Continuous precipitation of calcium sulfate dihydrate from waste sulfuric acid and lime

Precipitation of calcium sulfate dihydrate, gypsum, from (i) a pure sulfuric acid/lime suspension and (ii) a waste sulfuric acid/lime suspension in a continuous pilot plant in the temperature range from 40 °C to 80 °C was studied. It was observed that in the case of waste sulfuric acid with a high content of Mg²⁺ and Fe²⁺ ions, several hours after the beginning of the precipitation, partial dissolution of the product and modification of the crystals from needle‐ and plate‐like to agglomerated structures occurred. It is suggested that the secondary changes occur due to the increased concentration of Mg²⁺ and Fe²⁺ ions in the reactor. Below 60 °C, and above 70 °C plate‐like and needle‐like single crystals respectively were formed. The mean size (d₅₀) of the crystals was found to increase with increasing temperature and decrease with the initial concentration of lime. Gypsum produced between 70 °C and 80 °C is suitable for further processing for construction plaster. In a precipitation process with pure sulfuric acid only single perfect needle‐like crystals occurred. Copyright © 2005 Society of Chemical Industry     

Mapping the Characteristics of a 'Good' Play Therapist.

In this pilot study, concept mapping, a methodological approach combining qualitative and quantitative analytic strategies, was used to identify the therapist qualities, competencies, and skills necessary for effective play therapy outcomes as perceived by a sub-sample of 28 experienced play therapists who are members of the Association for Play Therapy (APT). The clusters associated with the therapeutic relationship and facilitative skills (e.g., empathy, warmth, and genuineness) were rated as the most essential skills to possess and also as the most difficult to develop. In contrast, the clusters associated with play therapy interventions and theories were rated as the least important skills to possess but as the easiest to acquire. The findings are discussed, with implications for therapeutic practice, research, and policy. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Fluage à long terme du bois fléchi en grandeur structurale

Résumé Cet article présente un modèle permettant de calculer le fluage de poutres fléchies de différentes sections soumises à des environnements variables en ce qui concerne l'humidité relative. Ce modèle est utilisé ici pour interpréter de nouveaux essais à long terme sur des poutres en bois massif et lamellé-collé qui ont été chargées pendant plus de 800 jours en conditions extérieures sous abri à Paris

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Summary Long term bending experiments on full size timber and glulam beams have been carried out under external and sheltered climatic conditions in Paris, and more than two years of test results on the creep behaviour of 75 beams are available. A model for predicting the long term mechanical behaviour of timber under variable humidity and load conditions, previously developed by the author, is described. The model is based on transient moisture transfer analysis linked with deformation analysis using a step-by-step computation scheme, and has been compared previously with experiments carried out under laboratory conditions of controlled variable climates by the author as well as with test results obtained from several other institutions. In general, the model has agreed satisfactorily with the experimental results. In the present paper the model is compared with experiments on full size beams carried out under the changeable conditions of a natural climate. The results show that, for low stress levels and corresponding loads, the model provides a reasonable prediction of the end creep levels after two years of loading.

     

Metallocene‐based functionalized polyolefins as compatibilizers in polyolefin nanocomposites

This article reports a study of some functionalized polyolefins evaluated as compatibilizers in polyethylene nanocomposites. The functionalized polymers were prepared by direct metallocene‐mediated copolymerizations of ethylene and a functional comonomer. The prepared nanocomposites were evaluated for mechanical and barrier property enhancement. A good combination of mechanical and barrier properties was obtained with the metallocene‐based functionalized polyethylene. The toughness–stiffness balance was better than or comparable to that achieved with conventional functionalized polymers such as maleic anhydride grafted polyethylene. The results also indicated that these metallocene‐based functionalized polyolefins, when used as compatibilizers, could have relatively higher molar masses and lower functionality than those of conventional post‐reactor‐modified compatibilizers, and so the drawbacks associated with the latter could be avoided. Their inherent properties could also further improve the final nanocomposite properties. This was attributed to the more homogeneous nature of metallocene‐catalyzed polymers in comparison with post‐reactor‐modified products. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 1094–1100, 2004     

Thermal cure monitoring of phenolic resole resins based on in situ fluorescence technique

The thermal curing reaction of two phenolic resole resins is monitored using the fluorescence technique. The intrinsic fluorescence can be used as an indicator for cure monitoring for the first resole. As the thermal curing proceeds, the intrinsic fluorescence intensity of the resole resin decreases and exhibits a few nanometers of redshift. The fluorescence intensity of the emission maxima is correlated with the conversion measured by differential scanning spectroscopy. A linear correlation is found at three different temperatures. The intrinsic fluorescence cannot always be used for monitoring the curing process of phenolic resole resins. Thus, three intramolecular charge transfer compounds and two organic donor–π‐acceptor salts are selected and applied for the cure monitoring of the second phenolic resole resin. As the curing reaction proceeds, the fluorescence emission spectra of the probes exhibit a blue spectral shift and the intensity changes because of environmental changes. An intensity ratio method is applied in which the ratios of the low‐ to high‐intensity changes in the emission bands are used to determine the degree of the curing process. There is a smooth correlation between the intensity ratio method and the degree of cure. The method enables one to follow the changes in the polymer structure at low and intermediate degrees of the curing process (below 70%) and obtain comparable results from different types of probes during the same curing process. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 1773–1780, 2002     

