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排序方式: 共有1061条查询结果,搜索用时 15 毫秒
1.
Nur Lina Rashidah Mohd Rashid Abdullah Abdul Samat Abdul Azim Jais Mahendra Rao Somalu Andanastuti Muchtar Nurul Akidah Baharuddin Wan Nor Roslam Wan Isahak 《Ceramics International》2019,45(6):6605-6615
The performance of low-to-intermediate temperature (400–800?°C) solid oxide fuel cells (SOFCs) depends on the properties of electrolyte used. SOFC performance can be enhanced by replacing electrolyte materials from conventional oxide ion (O2-) conductors with proton (H+) conductors because H+ conductors have higher ionic conductivity and theoretical electrical efficiency than O2- conductors within the target temperature range. Electrolytes based on cerate and/or zirconate have been proposed as potential H+ conductors. Cerate-based electrolytes have the highest H+ conductivity, but they are chemically and thermally unstable during redox cycles, whereas zirconate-based electrolytes exhibit the opposite properties. Thus, tailoring the properties of cerate and/or zirconate electrolytes by doping with rare-earth metals has become a main concern for many researchers to further improve the ionic conductivity and stability of electrolytes. This article provides an overview on the properties of four types of cerate and/or zirconate electrolytes including cerate-based, zirconate-based, single-doped cerate–zirconate and hybrid-doped cerate–zirconate. The properties of the proton electrolytes such as ionic conductivity, chemical stability and sinterability are also systematically discussed. This review further provides a summary of the performance of SOFCs operated with cerate and/or zirconate proton conductors and the actual potential of these materials as alternative electrolytes for proton-conducting SOFC application. 相似文献
2.
Muhammad Sheeraz Mamoon Ur Rashid Asad Ali Fazli Akram Ho Jeong Lee Jin San Choi Jong-Seong Bae Yong Soo Kim Young-Han Shin Chang Won Ahn Tae Heon Kim 《Journal of the European Ceramic Society》2021,41(10):5155-5162
We demonstrate the structural evolution of polymorphic phases in Al2O3-inserted SrMnO3 ceramics synthesized by solid state reaction. While the 4H-hexagonal phase is predominant in pure SrMnO3 ceramics, a small amount of 6H-hexagonal polymorph is identified in addition to the primary 4H-hexagonal SrMnO3 and the secondary hexagonal SrAl2O4 phases in the as-sintered ceramics, evidenced by x-ray diffraction and subsequent Rietveld refinement analyses. The existence of the 6H-hexagonal SrMnO3 phase is corroborated using Raman spectroscopy. The chemical compositions and electronic structures of the Al2O3-inserted SrMnO3 compounds are also examined using energy dispersive spectroscopy and x-ray photoelectron spectroscopy, respectively. The first-principles calculations reveal that there is no clear difference between the total energies of 4H- and 6H-hexagonal polymorphs regardless of the presence/absence of Sr and oxygen vacancies. Possible origins are discussed with the estimation of actual strain based on the refined lattice parameter of 6H SrMnO3. 相似文献
3.
M. M. Rashid 《International journal for numerical methods in engineering》2002,55(4):431-450
A computational procedure for remapping material state information from one finite element mesh to another is described. The procedure is useful in connection with evolving meshes for inelastic problems, as for example occur in the context of fracture simulation and adaptive mesh refinement. The proposed method is based on weak enforcement of equality between corresponding fields on the two meshes, where piecewise‐constant fields on both meshes are generalized from the quadrature‐point values. The essential algorithmic problem is that of calculating the volume partition of an arbitrary convex region with respect to a covering set of disjoint convex regions. Instead of geometrically resolving the associated intersections, the problem is herein approximated by a constrained optimization problem, which may be readily and efficiently solved computationally. This formulation is a main contribution of the paper. Computational examples are given that illustrate the effectiveness of the proposed procedure. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
4.
Numerical Modeling of Silicon Photodiodes for High-Accuracy Applications Part I. Simulation Programs
Jon Geist Deane Chandler-Horowitz A. M. Robinson C. R. James 《Journal of research of the National Institute of Standards and Technology》1991,96(4):463-469
The suitability of the semiconductor-device modeling program PC-1D for high-accuracy simulation of silicon photodiodes is discussed. A set of user interface programs optimized to support high-accuracy batch-mode operation of PC-1D for modeling the internal quantum efficiency of photodiodes is also described. The optimization includes correction for the dark current under reverse- and forward-bias conditions before calculating the quantum efficiency, and easy access to the highest numerical accuracy available from PC-1D, neither of which is conveniently available with PC-1D’s standard user interface. 相似文献
5.
