Electrical conductivity in iodine-doped ethyl cellulose

The electrical conductivity of solution-grown ethyl cellulose (EC) films, 5–30 μm thick, has been studied in the sandwich configuration (metal–EC–metal) as a function of iodine concentration from 0.5 to 5.0 wt% ratio. The studies were conducted in the temperature range 333–383 K, while the field was varied over the range (3.0–5.5) × 10⁴V/cm. Aluminium was used as the lower electrode, while the upper electrode was of Al, Ag, Cu, Au or Sn. Certain transient effects such as a large burst of current immediately after the application of field were observed. An attempt was made to identify the nature of the current by comparing the observed dependence on electric field, electrode material and temperature with the respective characteristic features of the existing theories of electrical conduction. The results show that the electrical conduction follows Ohm's law at lower fields, while at higher fields, space-charge limited current (SCLC) was observed. It was also found that Richardson–Schottky emission was responsible, to some extent, for the transport of charge carriers in the polymer. The conductivity of the films increased on doping with iodine. The dopant molecules are considered to act as additional trapping centes and provide links between the polymer molecules in the amorphous region, thus resulting in the formation of charge transfer complexes.     

Slip Length Measurements Using µPIV and TIRF-Based Velocimetry

The goal of this paper is to review progress (mostly recent) made in micro and nanovelocimetry, focusing on two techniques: µPIV (microparticle image velocimetry) and nanoPTV (nanoparticle tracking velocimetry). The paper focuses on the measurement of slippage (taken as a benchmark for these techniques), concentrating on work done in our group. We review the developments of µPIV that led, in the last ten years, to the achievement of 100 nm accuracy in the measurement of slip lengths. Later, this approach was complemented by nanoPTV, which recently obtained ±5 nm precision. Here, we also mention recent application of these techniques toward better characterization of microgel and polymer flows. As a whole, the two techniques have conveyed valuable information on flow behavior within and close to the boundaries of microchannels, on the importance of wetting, and on the role of surface heterogeneities. µPIV is commercially available but nanoPTV is not mature. Interesting instrumental developments are expected in the future for the latter technique.     

Photochemie von Acylaziden. VIII [1]. Reagieren Acylnitrene wie 1,3-Dipole??

Photochemistry of Acylazides. VIII. Do Acylnitrenes React like 1,3-Dipoles? The formation of three- ore five-membered heterocyclic rings by the reaction of acylnitrenes with olefins depends on the electron density at the double bond. The generally expected formation of aziridines by a cheletropic reaction was observed by photolysis of aroylazides 1 in the presence of 2,5-dihydrofuran 2 . But with enolethers 3 and 4 oxazolines were directly formed. This [3 + 2] cycloaddition is regiospecific. The cycloaddition is modestly stereoselective by steric hindrance within the cyclic enolether 3b . Very small de-values were found with chiral substituents in the acylazide 13 . The azide decomposition was also achieved by photoinduced electron transfer. The same cycloaddition products as obtained by direct photolysis of the azides were obtained via radical anions of the acylazide. Using Michler's ketone as electron donor in the triplet state the formation of isocyanate which diminishes the yield of cycloadducts can be avoided.     

Use of PCR-based methods and PFGE for typing and monitoring homofermentative lactobacilli during Comté cheese ripening

