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排序方式: 共有140条查询结果,搜索用时 15 毫秒
1.
Zempachi Ogumi Hiroya Yamashita Koji Nishio Zen-Ichiro Takehara Shiro Yoshizawa 《Electrochimica acta》1983,28(11):1687-1693
The feasibility of a solid polymer electrolyte (SPE) method for Kolbe type reactions was investigated by using Pt-SPE composed with Nafion 415 and platinum. The Kolbe reaction of acetic acid proceeded effectively on one side and both sides Pt-SPE composites. The lower current efficiency was observed on the latter than on the former. Neat acetic acid could also be electrolysed on both sides SPE though the cell voltage was fairly high.A methanolic solution of monomethyl adipate was electrolysed to give dimethyl sebacate on both sides Pt-SPE according to the Brown-Walker reaction. The current efficiency and the terminal voltage increased with the concentration of monomethyl adipate. Pt-SPE behaved as an active electrode of a high roughness factor, eg about 6, for the Kolbe reaction of acetate. 相似文献
2.
Masahiro Takehara Ippei Yoshimura Kouichi Takizawa Ryonosuke Yoshida 《Journal of the American Oil Chemists' Society》1972,49(3):157-161
Long chain N-acylglutamic acid was prepared in a high yield by a reaction of glutamic acid with fatty acid chloride in a mixed
solvent of water and a water miscible organic solvent such as acetone, methyl ethyl ketone, dioxane, tetrahydrofuran,t-butyl alcohol or cyclohexanone. In this reaction the composition of the mixed solvent influenced the yield of N-acylated
glutamic acid and the best yield was obtained when the reaction was carried out in the mixed solvent comprising 30–60% v/v
of the organic solvent. Long chain N-acylaspartic acid was also obtained in a high yield by the same method. As the other
method to obtain N-lauroyl-D L-glutamic acid, it was examined that N-acyl-α-aminoglutarodinitrile which was obtained by a reaction of α-aminoglutarodinitrile
with fatty acid chloride was hydrolyzed with an aqueous alkaline solution. The salts of long chain N-acylglutamic acid are
known as the surface active agents that react mildly on the human skin. 相似文献
3.
Sulface modification of lithium was carried out using the chemical reaction of the native film with acids (HF, H3PO4, HI, HCl) dissolved in propylene carbonate (PC). The chemical composition change of the lithium surface was detected using X-ray photoelectron spectroscopy. The electrodeposition of lithium on the as-received lithium or the modified lithium was conducted in PC containing 1.0 mol dm–3 LiClO4 or LiPF6 under galvanostatic conditions. The morphology of electrodeposited lithium particles was observed with scanning electron microscopy. The lithium dendrites were observed when lithium was deposited on the as-received lithium in both electrolytes. Moreover the dendrites were also formed on the lithium surface modified with H3PO4, HI, or HCl. On the other hand, spherical lithium particles were produced, when lithium was electrodeposited in PC containing 1.0 mol dm–3 LiPF6 on the lithium surface modified with HE However spherical lithium particles were not obtained, when PC containing 1.0 mol dm–3 LiClO4 was used as the electrolyte. The lithium surface modified by H3PO4, HI, or HCl was covered with a thick film consisting of Li3PO4, Li2CO3, LiOH, or Li2O. The lithium surface modified with HF was covered with a thin bilayer structure film consisting of LiF and Li2O. These results clearly show that the surface film having the thin bilayer structure (LiF and Li2O) and the use of PC containing 1.0 mol dm–3 LiPF6 enhance the suppression of dendrite formation of lithium. 相似文献
4.
In [N. Alon, M. Feldman, A.D. Procaccia, M. Tennenholtz, A note on competitive diffusion through social networks, Inform. Process. Lett. 110 (2010) 221–225], the authors introduced a game-theoretic model of diffusion process through a network. They showed a relation between the diameter of a given network and existence of pure Nash equilibria in the game. Theorem 1 of their paper says that a pure Nash equilibrium exists if the diameter is at most two. However, we have an example which does not admit a pure Nash equilibrium even if the diameter is two. Hence we correct the statement of Theorem 1 of their paper. 相似文献
5.