Castonguay Louis G.; Schut Alexander J.; Aikens Deane E.; Constantino Michael J.; Laurenceau Jean-Philippe; Bologh Laura; Burns David D. 《Canadian Metallurgical Quarterly》2004,14(1):4
This study is a preliminary investigation of an integrative treatment aimed at improving the efficacy of cognitive therapy (CT) for depression. The development of the treatment protocol was based on process findings, which suggested that strategies used in CT to resolve alliance ruptures may actually exacerbate problems in the therapeutic relationship. The protocol integrates, within the traditional CT treatment manual, procedures to repair alliance ruptures that are derived from or consistent with humanistic and interpersonal therapies. Although conducted by inexperienced therapists, the integrative treatment led to greater improvement than a waiting-list condition. The results also compare favorably to previous findings for CT. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
6.
Improvement of power supply EMC by chaos 总被引:12,自引:0,他引:12
The authors demonstrate the feasibility of using chaos to depress the spectral peaks of the interference from a switched mode power supply. A boost converter is used to show experimentally that the spectrum of the input current is spread, its peaks are reduced and EMC is improved, compared to the case when the circuit is operating periodically 相似文献
7.
Touqeer Haseeb Zaman Shakir Amin Rashid Hussain Mudassar Al-Turjman Fadi Bilal Muhammad 《The Journal of supercomputing》2021,77(12):14053-14089
The Journal of Supercomputing - The Internet of Things is a rapidly evolving technology in which interconnected computing devices and sensors share data over the network to decipher different... 相似文献
8.
One strategy for alleviating excess latency (delay) in the Internet is the caching of web content at multiple locations. This
reduces the number of hops necessary to reach the desired content. This strategy is used for web content such as html pages,
images, streaming video, and Internet radio. The network of servers which store this content, and the collections of objects
stored on each server, is called a content distribution network (CDN). In order to optimally design a CDN, given a network
topology with available server storage capacity at various points in the network, one must decide which object collections
to place on each server in order to achieve performance or cost objectives. The placements must be within the storage limits
of the servers and must reflect the request patterns for each collection of objects to be cached. Researchers have suggested
formulations for the CDN problem which address performance by minimizing latency (the average number of hops is a commonly
accepted measure of latency) from client to content, or formulations that focus on minimizing cost of storage and/or bandwidth.
In this research, we develop a model which allows for the simultaneous treatment of performance and cost, present examples
to illustrate the application of the model and perform a detailed designed experiment to gain insights into cost/hops tradeoff
for a variety of network parameters. 相似文献
9.
Pavel L. Katsel Tamara M. Dmitrieva Rashid B. Valeyev Yuri P. Kozlov 《Journal of chemical ecology》1992,18(11):2003-2010
Three components of the male yellowfin Baikal sculpin pheromonal signal have been isolated from urine by diethyl ether extraction, thinayer chromatography (TLC), and high-performance liquid chromatography (HPLC). Using mass spectrometry, we have identified two of them as testosterone (T) and 11-hydroxytestosterone (11HT). These steroids are synthesized in testes during full spermatogenesis, and they are excreted in male urine with milt. The third component is not a steroid. It is more likely to be a polyene alcohol (farnesol). 2Z,6E-Farnesol possesses behavioral activity. 相似文献
10.
The behavioral and physiological effects of plant allelochemicals have been difficult to demonstrate; it is not often clear whether the compounds are deterrent, toxic, or both. In this study, we compared the qualitative and quantitative effects of several iridoid glycosides on a generalist lepidopteran herbivore,Spodoptera eridania (Noctuidae). Larval growth and survivorship and larval preference or avoidance were measured on artificial diets containing different iridoid glycosides at different concentrations. We also tested the toxicity/deterrence of these compounds. We found that iridoid glycosides retarded larval growth significantly at relatively low concentrations and that they were usually avoided in preference tests. The toxicity/ deterrence test did not always reflect the results of these other tests. The merits of using a variety of methods for determining deterrence and/or toxicity of plant allelochemicals are discussed. 相似文献