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1.
UV‐C‐driven oxidation of ciprofloxacin in conventionally treated urban wastewater: degradation kinetics,ecotoxicity and phytotoxicity assessment and inactivation of ciprofloxacin‐resistant Escherichia coli 下载免费PDF全文
2.
A method for industrial-scale preparation of carboxypeptidase Y (CPY), which was secreted by Saccharomyces cerevisiae KS58-2D/pCY303 into the culture broth, was developed. Because the purification process consists of a few simple unit operations including only one chromatography step, a higher CPY recovery was achieved than that in the process using disrupted baker's yeast. Approximately 100 g of purified CPY powder was constantly obtained using the final culture broth from a 500-l fermentor. 相似文献
3.
One of the most important factors in corrosion prevention by protective coatings is the coating adhesion loss under environmental influence. Thus, adhesion strength is often used when characterizing protective properties of organic coatings on a metal substrate. In order to improve the adhesion of organic coating the metal substrate is often pretreated in some way. In this work, the adhesion of polyester coatings on differently pretreated aluminium surface (by anodizing, with and without sealing, by phosphating and by silane film deposition) was examined. The dry and wet adhesion of polyester coatings were measured by a direct pull-off standardized procedure, as well as indirectly by NMP test. It was shown that under dry test conditions all polyester coatings showed very good adhesion, but that aluminium surface pretreated by silane film showed superior adhesion. The overall increase of wet adhesion for polyester coating on aluminium pretreated by silane film was maintained throughout the whole investigated time period. The different trends in the change of adhesion of polyester coatings were observed for different aluminium pretreatments during exposure to the corrosive agent (3% NaCl solution). The highest adhesion reduction was obtained for polyester coating on aluminium pretreated with phosphate coating. The corrosion stability of polyester coated aluminium was investigated by electrochemical impedance spectroscopy in 3% NaCl solution. The results confirmed good protective properties of polyester coating on aluminium pretreated with silane film, i.e. greater values of pore resistance and smaller values of coating capacitance were obtained in respect to other protective systems, whereas charge-transfer resistance and double-layer capacitance were not measurable during 2 months of exposure to a corrosive agent. 相似文献
4.
Thermogravimetric technique and boat experiments were used to study the chlorination of MgO and its reactivity with respect
to Cl2 + air, Cl2 + N2, and Cl2 + CO gas mixtures at temperatures lower than 1000°C. Oxychlorination of MgO occurs at temperatures higher than that of its
carbochlorination. Effects of experimental parameters such as gas flow rate, temperature, and partial pressure of the carbochlorinating
gas mixture on the reaction rate were examined. At 550 °C, the apparent reaction orders with respect to Cl2 + CO, Cl2, and CO were 2.37, 1.47, and 0.89, respectively. At this temperature, the maximum reaction rate was obtained using a Cl2 + CO gas mixture having a Cl2/CO molar ratio equal to about 0.6. The apparent activation energy of carbochlorination of MgO was calculated as 49 kJ/mol
between 425 °C and 600 °C. 相似文献
5.
N. Kanari O. Evrard N. Neveux L. Ninane 《JOM Journal of the Minerals, Metals and Materials Society》2001,53(11):32-33
Hydrated ferrous sulfate, a by-product of the titanium-dioxide and steel-surface-treatment industries, is usually disposed
of as waste at a significant extra cost for these industries. Due to tight environmental regulations in the European countries,
waste disposal of ferrous sulfate will not be an acceptable solution in the near future. Consequently, the waste will have
to be treated. Recently, ferrous sulfate was successfully used to synthesize a novel superoxidant material (potassium ferrate)
containing iron in hexavalent state (FeVI). With ferrates synthesis, innovative applications are possible in different industrial sectors, such as treatment of water
and wastewater and effluent decontamination.
For more information, contact N. Kanari, Laboratoire Environnement et Minéralurgie (LEM), Mineral Processing and Environmental
Engineering team, BP 40, 54501 Vandœuvre, France. 相似文献
6.
Eleni Loizou Popi Nicolaidou Kanari Georgia Kyriacou Maria Aletrari 《Journal für Verbraucherschutz und Lebensmittelsicherheit》2010,16(1):459-463
Directive 98/83/EC concerning the drinking water quality and Directive 80/777/EC for Natural Mineral Water demand strict control
and monitoring for the presence of metals. The State General Laboratory as the official control laboratory (Accredited by
ISO 17025:2005) implements a national monitoring program in order to ensure that the drinking and natural mineral water quality
satisfy the requirements of the respective Directives. The National Monitoring program covers mainly metals such as Pb, Cd,
Cr, Ni, As, Se, Sb, Hg, Mn, Cu, Fe, Al and B in water supplied for human consumption either by distribution networks, vending
machines, mobile water containers, ground water intended for human consumption as well as bottled water. The determination
of metals in water by Inductively Coupled Plasma-Mass Spectroscopy (ICP-MS) is a technique that successfully meets the requirements
of the above Directives as it is a very powerful tool for the measurement of metals at very low concentrations with high accuracy
and precision. The results obtained indicate that metal concentrations in drinking and bottled water examined were by far,
below the acceptable legal limits and even below the relevant detection limits. However, in samples of bottled natural mineral
water, high boron concentration were determined and risk assessment was performed due to the absence of relevant legal limits.
