Piezoelectric properties of PVDF-conjugated polymer nanofibers

This study presents the development and characterization of PVDF-conjugated polymer nanofiber-based systems. Five different conducting polymers (CPs) were synthesized successfully and used to create the nanofiber systems. The CPs used are polyaniline (PANI), polypyrrole (PPY), polyindole (PIN), polyanthranilic acid (PANA), and polycarbazole (PCZ). Nanofiber systems were produced utilizing the Forcespinning® technique. The nanofiber systems were developed by mechanical stretching. No electrical field or post-process poling was used in the nanofiber systems. The morphology, structure, electrochemical and piezoelectric performance was characterized. All of the nanofiber PVDF/CP systems displayed higher piezoelectric performance than the fine fiber PVDF systems. The PVDF/PPY nanofiber system displays the highest piezoelectric performance of 15.56 V. The piezoelectric performance of the PVDF/CP nanofiber systems favors potential for an attractive source of energy where highly flexible membranes could be used in power actuators, sensors and portable, and wireless devices to mention some.     

The efficiency of private and public schools in urban and rural areas: moving beyond the development goals

Data from the Young Lives study are used to evaluate the efficiency of education systems in four low and middle income countries: Ethiopia, India, Peru and Vietnam. A meta‐frontier variant of data envelopment analysis is used to assess the relative performance of each country's system, and, within each country, to evaluate the impact of public and private schooling, and of urban and rural location. Comparisons are drawn between the four countries; the results indicate that in no country does the educational system perform uniformly badly or well. Conditioning on the inputs available, rural areas are often indicative of higher levels of efficiency, thus suggesting a number of implications for policy.     

Occurrence and characterisation of the hydrogen-evolving enzyme in Frankia sp.

An increase in hydrogen evolution from the hydrogen-evolving enzyme in the actinomycete Frankia was recorded in the presence of nickel. Immunogold localisation analysis of the intracellular distribution of hydrogenase proteins indicated that they were evenly distributed in the membranes and cytosol of both hyphae and vesicles. In addition, molecular characterisation of the hydrogen-evolving enzyme at the proteomic level, using two-dimensional gel electrophoresis combined with mass spectrometry, confirmed that the Frankia hydrogen-evolving enzyme is similar to the cyanobacterial bidirectional hydrogenase of Anabena siamensis.     

Studies on the dielectric and relaxor behavior of sol-gel derived barium strontium zirconate titanate thin films

The dielectric behavior of sol-gel derived Ba_0.80Sr_0.20(Zr_xTi_1−x)O₃ (0.0 ≤ x ≤ 0.50) thin films is studied. A relaxor behavior is observed for x ≥ 0.35. The degree of relaxation increases with Zr content. The frequency dependence of the polar regions follows Vogel-Fulcher relation with a characteristic cooperative freezing at freezing temperature (T_f). Below T_f, a long range polarization ordering is likely to take place. The plausible mechanism of the relaxor behavior of BSZT thin films with Zr contents ≥ 0.35 has been proposed based on the measured temperature as well as frequency dependent dielectric data. The solid solution system is visualized as a mixture of Ti^+ 4 rich polar regions and Zr^+ 4 rich regions; with the increase in Zr content the volume fraction of the polar regions is progressively reduced. At and above 35.0 at.% Zr substitution the polar regions exhibit typical relaxor behavior.     

Unified modeling technique for high-viscosity,melt-phase,condensation polymer reactors

Mathematical models for chemical reaction and mass transfer occurring in the manufacture of high-viscosity condensation polymers are considered. A preliminary study indicates that several diverse models can be represented using a single formula based upon an effectiveness factor. The effectiveness factor is shown to depend upon a ratio of time scales of mixing and reaction. The formula giving the effectiveness factor in terms of the time scales ratio is shown to depend upon mixing assumptions only. Starting with a mixing-cell model, a new modeling framework is developed and shown to include the previous models as special cases. The framework is free of inherent mixing assumptions and can be applied to a wide variety of situations once the mixing characteristics are specified. © 1993 John Wiley & Sons, Inc.     

Microwave-Assisted Synthesis of Fine Particle Oxides Employing Wet Redox Mixtures

Interaction of electromagnetic radiation with a physical mixture of metal nitrates and amides/hydrazides is observed to initiate high-temperature reactions, useful for realizing several high-temperature ceramic materials. A judicious choice of such redox mixtures undergoes exothermic reactions when they couple with microwave radiation. The coupling of electromagnetic radiation with metal salts and amides/hydrazides depends on the dielectric properties of the individual components in the reaction mixture. The approach has been used to prepare γ-Fe₂O₃, Fe₃O₄, MgCr₂O₄, α-CaCr₂O₄, and La_0.7Ba_0.3MnO₃.     

Favorable influence of ssDNA-functionalized SWCNT on the navigation pattern of C. elegans

Microsystem Technologies - Single-Walled Carbon Nanotubes (SWCNTs) are widely used as potential carriers in drug delivery systems. The objective of this work was to observe the effects of pristine,...     

Quantifying DNS namespace influence

Name resolution using the Domain Name System (DNS) is integral to today’s Internet. The resolution of a domain name is often dependent on namespace outside the control of the domain’s owner. In this article we review the DNS protocol and several DNS server implementations. Based on our examination, we propose a formal model for analyzing the name dependencies inherent in DNS. Using our name dependency model we derive metrics to quantify the extent to which domain names affect other domain names. It is found that under certain conditions, more than half of the queries for a domain name are influenced by namespaces not expressly configured by administrators. This result serves to quantify the degree of vulnerability of DNS due to dependencies that administrators are unaware of. When we apply metrics from our model to production DNS data, we show that the set of domains whose resolution affects a given domain name is much smaller than previously thought. However, behaviors such as using cached addresses for querying authoritative servers and chaining domain name aliases increase the number and diversity of influential domains, thereby making the DNS infrastructure more vulnerable.     

Extensive Study of Underlap Length Effect for 3-D SOI FinFET to Achieve High Switching Ratio and Low Power

Silicon - The primary purpose of this work is to study the effect of symmetric and asymmetric variation of underlap regions both on source and drain side of 3D SOI n-FinFET. Underlap length is...