Spatial and seasonal variations and ecotoxicological significance of sediment trace metal concentrations in Kebir-Rhumel basin (Northeast of Algeria)

This study sought to assess sediment contamination by trace metals (cadmium, chromium, cobalt, copper, manganese, nickel, lead and zinc), to localize contaminated sites and to identify environmental risk for aquatic organisms in Wadis of Kebir Rhumel basin in the Northeast of Algeria. Water and surficial sediments (0-5 cm) were sampled in winter, spring, summer and autumn from 37 sites along permanent Wadis of the Kebir Rhumel basin. Sediment trace metal contents were measured by Flame Atomic Absorption Spectroscopy. Trace metals median concentrations in sediments followed a decreasing order: Mn > Zn > Pb > Cr > Cu > Ni > Co > Cd. Extreme values (dry weights) of the trace metals are as follows: 0.6-3.4 microg/g for Cd, 10-216 microg/g for Cr, 9-446 microg/g for Cu, 3-20 microg/g for Co, 105-576 microg/g for Mn, 10-46 microg/g for Ni, 11-167 microg/g for Pb, and 38-641 microg/g for Zn. According to world natural concentrations, all sediments collected were considered as contaminated by one or more elements. Comparing measured concentrations with American guidelines (Threshold Effect Level: TEL and Probable Effect Level: PEL) showed that biological effects could be occasionally observed for cadmium, chromium, lead and nickel levels but frequently observed for copper and zinc levels. Sediment quality was shown to be excellent for cobalt and manganese but medium to bad for cadmium, chromium, copper, lead, nickel and zinc regardless of sites.     

Assessment of sediment quality and pore water ecotoxicity in Kebir Rhumel basin (NE-Algeria): a combined approach

The objectives of this study are to use different approaches to assess the current pollution status in the wadis of the Kebir Rhumel basin. First, sediment trace metal contents were measured by flame atomic absorption spectroscopy. Then, sediment quality was assessed on the basis of contamination assessment indexes such as: Geoaccumulation Index (Igeo), Contamination factor (C(f)), Contamination degree (C(d)), Sediment Pollution Index (SPI) and SEQ guidelines (Consensus Sediment Quality Guidelines). In addition, several toxicity tests (Daphnia magna mobility inhibition acute test-48 h, Aliivibrio fischeri luminescence inhibition acute test - 15/30 mn and Pseudokirchneriella subcapitata growth inhibition chronic test - 72 h) were conducted to assess sediment pore water ecotoxicity. Trace metal concentrations followed the order: Mn > Zn > Pb > Cr > Cu > Ni > Co > Cd. Indexes used indicate varying degrees of sediment quality. Igeo, C(f), C(d) and SPI reveal a polymetallic contamination dominated by two or more elements in which Cd, Cu and Pb are of greatest concern. SEQ guidelines showed that biological effects on fauna would likely be observed occasionally and/or frequently for Cd, Cr, Cu, Pb and Zn contents. Test organisms exposed to sediment pore water showed that the algal P. subcapitata test was more sensitive than the D. magna and A. fischeri tests. Hence, algal growth inhibition proved to be the most sensitive response to contaminants present in sediment extracts but a significant relationship with trace metal contents was not demonstrated.     

Kinetics and Thermodynamics of Oil Extraction from Olive Cake

The kinetics of oil extraction from olive cake by using ethanol 96% was studied for different solvent-to-solids ratios and temperatures. The thermodynamic aspect of the extraction process was also examined. In the kinetic study, the results produced by the model of So and Macdonald (a model involving two main mechanisms of oil extraction: a washing process and a diffusion process with two stages) were found to be in good agreement with the experimental data. The yield of oil in the extract increased with increasing contact time, solvent-to-solids ratio and extraction temperature. The calculated values of the mass transfer coefficients of various stages of the extraction were found to increase linearly with solvent-to-solids ratio and temperature. In all cases, the predominant mechanism in the extraction was the washing of the oil occurring on the particle surface. The values of the activation energy were 8.56 kJ mol⁻¹ for the washing stage, 9.88 kJ mol⁻¹ for the first stage of diffusion and 17.55 kJ mol⁻¹ for the second stage of diffusion by changing temperature from 20 to 50 °C. Further, the results obtained from thermodynamic study of extraction process gave positive values of enthalpy and entropy changes and negative values of change in free energy. Under the equilibrium conditions, the temperature coefficient was found to be 1.02.     

Physicochemical Characterization and Antioxidant Activity of Commercial Portuguese Honeys

The present study evaluated the physicochemical characteristics and antioxidant activity of 13 commercial honeys from diverse floral origin, produced in Portugal. The values of electrical conductivity of cardoon and pennyroyal honeys were superior to the maximum limits defined by European legislation. Citrus, strawberry tree, and 1 sample of lavender honeys had values of diastase activity below those determined by European legislation. Strawberry tree, pennyroyal, and cardoon honeys had the highest amounts of potassium that coincided with the highest electrical conductivity. Strawberry tree honey was the most effective as antioxidant along with cardoon and heather honeys. This ability was strongly correlated with the amounts of phenols and flavonoids and not with the levels of vitamin C or proline.     