The present paper demonstrates the steps undertaken by the General Water Analysis Laboratory of the SGL for the validated
method used by ICP-MS in the determination of trace metals including boron in drinking and bottled water. 相似文献
7.
B.V. Jegdi? J.B. Bajat J.P. Popi? S.I. Stevanovi? V.B. Miškovi?-Stankovi? 《Corrosion Science》2011,(9):2872-2880
The effect of different type of iron-phosphate coatings on corrosion stability and adhesion characteristic of top powder polyester coating on steel was investigated. Iron-phosphate coatings were deposited on steel in the novel phosphating bath with or without NaNO2 as an accelerator. The corrosion stability of the powder polyester coating was evaluated by electrochemical impedance spectroscopy (EIS), adhesion by pull-off and NMP test, while surface morphology of phosphate coatings were investigated by atomic force microscopy (AFM).The adhesion and corrosion stability of powder polyester coatings were improved with pretreatment based on iron-phosphate coating deposited from NaNO2-free bath. 相似文献
8.
Lj.S. Živković B.V. Jegdić J.P. Popić J.B. Bajat V.B. Mišković-Stanković 《Progress in Organic Coatings》2013
Cerium-based conversion coatings (CeCCs) are one of the most prospective alternatives to the widely used chromate conversion coatings (CCCs) due to their anticorrosion efficiency, environmentally friendly nature and low cost. In this work, the CeCCs on AA6060 were prepared by immersion into aqueous cerium salt solutions at room temperature, and subsequently post-treated in heated phosphate solution. The effect of counter ion (nitrate and chloride) on the coating properties was studied testing CeCCs as sole or conversion layers for the top polyester coating. Since the 60 μm thick polyester coating was applied, an artificial defect of 0.8 mm hole was introduced to faster assess the differences between pretreatments. The system with CCC pretreatment was used as reference. Corrosion properties were investigated in 0.5 M NaCl solution by electrochemical impedance spectroscopy while the adhesion strength was measured by NMPR (N-methyl-2-pyrrolidone) and pull-off tests. As shown, the post-treated chloride-based CeCC offered better protection than crack-free thin nitrate-based CeCC, when used as sole coatings. On the other hand, it was brought to evidence that in combination with top powder polyester coating, the CeCC deposited from nitrate solution exhibited better protection compared to protective system pretreated with chloride-based one. Excellent polyester coating adhesion was found independently on aluminium surface pretreatment. 相似文献
9.
Y Zhu ML Moreno E Porqueras E Bourke A Bruzzi M Aletrari P Kanari D Partasidou J Nienhuis W Ferigo JL Robert JH Miller JM Spieser E Roets J Hoogmartens 《Canadian Metallurgical Quarterly》1996,14(8-10):1151-1156
A liquid chromatographic method for the analysis of ampicillin was examined in a collaborative study involving seven laboratories. The method included an isocratic part, which is used in the assay. The isocratic part is similar to the assay method for ampicillin of the US Pharmacopeia XXIII Revision. When the isocratic part is combined with gradient elution, the method is suitable for purity control. Six samples of ampicillin (anhydrous, trihydrate and sodium salt) with varying purity were analysed. The main component and related substances were determined. An analysis of variance proved the absence of consistent laboratory bias. The laboratory-sample interaction was significant. Estimates of the repeatability and reproducibility of the method, expressed as standard deviations of the result of the determination of ampicillin, were calculated to be about 0.9 and 1.1 respectively. 相似文献
10.
Jarosław Markowski Monika Zbrzeźniak Monika Mieszczakowska-Frąc Krzysztof Rutkowski Wioletta Popińska 《LWT》2012,49(2):263-266
BackgroundPears due to low acidity are a suitable raw material for the production of multifruit nectars thus it is justified to determine the chemical composition and investigate the effect of cultivar and fruit maturity on juices quality.MethodsJuices from ‘Alexander Lucas’ and ‘Conference’ cultivars were produced after harvest and after 3 months of pears storage.ResultsAverage yield of clear juices was 76.4% for ‘Conference’ cultivar and 74.3% for ‘Alexander Lucas’. In the case of cloudy juices, the yield was lower by about 3%. Processing of ‘Conference’ cv. from stored fruit resulted in yield decrease compared to fruits after harvest; this was not in case of ‘Alexander Lucas’ in 2008, where juices produced from stored fruits were characterized by a higher yield compared to fresh fruit.Total solids content in clear juices was 125–135 g/L and 135–141 g/L for cloudy juices. ABTS●+ and total phenolics analysis showed that cloudy juices were characterized by a higher antioxidant activity and phenolics content than the clear ones.ConclusionPear storage, on the contrary to apples, does not decrease their suitability for cloudy juice production. Cloudy juices as a rule have higher antioxidant activity than the clear ones. 相似文献