invariant diffusion transformations. The predictions of the modeling are compared with isovelocity
experiments in two iron systems, Fe-7.29 wt pct Cr and Fe-3.1 wt pct Ni. The ferrite to austenite phase transformation is
used to demonstrate that stabilization of a planar transformation front at absolute stability is the natural lower velocity
limit for a composition-invariant (massive) transformation. The results of the model, which includes nonequilibrium effects,
clearly show that steady-state plane-front growth leading to composition invariance can be obtained at various temperatures
depending on the growth velocity. In the lower velocity range, at the limit of absolute stability (of the order of 10 μm/s in the systems studied), the transformation interface moves under conditions of local equilibrium, and the temperature
corresponds to the lower solvus temperature. At higher velocity (of the order of the interface diffusion rate, which in these
systems is of the order of cm/s), the transformation is predicted to proceed at temperatures close to T
0. At even higher rates, atom attachment kinetic undercooling will decrease the transformation temperature with respect to
T
0. In some cases, this temperature might even drop below the lower solvus.
This article is based on a presentation made at the symposium entitled “The Mechanisms of the Massive Transformation,” a part
of the Fall 2000 TMS Meeting held October 16–19, 2000, in St. Louis, Missouri, under the auspices of the ASM Phase Transformations
Committee. 相似文献
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6.
S Dawson D Bennett SD Carter M Bennett J Meanger PC Turner MJ Carter I Milton RM Gaskell 《Canadian Metallurgical Quarterly》1994,56(2):133-143
Twelve specific pathogen-free cats were infected either by intra-articular inoculation or by contact exposure to one of two strains of feline calicivirus (FCV), either F65, a field strain originating from an outbreak of lameness in a group of cats, or a vaccine strain. Following either route of exposure, both strains induced signs typical of FCV infection including oral and nasal ulceration, conjunctivitis and ocular discharge. These signs were of equal severity for both virus strains, but overall, following either route of infection, F65 induced more severe disease than the vaccine strain, with marked pyrexia, lethargy and lameness. Vaccine virus only induced a relatively mild lameness following intra-articular inoculation. Gross pathological and histopathological lesions were seen in some of the joints, but again changes were more severe in the F65-exposed cats. Virus was isolated from both normal and affected joints from both groups of F65-exposed cats, and from a joint from each cat inoculated intra-articularly with vaccine virus. Mild transient lameness was also seen in one of two control cats inoculated intra-articularly, but no pathological changes were seen or virus isolated from joints. A cDNA probe used in RNA dot blot hybridisation experiments was found to be specific and more sensitive than virus isolation in detecting FCV in selected tissues. This may be useful in future studies on the pathogenesis of FCV disease and in studies on viral persistence in FCV carriers. 相似文献
7.
Milton E. Rose 《Journal of scientific computing》1990,5(2):169-185
A compact finite-difference scheme to solve one-phase Stefan problems in one dimension is described. Numerical experiments indicate that the moving interface is obtained withO(t) accuracy when 3–4 iterations per time step are used to solve the nonlinear implicit scheme. The scheme can be adapted to ADI methods in higher dimensions. 相似文献
8.
Chengyun Yue J. Milton Harris Per-Erik Hellberg Karin Bergstrom 《Journal of the American Oil Chemists' Society》1996,73(7):841-845
A series of noncyclic acetal-linked cleavable surfactants were simply prepared by condensation of aldehydes with poly(ethylene
glycol) monomethyl ethers. All of the products were characterized by1H nuclear magnetic resonance. Their hydrophile-lipophile balance, surface tension, cloud point, critical micelle concentration,
and foam height were determined. Hydrolysis kinetic studies, followed by gas chromatography, showed that they had higher hydrolytic
reactivity in acidic solution than cyclic acetal-linked cleavable surfactants. 相似文献
9.
Milton J. Rosen 《Journal of the American Oil Chemists' Society》1972,49(5):293-297
Changes in the various structural units present in surfactants strongly affect the interfacial properties shown by these materials.
Such properties as surface tension reduction, micelle formation, wetting, foaming and defoaming, detergency, and dispersion
of solids all show marked changes with variations in both the hydrophilic and hydrophobic portions of the surfactant molecule,
reflecting the processes occurring on a molecular level. Changes in these properties caused by such factors as the length
and nature of the hydrophobic group, branching or unsaturation in the hydrophobic group, the nature of the hydrophilic group
and its position in the molecule, and the presence or absence of an ionic charge are described and explained in terms of the
molecular processes involved.
Presented at the AOCS Short Course, “Update on Detergents and Raw Materials,” Lake Placid, New York, June 1971. 相似文献
10.
Relationship of structure to properties of surfactants. 16. Linear decyldiphenylether sulfonates 总被引:1,自引:0,他引:1
Milton J. Rosen Zhen Huo Zhu Xi Yuan Hua 《Journal of the American Oil Chemists' Society》1992,69(1):30-33
The properties of some well-characterized sodium linear decyldiphenylether (C10DPE)sulfonates have been studied. Among the properties investigated are dynamic and equilibrium surface tension, critical
micelle concentration (CMC), area per molecule at the aqueous solution/air interface, wetting time by the Draves technique,
foaming by the Ross-Miles method, solubilization, and hydrotropy. The decyldiphenylether moiety appears to be equivalent to
a terminally substituted straight alkyl chain of 16 carbon atoms. The trialkyl- and dialkyl-mono-sulfonates have solubilities
of < 0.01 g/dm3 in water, but are readily soluble in hexane. The didecyldiphenyl ether disulfonate (DADS) has a very low CMC value (1.0 ×
10−5 mol dm−3) in aqueous 0.1 N Na+ solution (NaCl), characteristic of surfactants with two hydrophilic and two hydrophobic groups. It also has a much larger
area per molecule at the aqueous solution/air interface than the monodecyldiphenyl-ether monosulfonate (MAMS) and a much higher
surface tension at the CMC. MAMS has a much lower surface tension at a surface age of 1 second (γ1s) than either DADS or the monodecyldiphenylether disulfonate (MADS). In agreement with γ1s and γeq values, wetting times increase in the order: MAMS < DADS < MADS and initial foam heights decrease in the order: MAMS > DADS
> MADS. Solubilization for three water-insoluble surfactants decreases in the order: DADS > MAMS > MADS, while hydrotropy
is most pronounced with the disulfonates. 相似文献