Thermal Conductivity and Viscosity of Nanofluids Having Nanoencapsulated Phase Change Material

In this study, the thermal conductivity and viscosity of nanofluids, composed of a base fluid and nanoencapsulated phase change material (NEPCM), were investigated experimentally. The NEPCM was prepared by the encapsulation of n-nonadecane as phase change material with diethylenetriamine and toluene-2,4-diisocyanate using interfacial polymerization method. The NEPCM was characterized using scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), and differential scanning calorimetry (DSC) analyses. In the preparation of the nanofluids containing NEPCM, two different base fluids, water and ethylene glycol (EG), were used. The concentration of NEPCM and the working temperature were selected as the main parameters. It was found that the viscosity of the nanofluids decreases with increasing temperature and increases with increasing solid concentration. The viscosity was also expressed as a function of the solid concentration and temperature. The thermal conductivity of the nanofluids was found to increase with increasing temperature. Thermal conductivity exhibited an increasing tendency with increasing solid concentration, but the changes in thermal conductivity according to base fluid are in the range of uncertainty of the measurement for both nanofluids with a solid volumetric fraction lower than 1.68%.     

Monitoring of Zn(II), Cd(II), Pb(II) and Cu(II) During Refining of Some Vegetable Oils Using Differential Pulse Anodic Stripping Voltammetry

In this study, a novel approach has been developed using differential pulse anodic stripping voltammetry (DPASV) for the simultaneous determination of Zn(II), Cd(II), Pb(II) and Cu(II) in edible oils at hanging mercury drop electrode. The microwave digestion of oil samples was carried out with concentrated HNO₃ and H₂O₂. KNO₃ was used as a supporting electrolyte. The experimental conditions optimized such as deposition time, stirring rate and size of mercury drop were 300 s, 600 rpm and 10 mm², respectively. The method was applied to quantify Zn(II), Cd(II), Pb(II) and Cu(II) in crude and refined hazelnut, corn, sunflower and olive oils. During refining of different vegetable oils, the removal efficiencies of Zn(II), Cd(II), Pb(II) and Cu(II) were calculated as 98.20–99.91, 98.50–99.90, 95.26–99.76 and 95.93–99.92 %, respectively. The limits of detection for Zn(II), Cd(II), Pb(II) and Cu(II) were 2.1?×?10^?8, 8.7?×?10^?10, 7.1?×?10^?9 and 3.4?×?10^?9 and the limits of quantification were 6.8?×?10^?8, 2.9?×?10^?9, 2.3?×?10^?8 and 1.1?×?10^?8 M with linear regression coefficients (R ²) of 0.9930, 0.9928, 0.9893 and 0.9931, respectively. It was observed that the above metals in crude and refined vegetable oils could be determined simultaneously by the DPASV method.