The dark side of galaxy formation

I discuss the discovery of a population of extremely luminous, but very dusty and very distant, galaxies in the submillimetre (submm) waveband. Almost all the light emitted by the stars in these galaxies is absorbed by interstellar dust (which is produced by the same stars) and re-radiated in the far-infrared. This leaves little to be detected at optical wavelengths and results in most of these galaxies being effectively invisible in even the deepest optical images obtainable with the Hubble space telescope. Yet this population contributes most of the light emitted by galaxies at wavelengths of lambda > or approximately equal 100 microm over the lifetime of the Universe. Together with other observations, this suggests that perhaps up to half of all the stars seen in galaxies today were formed in very dusty regions in the early Universe. Hence, studying the galaxies detected in the submm wavebands is critical for developing and testing models of galaxy formation and evolution. Individually, these luminous submm galaxies are forming stars a thousand times faster than our Galaxy is at the present-day, sufficiently fast to form all the stars in the most luminous galaxy in the local Universe within a short period, up to ca. 0.1-1 Gyr. Detailed study of a handful of examples of this population confirm these estimates and unequivocally identify the bulk of this submm-selected population with dusty, star-burst galaxies in the very distant Universe. The extreme faintness of this population in the optical and near-infrared wavebands, resulting from their obscuration by dust, means that our understanding of the detailed nature of these galaxies is only slowly growing. I give a brief summary of the properties of these highly obscured systems and describe the wide range of facilities currently being developed that will greatly aid in their study.     

A comparative study of recent relay autotuning methods for multivariable systems

A typical procedure for designing multivariable controllers is the following: build a model for the multivariable process, choose the control structure, calculate the control parameters, test the controller (possibly with simulation) and then retune controller parameters as necessary. This procedure is complex and time consuming even for scalar control loops. For multivariable controllers, the procedure is even more daunting. Automation of the design method is and has been a concern of many researchers. There has been a large number of papers on relay autotuning of control systems. The choice of relay feedback to solve the design problem is justified by the possible integration of system identification and control into the same design strategy, giving birth to relay autotuning. In this paper, nine different relay autotuning methods for multivariable systems are compared. Most of these methods have common basics but they may differ in the tuning procedure, convergence, identification method, control structure and performance achievement. The paper summarizes these methods and investigates the advantages and drawback of each algorithm.     

Direct activity of human T lymphocytes and natural killer cells against Cryptococcus neoformans

Lymphocytes constitute a critical component of host defenses against cryptococcosis. Previously, we demonstrated that human lymphocytes cultured with interleukin-2 formed conjugates with, and directly inhibited the growth of, Cryptococcus neoformans. Here, we explore the anticryptococcal activity of freshly isolated, highly purified populations of human peripheral blood lymphocytes. Lymphocytes were incubated with encapsulated C. neoformans for 24 h, after which the lymphocytes were lysed, dilutions and spread plates were made, and CFU were counted. Fungistasis was determined by comparing growth in wells with and without lymphocytes. Nylon wool-nonadherent peripheral blood mononuclear cells (NWNA PBMC) were highly fungistatic, even if either T cells or natural killer (NK) cells were depleted by panning. A mixed population of T cells and NK cells, obtained by rosetting NWNA PBMC with sheep erythrocytes, completely inhibited cryptococcal growth, whereas the nonrosetting cells had little fungistatic activity. CD4+, CD8+, and CD16/56+ lymphocytes, isolated by positive immunoselection, had potent growth-inhibitory activity. In contrast, purified B cells had no activity. Fungistasis was seen even in the absence of opsonins. Antifungal activity was markedly diminished when surface receptors on NWNA PBMC were cleaved by treatment with trypsin or bromelain. Supernatants from stimulated lymphocytes or concentrated lymphocyte sonicates were not active. Lymphocyte-mediated fungistasis was seen with two different strains of C. neoformans. CD4+, CD8+, and CD16/56+ lymphocytes formed conjugates with C. neoformans, as observed under Nomarski differential interference contrast microscopy and videomicroscopy. These data demonstrate that freshly isolated peripheral blood T cells and NK cells have the capacity to bind and directly inhibit the growth of C. neoformans.     

Reciprocal Citizens Exchange: A Confidence-Building Alternative to Nuclear Deterrence

This paper articulates a new and very different approach to deterrence in the nuclear age, one focussed on the underlying causes rather than the more easily visible effects of superpower intransigence, one based on positive rather than negative incentives, and one with the unusual potential to remove barriers (whether perceived or real) between political adversaries rather than continuously to create them. I suggest a deterrent ``force,' or perhaps more appropriately a ``restraining presence,' that uniquely combines inhibition of war-like or destabilizing acts in the short term with the simultaneous enhancement of transnational understanding over the longer term, at all levels of the body politic. Specifically, I propose a highly visible, mutially endorsed and deliberately massive effort by both the U.S. and the U.S.S.R. in support of a confidence-building program involving the reciprocal exchange, from one nation to the other, of large numbers of citizen ``hostages' chosen from all walks of life. Over a period of a generation or more, these carefully-selected and well-prepared volunteers would have the opportunity to lay the psychological and political groundwork for a significant and powerful, yet non-violent and gradual, shift in the conceptualization of deterrence currently endorsed by both superpowers.     

A typology of university student living groups.

Subjected 100 university living groups measured on 10 dimensions of their social environments to cluster analysis to develop an empirically based taxonomy of university living groups. 5 distinctive clusters of living groups were identified: competition oriented, supportive achievement oriented, independence oriented, relationship oriented, and traditionally socially oriented. Clusters showed systematic differences in sex composition (i.e., male, female, and coed), size, and institutional affiliation. Some evidence that different clusters of living groups had different impacts on Ss was presented. It is concluded that an empirically derived taxonomy of the social environments of university living groups is a necessary step in understanding which types of living group programs produce optimal outcomes for various types of students. (31 ref) (PsycINFO Database Record (c) 2010 APA, all rights reserved)