Differences in cytocompatibility,dynamics of the oxide layers’ formation,and nickel release between superelastic and thermo-activated nickel–titanium archwires

Superelastic (SE) and thermo-activated (TA) nickel–titanium (NiTi) archwires are used in everyday orthodontic practice, based on their acceptable biocompatibility and well-defined shape memory properties. However, the differences in their surface microstructure and cytotoxicity have not been clearly defined, and the standard cytotoxicity tests are too robust to detect small differences in the cytotoxicity of these alloys, all of which can lead to unexpected adverse reactions in some patients. Therefore, we tested the hypothesis that the differences in manufacture and microstructure of commercially available SE and TA archwires may influence their biocompatibility. The archwires were studied as-received and after conditioning for 24 h or 35 days in a cell culture medium under static conditions. All of the tested archwires, including their conditioned medium (CM), were non-cytotoxic for L929 cells, but Rematitan SE (both as received and conditioned) induced the apoptosis of rat thymocytes in a direct contact. In contrast, TruFlex SE and Equire TA increased the proliferation of thymocytes. The cytotoxic effect of Rematitan SE correlated with the higher release of Ni ions in CM, higher concentration of surface Ni and an increased oxygen layer thickness after the conditioning. In conclusion, the apoptosis assay on rat thymocytes, in contrast to the less sensitive standard assay on L929 cells, revealed that Rematitan SE was less cytocompatible compared to other archwires and the effect was most probably associated with a higher exposition of the cells to Ni on the surface of the archwire, due to the formation of unstable oxide layer.     

Random binary search tree with equal elements

We consider random binary search trees when the input consists of a multiset, i.e. a set with multiple occurrences of equal elements, and prove that the randomized insertion and deletion algorithms given by Martínez and Roura (1998) [4] produce random search trees regardless of multiplicities; even if all the elements are equal during the tree updates, a search tree will maintain its randomness. Thus, equal elements do not degenerate a random search tree and they need not to be handled in any special way. We consider also stability of a search tree with respect to its inorder traversal and prove that the algorithms used produce stable trees. This implies an implicit indexing of equal elements giving another proof that multiplicities do not pose problems when maintaining random binary search trees.     

Overlap-freeness in infinite partial words

We prove that there exist infinitely many infinite overlap-free binary partial words containing at least one hole. Moreover, we show that these words cannot contain more than one hole and the only hole must occur either in the first or in the second position. We define that a partial word is $k$-overlap-free if it does not contain a factor of the form $xyxyx$ where the length of $x$ is at least $k$. We prove that there exist infinitely many 2-overlap-free binary partial words containing an infinite number of holes.     

On the system of word equations x i 1 x i 2…x i m=y i 1 y i 2…y i n (i=1, 2, …) in a free monoid

 It is proved that the system of word equations x ⁱ ₁=y ⁱ ₁ y ⁱ ₂…y ⁱ _n , i=1, 2,…, ⌈n/2⌉ +1, has only cyclic solutions. Some sharpenings concerning the cases n=5, 7 and n≥9 are derived as well as results concerning the general system of equations x ⁱ ₁ x ⁱ ₂…x ⁱ _m =y ⁱ ₁ y ⁱ ₂…y ⁱ _n , i=1, 2,… . Applications to test sets of certain bounded languages are considered. Received: 18 May 1995/2 January 1996     

Formulation of consistent restoring stiffness in ship hydroelastic analysis

In this article, the role of the restoring stiffness, as one of the basic parameters in ship hydroelastic analysis, is brought out. It is formulated using the variational principle and the method of virtual displacements. It is shown that asymmetry of the restoring stiffness is a physical reality. Moreover, it is confirmed that modal variation, still disputed in the relevant literature, has to be taken into account to satisfy the ship’s stability. Consistent stiffness is formulated here by regarding stiffness definition as relation between forces and displacements. Hybrid stiffness known from the literature is wrong since some terms are specified as relation between forces and displacement gradient. Influence of the consistent and symmetrized stiffness matrix, and the hybrid one, on dynamic response is illustrated for a prismatic pontoon and a large container ship. It is found that the latter two matrices do not assure convergence of transfer functions of sectional forces to zero value as the wave frequency approaches zero. The rigid body and elastic responses are compared, and pertinent conclusions are drawn. It is also shown that it is not necessary to use the unified geometric and restoring stiffness for ordinary hydroelastic analysis of ship structures. The consistent formulation of the restoring stiffness matrix will be useful for extending linear potential theory hydrodynamic codes for rigid body analysis to deformable bodies.