Individually, photoredox catalysis (PC) and photodynamic therapy (PDT) are well-established concepts that have experienced a remarkable resurgence in recent years, leading to significant progress in organic synthesis for PC and clinical approval of anticancer drugs for PDT. But, very recently, new photoredox catalyst systems based on Ir(III) and Ru(II) complexes have garnered significant interest because they can simultaneously be used as PDT agents apart from their demonstrated PC activity. This highlight discusses the unique PC behavior of emerging Ir(III)- and Ru(II)-based systems while also examining their potential PDT activity in cancer treatment. 相似文献
As per the most recent literature, Orthogonal Frequency Division Multiplexing (OFDM), a multi access technique, is considered most suitable for the 3G, 4G and 5G techniques in high speed wireless communication. What made OFDM most popular is its ability to deliver high bandwidth efficiency and superior data rate. Besides it, high value of peak to average power ratio (PAPR) and Inter Carrier Interference (ICI) are the challenges to tackle down via appropriate mitigation scheme. As a research contribution in the present work, an improved self-cancellation (SC) technique is designed and simulated through Simulink to mitigate the effect of ICI. This novel proposed technique (Improved SC) is designed over discrete wavelet transform (DWT) based OFDM and compared with conventional SC scheme over different channel conditions i.e. AWGN and Rayleigh fading environments. It is found that proposed DWT-OFDM with Improved SC scheme outperforms conventional SC technique significantly, under both AWGN and Rayleigh channel conditions. Further, in order to justify the novelty in the research contribution, a Split-DWT based Simulink model for Improved SC scheme is investigated to analyse the BER performance. This Split-DWT based Simulink model presented here foretells the future research potential in wavelet hybridization of OFDM to side-line ICI effects more efficiently.
The technology for transesterification reactions between methyl esters and alcohols is well established by using classical homogeneous alkaline catalysts, which provide high conversion of methyl esters to specialty or nonindigenous esters. However, in certain products where the purity of the esters is of concern, the removal of homogeneous catalysts after the completion of the reaction is a challenge in terms of production cost and water footprint. Therefore, a study to investigate the potential of heterogeneous catalysts was conducted on reactions between methyl palmitate and triethanolamine. The degree of basicity and active surface area of calcium oxide (CaO), zinc oxide (ZnO), and magnesium oxide (MgO) were first characterized by using temperature-programmed desorption (TPD-CO2) and Brunauere–Emmett–Teller (BET), respectively. Among the metal oxides investigated, the CaO catalyst showed the best catalytic activity toward the transesterification process as it gave the highest conversion of methyl palmitate and yielded fatty esteramine compositions similar to the conventional homogeneous catalyst. The optimum transesterification condition by using the CaO catalyst utilized a lower vacuum system of approximately 200 mbar, which could minimize a considerable amount of energy consumption. Furthermore, low CaO dosage of 0.1% was able to give a conversion of 94.5% methyl ester and formed esteramine at 170 °C for 2 h. Therefore, the production of esterquats from esteramine may become more economically feasible through the methyl ester route by using the CaO catalyst, which can be recycled three times. 相似文献
An assessment is made of the technical contents of flight-vehicle structures curricula at 41 U.S. universities with accredited aerospace engineering programs. The assessment is based on the technical needs for the new and projected aeronautical and space systems as well as on the likely characteristics of the aerospace engineering work environment. A number of deficiencies and areas of concern are identified and recommendations are presented for enhancing the effectiveness of flight-vehicle structures education. A number of government supported programs that can help aerospace engineering education are listed in the appendix. 相似文献
Direct conversion receiver (DCR) architecture, which has introduced the zero intermediate frequency (IF) approach, supports efficient wireless handset designs with a high level of integration. Transmission over wireless channels is subject to time dispersion due to multipath propagation and frequency dispersion due to Doppler effect, the design of wireless receivers are tremendously important in supporting reliable communication links. With wireless technology growing, the choice of optimal wireless receiver architecture that supports monolithic integration without performance degradation becomes an important dimension in modern handset design. The increasing demand for mobile terminals with smaller physical dimensions has led to the investigation of DCR, which supports single chip and multinode designs. Since DCR is a promising architecture for fourth generation mobile terminals, it is important to note that implementation of a certain dc offset technique does not compromise the benefits of low complexity receiver design. 相似文献
Analyzing videos and images captured by unmanned aerial vehicles or aerial drones is an emerging application attracting significant attention from researchers in various areas of computer vision. Currently, the major challenge is the development of autonomous operations to complete missions and replace human operators. In this paper, based on the type of analyzing videos and images captured by drones in computer vision, we have reviewed these applications by categorizing them into three groups. The first group is related to remote sensing with challenges such as camera calibration, image matching, and aerial triangulation. The second group is related to drone-autonomous navigation, in which computer vision methods are designed to explore challenges such as flight control, visual localization and mapping, and target tracking and obstacle detection. The third group is dedicated to using images and videos captured by drones in various applications, such as surveillance, agriculture and forestry, animal detection, disaster detection, and face recognition. Since most of the computer vision methods related to the three categories have been designed for real-world conditions, providing real conditions based on drones is impossible. We aim to explore papers that provide a database for these purposes. In the first two groups, some survey papers presented are current. However, the surveys have not been aimed at exploring any databases. This paper presents a complete review of databases in the first two groups and works that used the databases to apply their methods. Vision-based intelligent applications and their databases are explored in the third group, and we discuss open problems and avenues for future research.
In this study, we demonstrate Zn1?xFexS (x = 0.0, 0.25, 0.50, 0.75, and 1.0) device applications by reporting electronic, magnetic, and optical properties, computed with Wien2k software, using density functional theory (DFT). The modified Becke and Johnson (mBJ) potential has been applied to accurately determine the material band gap. The presence of half-metallic ferromagnetism (HMF) is demonstrated. Moreover, the observed ferromagnetism is justified in terms of various splitting energies and the exchange constants. The Fe magnetic moment decreases from 4.0 μB due to the strong p ? d hybridization. A complete set of various optical parameters is also presented. The variation in the calculated static dielectric constant, due to Fe doping, is inversely related to the band gap that verifies Penn’s model. Moreover, the band gap of ZnS is tunable by the Fe doping, from ultraviolet to visible regions, depicting that the materials are appropriate for optoelectronic devices. 相似文献
In this paper, we introduce and consider a new class of mixed variational inequalities involving four operators, which are called extended general mixed variational inequalities. Using the resolvent operator technique, we establish the equivalence between the extended general mixed variational inequalities and fixed point problems as well as resolvent equations. We use this alternative equivalent formulation to suggest and analyze some iterative methods for solving general mixed variational inequalities. We study the convergence criteria for the suggested iterative methods under suitable conditions. Our methods of proof are very simple as compared with other techniques. The results proved in this paper may be viewed as refinements and important generalizations of the previous known results. 相似文献