Effect of 100 KeV Ar+ ion beam irradiation on ZnO thin films – Influence of morphology vis-a-vis electrode/electrolyte interface and its impact on photoelectrochemical water splitting

The present study attempts quantitative determination of changes in the morphological surface features viz. fractal dimension, lower and upper cut off length scale through Power Spectral Density analysis prior to and after irradiation of 100 KeV Ar⁺ ion beam at incidence angles of 0°, 40° and 60° on ZnO thin films. All the unirradiated and irradiated samples are subjected to photoelectrochemical characterization and a correlation between photoelectrochemical performance and morphological parameters is established. Sample irradiated at 40° angle at the fluence of 5 × 10¹⁶ ions/cm² is found to possess maximum fractal dimension of 2.72, lower and upper cut off length scale of 3.16 nm and 63.00 nm respectively. This sample exhibits maximum photocurrent density of 3.19 mA/cm² and applied bias photon-to-current efficiency of 1.12% at 1.23 V/RHE. Hydrogen gas collected for duration of 1 h for the same sample was ~4.83 mLcm^?2.     

Mössbauer studies of iron-bearing minerals in coal and coal ash

⁵⁷Fe Mössbauer spectroscopy has been used to characterize the iron-bearing minerals present in some British Columbia coals. The minerals observed in a range of samples include pyrite/marcasite, siderite, jarosite, rozenite or melanterite, and Fe²⁺ -bearing clay minerals such as illite. The presence of jarosite is confirmed through the magnetic hyperfine interaction observed at 4.2 K. The absence of magnetic ordering at 4.2 K for the ferrous sulphate component indicates the presence of rozenite, FeS0₄ · 4H₂0, or melanterite, FeS0₄ · 7H₂0, rather than szomolnokite, FeS0₄ · H₂0 or FeS0₄. The effects of ashing on two of the coals is also studied.     

Augmented photoelectrochemical response of CdS/ZnS quantum dots sensitized hematite photoelectrode

A visible light active and stable photoelectrode has been developed by depositing a passivating layer of ZnS QDs on CdS QDs sensitized hematite photoelectrode (Hematite‐CdS/ZnS) for PEC generation of hydrogen. Photoelectrochemical properties, in terms of stability and efficiency, have been investigated on the various hematite photoelectrodes sensitized with CdS QDs and CdS/ZnS QDs by varying number of SILAR cycles. I–V characteristics show that two layers of ZnS QDs deposited over three layers of CdS could enhance PEC response of hematite and efficiency by a factor of 3 and 11 respectively. Chronoamperometry measurement ensures that after adding a layer of ZnS QDs, CdS sensitized hematite film turns out to be a stable photoelectrode in the electrolyte. Prepared photoelectrodes have been characterized by XRD, SEM, HRTEM and UV–Vis spectrophotometer for various structural, morphological and optical properties to analyze PEC results. Mott–Schottky analysis and incident photon to current conversion efficiency (IPCE) measurements of sensitized hematite photoelectrode supported the improved PEC response of CdS/ZnS QDs sensitized hematite thin films. Copyright © 2016 John Wiley & Sons, Ltd.     

Nanostructured Zn-Fe2O3 thin film modified by Fe-TiO2 for photoelectrochemical generation of hydrogen

Nanostructured semiconductor thin films of Zn-Fe₂O₃ modified with underlying layer of Fe-TiO₂ have been synthesized and studied as photoelectrode in photoelectrochemical (PEC) cell for generation of hydrogen through water splitting. The Zn-Fe₂O₃ thin film photoelectrodes were designed for best performance by tailoring thickness of the Fe-TiO₂ film. A maximum photocurrent density of 748 μA/cm² at 0.95 V/SCE and solar to hydrogen conversion efficiency of 0.47% was observed for 0.89 μm thick modified photoelectrode in 1 M NaOH as electrolyte and under 1.5 AM solar simulator. To analyse the PEC results the films were characterized for various physical and semiconducting properties using XRD, SEM, EDX and UV–Visible spectrophotometer. Zn-Fe₂O₃ thin films modified with Fe-TiO₂ exhibited improved visible light absorption. A noticeable change in surface morphology of the modified Zn-Fe₂O₃ film was observed as compared to the pristine Zn-Fe₂O₃ film. Flatband potential values calculated from Mott–Schottky curves also supported the PEC response.     

Realization of a compact microstrip antenna: An optimization approach

A new compact square microstrip patch antenna is proposed using the optimization approach, namely, the genetic algorithm (GA). The antenna is designed at three different frequencies, 785 MHz., 1.57 GHz, and 2.46 GHz, for mobile communication, GPS, and Bluetooth applications, respectively. The simulations are carried out using IE3D from Zeland Software, which is based on the method of moments (MoM). The antenna consists of a probe‐fed truncated‐corner square patch with four inserted slits along the four diagonals and four angular grooves along the four edges of the patch. The proposed design has a reduced antenna size, as compared to the conventional microstrip antenna at a given operating frequency. The return loss, impedance, and axial‐ratio bandwidth are determined and compared with the conventional square‐patch antenna. © 2006 Wiley Periodicals, Inc. Int J RF and Microwave CAE, 2006.     

Electrical transport properties of polycrystalline HgTe films grown from mercury-rich HgTe

Measurements of the Hall coefficient and the d.c. conductivity were made on polycrystalline films prepared from mercury-rich HgTe. It was found that, in addition to grain boundary potential barrier scattering, the contribution of ionized impurity scattering is also quite significant. The effect of excess mercury in HgTe is to increase the mobility and to reduce compensating effects.     

Characterization of information improvement due to N revisions and its generalization by a functional equation

The idea of information improvement was introduced by Thiel [3]. This idea was further extended by the first author to information improvement due to 2 and N revisions and specifically states that different experimenters (a finite number) are required to proceed with given distributions P and U and are permitted to choose a suitable revision. We attempted to provide a measure of information corresponding to Theil's measure which reflected the effect of all revisions. In this paper, the authors have studied a joint characterization of information improvement of N revisions and its generalization by considering a suitable functional equation.     

Some statistical inferences regarding population diversity in terms of the hypoentropy measure

We consider a measure of the diversity of a population based on the λ-measure of hypoentropy introduced by Ferreri (1980). Our purpose is to study its asymptotic distribution for testing hypotheses. A numerical example based on real data is given. This work was partially supported by the Dirección General de Investigación Cientifica y Técnica (DGICYT) under the contract PS89-0019.     

Ultrasonic study of silver nanoparticles for various applications

ABSTRACT

Acoustic properties of aqueous solution of AgNO₃ at various concentrations, in presence of Tannic Acid at a fixed concentration (1 × 10^?4 M/L) are studied by ultrasonic method. Tannic acid, a compound derived from plant extracts, is used as the reducing and stabilizing agent to synthesize Ag-NPs and also enables variation of the mean size of Ag-NPs by taking a suitable concentration ratio of AgNO₃ and Tannic acid in distilled water. Ag-NPs are synthesized at room temperature and further stabilized with the aid of sonication. The temperature dependence of acoustic properties is studied and discussed in this paper. Acoustic properties were measured using multi-frequency nano fluid interferometer. It is found that there is a systematic increase in ultrasonic velocity upto 60 ^oC for almost all the concentrations studied and thereafter its value decreases, while this velocity decreases with increasing concentration of AgNO₃ in solution at higher concentrations only. This study is important to find optimum concentration required for a particular application. The present result will be useful as data for various applications.