Light-induced electron spin polarization in the ground state of water-soluble copper porphyrins

Light-induced spin-polarized transient EPR spectra are reported for several water-soluble copper porphyrins. The spectra are assigned to the doublet ground state, with emissive spin polarization resulting from photoexcitation and subsequent electronic relaxation. In contrast to other systems for which polarization of a doublet ground state has been observed, the exchange interactions in the copper porphyrins are strong and the geometry is fixed. It is proposed that intersystem crossing from the photoexcited trip-doublet to the trip-quartet state can lead to net polarization of the spin system and that this polarization is maintained during electronic decay, possibly via charge-transfer and exciplex states. The intensity of the observed spin polarization is essentially independent of the molecular orientation in the external field, but is strongly dependent on the nature of the charged peripheral groups. Possible reasons for this behavior are discussed.     

Data Squashing by Empirical Likelihood

Data squashing was introduced by W. DuMouchel, C. Volinsky, T. Johnson, C. Cortes, and D. Pregibon, in Proceedings of the 5th International Conference on KDD (1999). The idea is to scale data sets down to smaller representative samples instead of scaling up algorithms to very large data sets. They report success in learning model coefficients on squashed data. This paper presents a form of data squashing based on empirical likelihood. This method reweights a random sample of data to match certain expected values to the population. The computation required is a relatively easy convex optimization. There is also a theoretical basis to predict when it will and won't produce large gains. In a credit scoring example, empirical likelihood weighting also accelerates the rate at which coefficients are learned. We also investigate the extent to which these benefits translate into improved accuracy, and consider reweighting in conjunction with boosted decision trees.     

Maximization of mutual information for supervised linear feature extraction.

In this paper, we present a novel scheme for linear feature extraction in classification. The method is based on the maximization of the mutual information (MI) between the features extracted and the classes. The sum of the MI corresponding to each of the features is taken as an heuristic that approximates the MI of the whole output vector. Then, a component-by-component gradient-ascent method is proposed for the maximization of the MI, similar to the gradient-based entropy optimization used in independent component analysis (ICA). The simulation results show that not only is the method competitive when compared to existing supervised feature extraction methods in all cases studied, but it also remarkably outperform them when the data are characterized by strongly nonlinear boundaries between classes.     

An experimental and three-dimensional numerical study of natural convection heat transfer between two horizontal parallel plates

In this study, experimental and three-dimensional numerical studies were performed to investigate the effects of plate spacing and temperature difference on natural convection between isothermally heated upward-facing lower horizontal plate and externally insulated horizontal upper plate. Air is used as the heat transfer medium. Rayleigh number varied in the 1108–2.339 × 10⁵ range. Several numerical simulations for three-dimensional steady laminar and turbulent flows heat transfer were carried out using a commercial CFD code Fluent 6.2. Results have shown that there is a good agreement between the numerical and present experimental results as well as with available data in literature.     

The effect of the third invariant on the strength and failure of boron carbide and silicon carbide

This article presents new test data to assess the effect the third invariant has on the strength and failure of two ceramic materials: boron carbide and silicon carbide. Two experimental techniques are used: the Brazilian test that produces a biaxial state of stress, and a new technique that uses a high-pressure confinement vessel to load a specially designed dumbbell specimen in triaxial extension. The dumbbell geometry provides two important advantages over the typically used cylindrical specimen: no adhesive is required to bond the specimen to the load cell because the dumbbell geometry naturally takes the specimen into tension, and any loading asymmetries are essentially eliminated due to the axisymmetric geometry. The results show that when the stress state is on the tensile meridian the equivalent stress at failure is constant, independent of the hydrostatic pressure. The average equivalent stress at failure is for boron carbide and for silicon carbide. The Brazilian test was only performed on boron carbide and failed at , much higher than when on the tensile meridian () indicating that the effect of the third invariant is significant (because of the difference in the failure strength) and must be accounted for to accurately predict when failure will occur.     

Wear Mechanisms of Chromia Refractories in Slagging Gasifiers

The hot-face refractory lining is a key component of gasification systems. The refractory liner protects the gasification system from the high-temperature corrosive gaseous and from the molten slag environment associated with the conversion of carbon feedstocks. This paper will discuss the effect of gasifier operating conditions and carbon feedstock slag/ash chemistry on the refractory service life. Particular attention is focused on the wear mechanism of chromia refractories, determined through postmortem analysis of spent refractory bricks from service in gasifiers. Also presented is the behavior of a phosphate-containing chromia refractory with improved resistance to structural spalling.     

基于ATSQL2时间点与时间段时态操作扩充

以时态数据操作语言ATSQL2为基础,对其时间点与时间段查询运算操作存在的不足进行扩充。增加时间运算操作函数,完成不同时态逻辑时间段运算,不同时间粒度之间的转换和时间比较逻辑判断操作。结果表明,扩充后的时间运算操作,丰富了原有ATSQL2的查询操作语义,简化了复杂时态数据操作语句的书写,使时态查询操作更加高效、简便。     

The in-line inspection of carbon anodes for aluminum production

In this paper, methods for measuring the quality of carbon anodes consumed in the commercial production of aluminum are discussed. The electrical and mechanical qualities of these anodes are important for the economic operation of the aluminum plant. While the investigation is ongoing, results from tests made at an aluminum reduction plant are included. The methods reviewed include direct resistivity measurement using core samples, ultrasonic measurement, the hammer method, analysis of the Hall effect, the four-probe method, and use of magnetic coils (various arrangements).     

川南石刻图像模板匹配方法研究

本文以四川南部地区南宋墓葬石刻艺术图像为切入点,提出石刻图像模板匹配的方法,重点讨论石刻图像模板匹配的具体方法与流程,以及匹配过程中需要解决的几个关键技术性问题,最后通过仿真实验证明了该方法的有效性,并指出进一步的研究方向.