6-(2-Cyanoethylamino)-6-deoxycellulose (Cell-CEA) as a novel cellulose derivative was prepared from 6-bromo-6-deoxycellulose. The influence of the reaction conditions on the degree of substitution was studied in detail. The dielectric characteristics of a Cell-CEA sample having degree of substitution of 0.86, together with those of microcrystalline and regenerated celluloses, have been investigated in the temperature range from −60 to 120°C, and frequency range 30 Hz to 100kHz. One relaxation process, designated as β, was recognised, which was attributed to side-group motions, probably −CH2X (X = OH or NHCH2CH2CN). The higher activation energy of this process and the shift to higher temperature in Cell-CEA, compared with microcrystalline and regenerated celluloses, reflects the enhanced steric constraints involved in the motion of the bulkier, −CH2NHCH2CH2CN, side groups. The results obtained are discussed in terms of the dielectric parameters ϵ″max′ β and Δϵ. 相似文献
6.
对电解二氧化锰(EMD)的粉末与大颗粒中和工艺进行了考察。电子微探分析(EPMA)结果表明:大颗粒中和的EMD粒子内部及粒子之间,存在Na含量的偏差。粉末中和EMD的Na含量,较大颗粒中和的EMD低30%~50%。大颗粒中和与粉末中和相比,需要较强的中和条件。 相似文献
7.
Yasuhito Ishigaki Yuka Nakamura Teruaki Takehara Noriko Nemoto Takayuki Kurihara Hironori Koga Hideaki Nakagawa Tsutomu Takegami Naohisa Tomosugi Shichiro Miyazawa Susumu Kuwabata 《Microscopy research and technique》2011,74(5):415-420
Ionic liquid is a kind of salt that stays in a molten state even at room temperature. It does not vaporize at all in vacuum and facilitates electrical conductivity to the sample surfaces for observations with a scanning electron microscope (SEM). In this study, we used an ionic liquid in SEM for the first time to observe fixed human culture cells. The condition for the cell culture using wrapping sheets and SEM settings were varied to elucidate the optimized protocol. Compared to samples prepared by the conventional way, the ionic liquid‐treatment of samples gave SEM images of the cellular ultra structures in more detail, enabling observation of microvilli that made bridges between separated cells. In addition, the ionic liquid treatment is less time consuming as well as less laborious compared with the conventional way that includes dehydration, drying, and conductivity treatments. Totally, we concluded the ionic liquid is a useful reagent for SEM sample preparation. Microsc. Res. Tech., 2011. © 2010 Wiley‐Liss, Inc. 相似文献
8.
We have applied particle tracking techniques to obtain spatially resolved velocity measurements in electrokinetic flow devices. Both micrometer-resolution particle image velocimetry (micro-PMV) and particle tracking velocimetry (PTV) techniques have been used to quantify and study flow phenomena in electrokinetic systems applicable to microfluidic bioanalytical devices. To make the flow measurements quantitative, we performed a series of seed particle calibration experiments. First, we measure the electroosmotic wall mobility of a borosilicate rectangular capillary (40 by 400 microm) using current monitoring. In addition to this wall mobility characterization, we apply PTV to determine the electrophoretic mobilities of more than 1,000 fluorescent microsphere particles in aqueous buffer solutions. Particles from this calibrated particle/ buffer mixture are then introduced into two electrokinetic flow systems for particle tracking flow experiments. In these experiments, we use micro-PIV, together with an electric field prediction, to obtain electroosmotic flow bulk fluid velocity measurements. The first example flow system is a microchannel intersection where we demonstrate a detailed documentation of the similitude between the electrical fields and the velocity fields in an electrokinetic system with uniform zeta potential, zeta. In the second system, we apply micro-PIV to a microchannel system with nonuniform zeta. The latter experiment provides a simultaneous measurement of two distinct wall mobilities within the microchannel. 相似文献
9.
Sheng Sun Takako Takehara In Doo Kang 《Journal of the Society for Information Display》2005,13(2):99-103
Abstract— With the prevailing trend of large‐panel TFT monitors and, most recently, LCD TVs, large‐sized‐substrate processing is becoming the mainstream of TFT‐LCD production. To enable this trend of ever‐increasing large‐area processing, a multiple generations of PECVD systems for volume production has been successfully developed. This paper discusses the scaling‐up challenges from the equipment manufacturer's perspective, with the focus on process scalability, system design optimization, productivity enhancement, and cost‐of‐ownership reduction. 相似文献
10.
Pretreatment of alumina particles fouled with bovine serum albumin (BSA) by 0.3% (v/v) gaseous ozone markedly accelerated the removal of BSA during alkali cleaning through partial decomposition of the BSA molecule. The results suggest that ozone pretreatment can reduce the NaOH concentration required for adequate alkali cleaning by at least one order of magnitude. 相似文献