Functional copolymer of geraniol and acrylonitrile: Synthesis and characterization

The radical copolymerization of acyclic terpene namely geraniol [GER] with acrylonitrile [AN] in DMF at (70 ± 0.1)°C for 1 h, using benzoylperoxide (BPO) as an initiator has been carried out under inert atmosphere of nitrogen. The kinetic expression for reaction is R_p ∝ [BPO]^0.5 [AN]^1.0 [GER]^1.0. The IR spectrum of the copolymer shows bands at 3432 and at 2244 cm^?1 due to ? OH group of GER and ? CN group of AN, respectively. The ¹³C‐NMR spectrum shows peaks at 73–75 δ ppm and 116–120 δ ppm due to ? OH group of GER and ? CN group of AN, respectively. The thermogravimetric analysis and differential scanning calorimetry study shows that copolymer is thermally stable up to 407°C and has glass transition temperatures (T_g) 56°C. The reactivity ratios r₁ (AN) and r₂ (GER) have been calculated as 0.05 and 0.005, respectively. The Alfrey‐Price Q‐e parameter for GER has been calculated as 0.094 and ?2.0, respectively. The molecular weights of the copolymers have been evaluated by gel‐permeation chromatography. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

2,2′-oxo-1,1′-azobenzene: microbial transformation of rye (Secale cereale L.) allelochemical in field soils byAcinetobacter calcoaceticus: III

Acinetobacter calcoaceticus, a gram-negative bacterium isolated from field soil, was found to be responsible for the biotransformation of 2(3H)-benzoxazolinone (BOA) to 2,2-oxo-1,1-azobenzene (AZOB). Experiments were conducted to evaluate the transformation of BOA to AZOB by this microbe in sterile and nonsterile soil. Transformation studies with soils inoculated withA. calcoaceticus indicated that the production of AZOB increased linearly with the concentration of BOA in sterile soil and showed a quadratic trend in nonsterile soils. This also indicated that all soil types studied for the transformation experiments might containA. calcoaceticus capable of the conversion of benzoxazolinones.     

Fuzzy logic techniques for navigation of several mobile robots

In this paper, navigation techniques for several mobile robots as many as one thousand robots using fuzzy logic are investigated in a totally unknown environment. Fuzzy logic controllers (FLC) using different membership functions are developed and used to navigate mobile robots. First a fuzzy controller has been used with four types of input members, two types of output members and three parameters each. Next two types of fuzzy controllers have been developed having same input members and output members with five parameters each. Each robot has an array of ultrasonic sensors for measuring the distances of obstacles around it and an infrared sensor for detecting the bearing of the target. These techniques have been demonstrated in various exercises, which depicts that the robots are able to avoid obstacles as well as negotiate the dead ends and reach the targets efficiently. Amongst the techniques developed, FLC having Gaussian membership function is found to be most efficient for mobile robots navigation.     

Extreme learning machine and bayesian optimization-driven intelligent framework for IoMT cyber-attack detection

The Journal of Supercomputing - The Internet of Medical Things (IoMT) is a bionetwork of allied medical devices, sensors, wearable biosensor devices, etc. It is gradually reforming the healthcare...     

床沙表层非均匀分布对泥沙输移的影响

本文基于床沙宽度百分比及面积百分比的分析，选择上述二者有关参数来反映床沙表层不均匀分布特征，并由此得到了床沙不受隐蔽作用的最大粒径Ｄａ与面积平均粒径ｄｓ之关系。借助力学分析方法，分别得到了隐蔽区与暴露区的泥沙起动流速公式；同时，在输沙率关系中引入了宽度百分比Ｐｂ及ｄｓ，该式能较好地反映床沙粗化过程中，输沙率与表层泥沙组成之间的依存关系。     

Design of robust model-based controllers via parametric programming

In this paper a method is presented for deriving the explicit robust model-based optimal control law for constrained linear dynamic systems. The controller is derived off-line via parametric programming before any actual process implementation takes place. The proposed control scheme guarantees feasible operation in the presence of bounded input uncertainties by (i) explicitly incorporating in the controller design stage a set of feasibility constraints and (ii) minimizing the nominal performance, or the expectation of the performance over the uncertainty space. An extension of the method to problems involving target point tracking in the presence of persistent disturbances is also discussed. The general concept is illustrated with two examples.     

A review of particle swarm optimization and its applications in Solar Photovoltaic system

Particle swarm optimization is a stochastic optimization, evolutionary and simulating algorithm derived from human behaviour and animal behaviour as well. Special property of particle swarm optimization is that it can be operated in continuous real number space directly, does not use gradient of an objective function similar to other algorithms. Particle swarm optimization has few parameters to adjust, is easy to implement and has special characteristic of memory. Paper presents extensive review of literature available on concept, development and modification of Particle swarm optimization. This paper is structured as first concept and development of PSO is discussed then modification with inertia weight and constriction factor is discussed. Issues related to parameter tuning, dynamic environments, stagnation, and hybridization are also discussed, including a brief review of selected works on particle swarm optimization, followed by application of PSO in Solar Photovoltaics.     

Autonomous bioremediation of a microbial protein (bioremediase) in Pozzolana cementitious composite

The self-bioremediation in cementitious composite material is one of the most interesting avenues relating to damage management and self-life of constructions, which needs to be cogitated. The self-bioremediation of a microbial protein-impregnated cementitious material has been explored in this work. The bioremediase protein was isolated from a hot spring bacterium (BKH1) and incorporated at three different concentrations into commercial Pozzolana cements that are widely used for mortar sample preparation. Artificial cracks were generated within the mortar samples by applying partial breaking load (50 %) and the samples were cured under water for different days. Image analysis by Crackscope and microstructure analysis by field emission scanning electron microscope ascertained the formation of irregular crystalline healing material within the cracks of the test samples. X-ray diffractometer and energy dispersive spectra analyses confirmed that the irregular crystalline structures were due to the deposition of new silicate phase (Gehlenite) within the cracks. Increase of ultrasonic pulse velocity and compressive strength, augmentation of sulphate resistance, decrease of chloride permeability and water absorption capacity revealed that there were overall improvement of mechanical properties and durability of the protein-incorporated mortar samples compared to the control (without protein incorporation) mortar samples. This cost effective and eco-friendly self-bioremediation phenomenon observed in mortar is evolved due to the biosilicification activity of bioremediase protein when amended in mortar samples. The exceptional potential of the microbial bioremediase protein for self-bioremediation attribute may add a new dimension in self-healing construction technology in near future.