Synthesis of heterocyclic metal complexes and their evaluation as marine antifoulants

4-Amino-3-thio-1,24-triazolidine (L₁) and 4-amino-5-thio-1,3,4-thiadiazole (L_II) as well as their metal complexes of the general formulae ML_I·2H₂O and ML_IICl (M; Pb(II), Cd(II) and Zn(II)) were prepared. With Sn(II), we obtained Sn(L_I)₂·2H₂O and SnL_IICl, respectively. The structures of the compounds were identified through elemental analysis, and IR and UV spectra measurements, in addition to thermal analysis in case of the metal complexes. The antifouling properties of the compounds were tested by their incorporation into paint formulations which were applied to PVC substrates and tested in water from Alexandria western harbour. When the compounds were added at 17·5% by volume, the coated panels were fouled after 3 months of immersion. The addition of 6·7% by volume of tributyltin oxide to 15·8% of the prepared compounds in one formulation elevated the paint efficiency and prevented fouling for 11 months. Paint containing solely tributyltin oxide at the same concentration was inactive against algae.     

CAS-BUS: A Test Access Mechanism and a Toolbox Environment for Core-Based System Chip Testing

As System on a Chip (SoC) testing faces new challenges, some new test architectures must be developed. This paper describes a Test Access Mechanism (TAM) named CAS-BUS that solves some of the new problems the test industry has to deal with. This TAM is scalable, flexible and dynamically reconfigurable. The CAS-BUS architecture is compatible with the IEEE P1500 standard proposal in its current state of development, and is controlled by Boundary Scan features.This basic CAS-BUS architecture has been extended with two independent variants. The first extension has been designed in order to manage SoC made up with both wrapped cores and non wrapped cores with Boundray Scan features. The second deals with a test pin expansion method in order to solve the I/O bandwidth problem. The proposed solution is based on a new compression/decompression mechanism which provides significant results in case of non correlated test patterns processing. This solution avoids TAM performance degradation.These test architectures are based on the CAS-BUS TAM and allow trade-offs to optimize both test time and area overhead. A tool-box environment is provided, in order to automatically generate the needed component to build the chosen SoC test architecture.     

Electrophysiological and Fos immunohistochemical evidence for the excitatory nature of the parafascicular projection to the globus pallidus

Extracellular recordings and immunohistological detection of c-Fos-like immunoreactive proteins were used to determine the synaptic effect of the parafascicular projection to the globus pallidus. Electrical stimulation of the parafascicular neurons induced a single-spike excitatory response with a stable latency of 2.3 ms, suggesting a monosynaptically driven effect. Pharmacological stimulation of the parafascicular nucleus with carbachol increased tonically the pallidal discharge rate by 142%. The discharge rate of the pallidal neurons was described by 37% in parafascicular-lesioned rats. These results demonstrate the excitatory nature and the tonic action of the parafasciculopallidal projection. Carbachol activation of parafascicular neurons also induced the synthesis of c-Fos-like immunoreactive proteins in the pallidal neurons. Control experiments in subthalamic-lesioned rats showed that the parafascicular excitation of the pallidal neurons remained, but both electrophysiological and expression of c-Fos-like immunoreactive proteins were attenuated. This suggests that the direct parafascicular excitation of the pallidal neurons is indirectly reinforced by the previously described parafascicular excitatory input to the subthalamic nucleus. Conversely, the effect of this last input to the subthalamic nucleus is dramatically enhanced in rats with pallidal lesion. Our results demonstrate the complex role of the parafascicular nucleus in activating both the globus pallidus and the subthalamic nucleus, two closely related structures. These results illustrate the integrative capacities of the globus pallidus, whose activity is modulated by multiple afferents.     

Effect of functional group of ferrocene redox substance on the transport properties of newly designed ion exchange membrane prepared from polymer gel

A different newly designed cationic exchange polymer membrane and anionic exchange polymer membrane were introduced, and also the transport properties of these polymeric membranes were investigated in this study. The transport properties of these polymer membranes in contact with ferrocene redox derivatives were estimated by using electrochemical techniques such as cyclicvoltammetry, chronopotentiometry, and chronoamperometry techniques, respectively. The used ferrocene redox substances, which have different functional groups, were (Ferrocenylmethyl) trimethylamonium iodide, FcMA, Ferrocenedimethanol, FcDM, and Ferrocene carboxylic acid, FcCA. It indicated that the performance of a membrane depended on the content of polymer gel, anionic exchange polymer site (20 wt % and 50 wt %) or cationic polymer exchange site (20 wt % and 50 wt %), and the efficiency of the functional groups of cationic and anionic exchange polymer site as well. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Water and salt permeability of reinforcement polymer‐gel composite membrane

The charged mosaic polymer membrane (CMM) without reinforcement and the composite charged mosaic polymer membrane (CCMM) with reinforcement were investigated in terms of salt and water transport (permeability). The composite charged mosaic polymer membrane (CCMM) with reinforcement showed a unique transport behavior such as preferential material transport L_p and ω. Water permeability coefficient, L_p and salt permeability coefficient, ω were estimated by taking account of active layer thickness of composite polymer gel. The L_p and ω values of CCMM with reinforcement were larger than those of CMM without reinforcement. On the other hand, the reflection coefficient of CCMM, σ, showed negative value, which suggested preferential material transport to solvent transport. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Large deformation analysis in the context of 3D compressible nonlinear elasticity using the VDQ method

In this article, a new solution approach is developed to numerically compute large deformations of 3D hyperelastic solids based on the compressible nonlinear elasticity. The governing equations are derived by the minimum total potential energy principle, and the Neo-Hookean model is used for the hyperelastic character of material. One of the key novelties of the work is its formulation in which the tensor form of equations is replaced by an efficient matrix–vector form that can be readily utilized in the coding process. Moreover, the variational differential quadrature technique is adopted to arrive at the discretized governing equations in a direct way. Simple implementation, fast convergence rate, and computational efficiency are the main advantages of present approach. Through some examples, the accuracy and effectiveness of the proposed numerical approach are revealed.

     

Hash key-based image encryption using crossover operator and chaos

This paper proposes a color image encryption scheme using one-time keys based on crossover operator, chaos and the Secure Hash Algorithm(SHA-2). The (SHA-2) is employed to generate a 256-bit hash value from both the plain-image and the secret hash keys to make the key stream change in each encryption process. The SHA-2 value is employed to generate three initial values of the chaotic system. The permutation-diffusion process is based on the crossover operator and XOR operator, respectively. Experimental results and security analysis show that the scheme can achieve good encryption result through only one round encryption process, the key space is large enough to resist against common attacks,so the scheme is reliable to be applied in image encryption and secure communication.     

Fuzzy fault tolerant predictive control for a diesel engine air path

This paper proposes a Fuzzy Fault Tolerant Predictive Control (FFTPC) with integral action method for a class of nonlinear systems. The Takagi-Sugeno (T-S) fuzzy approach is introduced as a modelling technique in order to consider the active control methods adapted to linear models. The proposed control strategy is based on a combination between Parallel Distributed Compensation (PDC) control law and Model Predictive Control (MPC) where the T-S fuzzy aspect uses the Unmeasurable Premise Variables (UPV). A T-S fuzzy observer provides an L2 norm estimation of system state vector and faults. The controller and observer gains are obtained by solving Linear Matrix Inequalities (LMIs) derived from the Lyapunov theory. The validity of the proposed Fault Tolerant Control (FTC) strategy is illustrated through an application to a Diesel Engine Air Path (DEAP) system.