In order to obtain a better understanding of the biochemical events taking place in Saccharomyces cerevisiae during the lag phase, the proteins expressed during the first hours after inoculation were investigated by two-dimensional (2-D) gel electrophoresis and compared to those expressed in late respiratory growth phase. The studies were performed on a haploid strain (S288C) grown in defined minimal medium. Some of the abundant proteins, whose expression relative to total protein expression was induced during the lag phase, were identified by MALDI MS, and the expression of the corresponding genes was assessed by Northern blotting. The rate of protein synthesis was found to increase strongly during the lag phase and the number of spots detected on 2-D gels increased from 502 spots just after inoculation to 1533 spots at the end of the lag phase. During the first 20 min, the number of detectable spots was considerably reduced compared to the number of spots detected from the yeast in respiratory growth just prior to harvest and inoculation (747 spots), indicating an immediate pausing or shutdown in synthesis of many proteins just after inoculation. In this period, the cells got rid of most of their buds. The MALDI MS-identified, lag phase-induced proteins were adenosine kinase (Ado1p), whose cellular role is presently uncertain, cytosolic acetaldehyde dehydrogenase (Ald6p) and (DL)-glycerol-3-phosphatase 1, both involved in carbohydrate metabolism, a ribosomal protein (Asc1p), a fragment of the 70-kDa heat shock protein Ssb1, and translationally controlled tumour protein homologue (Yk1056cp), all involved in translation, and S-adenosylmethionine synthetase I involved in biosynthesis reactions. The level of mRNA of the corresponding genes was found to increase strongly after inoculation. By pattern matching using previously published 2-D maps of yeast proteins, several other lag phase-induced proteins were identified. These were also proteins involved in carbohydrate metabolism, translation, and biosynthesis reactions. The identified proteins together with other, yet unidentified, lag phase-induced proteins are expected to be important for yeast growth initiation and could be valuable biological markers for yeast performance. Such markers would be highly beneficial in the control and optimisation of industrial fermentations.     

Does a Cleaner Thames Pass an Economic Appraisal?

Abstract

Due to substantial clean-up efforts, water quality in the River Thames in London has steadily improved over the last three decades. However, London's Victorian sewage system still discharges untreated sewage into the Thames, at times of moderate to heavy rainfall. This happens approximately 60 times every year, creating adverse environmental and amenity impacts on the river. Major and costly engineering works will be required to solve the sewage overflow problem. This paper reports the results of a stated preference study designed to value the multiple non-market benefits—eductions in sewage litter, risk to human health, and risk to fish populations—associated with a range of potential engineering solutions. Our findings indicate that household willingness to pay for these benefits is likely to be significantly greater than the projected costs per household of, at least, some potential technical solutions. Although arguably justifiable on economic grounds, the final decision on whether to proceed with such a large infrastructure project is unlikely to depend wholly on cost-benefit thinking, but involve complex trade-offs with other socially desirable criteria.     

Surface modification of semiconductor photoelectrode for improved solar cell performance

The investigation is focused on the synthesis of nanostructured TiO₂–CuO admixed photoelectrode and its use as a photoelectrode of high-efficiency PEC solar cells for hydrogen production. TiO₂, in the nanostructured form, has been prepared by hydrolysis of titanium(IV) isopropoxide solution. An improvement in the nanostructured TiO₂ photoelectrode carried out in the present work corresponds to admixing CuO to improve the spectral response. In the present study, photo-electrochemical (PEC) and hydrogen evolution characteristics of new types of ns-TiO₂–CuO admixed/Ti septum-based semiconductor septum photo-electrochemical (SC-SEP PEC) solar cell has been studied. The CuO admixed ns-TiO₂ exhibited a high photocurrent and photovoltage of 18.6 mA/cm² and 680 mV, respectively. The ns-TiO₂–CuO electrode exhibited a higher hydrogen gas evolution rate of 14.00 l/h m².     

Installation of UPFC for enhancing overall performance of electrical power system

Stability of any power system is a major issue for secure operation of the system. The stability of power system is concerned with the behavior of synchronous generators following disturbances. Transmission system in competitive market refers to over loading of transmission lines or transformers due to market settlement. Thus there is a need of enhancing transmission capability of the network. FACTS controllers have the capability of controlling power flow by means of controlling line parameters, voltage injection at some of the angle. In the proposed work optimal location for installation of FACTS device is obtained using NN and the amount of voltage and angle to be injected in the system using UPFC is calculated using Bees algorithm. The method is tested on IEEE 26 bus system but it is general in nature and can be applied to any power system. The results exhibit the performance of the method in maintaining the system stability and АТС enhancement.     

Qualifikation des Datenschutzbeauftragten durch praxisnahe Ausbildung

Die Anforderungen an Fachkunde und Aufgaben eines betrieblichen Datenschutzbeauftragten (DSB) sind hoch. Der Beitrag stellt die am vom Anforderungsprofil eines Datenschutzbeauftragten ausgerichteten Inhalte und Methoden der Ausbildung durch die GDD-Datenschutz-Akademie vor. Dort k?nnen Datenschutzbeauftragte zus?tzlich ihre Qualifikation zertifizieren.