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排序方式: 共有223条查询结果,搜索用时 364 毫秒
1.
Haliza Abdul Aziz Noor Azeerah Abas Bonnie Tay Yen Ping Zainab Idris 《Journal of surfactants and detergents》2020,23(2):251-262
The technology for transesterification reactions between methyl esters and alcohols is well established by using classical homogeneous alkaline catalysts, which provide high conversion of methyl esters to specialty or nonindigenous esters. However, in certain products where the purity of the esters is of concern, the removal of homogeneous catalysts after the completion of the reaction is a challenge in terms of production cost and water footprint. Therefore, a study to investigate the potential of heterogeneous catalysts was conducted on reactions between methyl palmitate and triethanolamine. The degree of basicity and active surface area of calcium oxide (CaO), zinc oxide (ZnO), and magnesium oxide (MgO) were first characterized by using temperature-programmed desorption (TPD-CO2) and Brunauere–Emmett–Teller (BET), respectively. Among the metal oxides investigated, the CaO catalyst showed the best catalytic activity toward the transesterification process as it gave the highest conversion of methyl palmitate and yielded fatty esteramine compositions similar to the conventional homogeneous catalyst. The optimum transesterification condition by using the CaO catalyst utilized a lower vacuum system of approximately 200 mbar, which could minimize a considerable amount of energy consumption. Furthermore, low CaO dosage of 0.1% was able to give a conversion of 94.5% methyl ester and formed esteramine at 170 °C for 2 h. Therefore, the production of esterquats from esteramine may become more economically feasible through the methyl ester route by using the CaO catalyst, which can be recycled three times. 相似文献
2.
Anmar W. Sabri Zainab H. Ali Serwan F. Shawkat Lamia A. Thejar Thaer I. Kassim Khalid A. Rasheed 《河流研究与利用》1993,8(3):237-250
The influences of the Samarra impoundment on the ecology of the downstream sector of the river Tigris are investigated. Zooplankton were collected monthly from July 1987 to July 1988. It was found that zooplankton were most abundant during high river discharges in March. During the month of low river discharge, September, the zooplankton population was greatly reduced immediately below the barrage and remained so to the last downstream station. Several factors seem to explain such differences. The high discharge from the impoundment was found to be the dominating factor and may flush the small backwaters in which zooplankton were abundant, thus increasing the population in the river. Zooplankton species vary in their ability to sustain populations in the river, variations which are due mainly to species-specific characteristics. 相似文献
3.
Khan Muhammad Hussain Saleem Zainab Ahmad Muhammad Sohaib Ahmed Ayaz Hamail Mazzara Manuel Raza Rana Aamir 《Neural computing & applications》2021,33(21):14507-14521
Neural Computing and Applications - Preserving red-chili quality is of utmost importance in which the authorities demand quality techniques to detect, classify, and prevent it from impurities. For... 相似文献
4.
Chitosan-based nanocomposites containing gamma-treated carbon nanotubes (CNTs) were developed for controlled release of pesticide. The CNTs were irradiated under gamma irradiation in air at different doses. The transmission electron microscopic images of gamma-treated CNTs showed disentanglement of the tubes without distorting their tubular structure which effectively increased the dispersion properties of CNTs in nanocomposites. X-ray diffraction analysis of CNTs showed some structural changes, and an irradiation dose of 150 kGy is the most effective. Azinphos methyl (AZM) was selected as a model drug, and its release was studied using HPLC technique. Controlled release response of CNTs-based nanocomposites opens a new avenue for pesticides applications because it requires less quantity of pesticides. As a result, the side effects of pesticide in our environment are minimized. 相似文献
5.
This study pertains to the conformational changes of Poly (vinylbenzyltrimethylammonium chloride) (PVBTMAC) brush onto SiO2-coated resonator; which was further incorporated by using quartz crystal microbalance with dissipation (QCM-D) in the presence of Hofmeister series of anions as a function of ionic strength. Gradual shrinkage of highly extended PVBTMAC followed by loose inhomogeneous layer was on account of change in frequency (?f) and dissipation (??D) at low ionic strength. On the contrary, the increase in ionic strength collapses chains and dense homogenous layer is formed. The chaotropic anions comparativley bring drastic change in frequency unlike kosmotropic anions. This is because weakly hydrated chaotropic anions form strong ion pair with weakly hydrated trimethyl ammonium group on the PVBTMAC brush and as a result strong counter ion condensation was observed on polymer chain. Thus, the apparent mass associated with PVBTMAC chains increases that accounts for large change in ?f. 相似文献
6.
Zainab Z. Ismail Basma B. Hameed 《The International journal of environmental studies》2013,70(2):122-138
Excess nitrogen is one of the main causes of eutrophication in water bodies. In this study, the undesirable agricultural lignocellulosic material giant reed was used to remove ammonium ions from aqueous solutions. Batch experiments were conducted to investigate the effect of various parameters such as contact time, initial ammonium concentration, adsorbent dosage, pH, particle size, agitation rate and phosphate coexisting during the ammonium adsorption process. The ammonium sorption capacity of fibrous giant reed (FGR) at equilibrium was 12.49?mg?N/g with a maximum removal efficiency of 76% observed within 30?min at pH range of 6.5–9.5. Results revealed that the Freundlich isotherm model fitted better with the sorption process than the Langmuir model, and the adsorption process was well described by pseudo-second-order kinetic model. FT-IR analyses indicated that complexation and ion exchange could be the main mechanisms for the ammonium removal by FGR. Results revealed that FGR has a sorption capacity comparable to that of other natural sorbents with the advantage of greater availability with no cost. 相似文献
7.
Zainab Z. Ismail 《The International journal of environmental studies》2013,70(1):135-149
The presence of excessive amounts of nutrients including phosphates in water is undesirable. They cause the deterioration of water quality and problems in many natural and engineering systems. The recycling of agricultural waste materials as biosorbents for contaminants removal provides a cheap and ecological means to reduce wastes. This study explored the use of date palm wastes for the effective removal of phosphate from aqueous solutions. Granular date stones (GDS) and palm surface fibres (PSF) as raw abundant waste materials were examined for PO4 -3 removal from aqueous solution. The experimental work was performed in a batch mode to investigate the influence of initial phosphate concentration, contact time, and pH of solution on phosphate biosorption. The FT-IR spectra for the waste materials display many adsorption peaks, confirming the complex nature of the GDS and PSF. Phosphate percentage removal up to 87 and 85% were obtained at initial PO4 -3 concentration of 50 mg as P/L using GDS and PSF, respectively. Due to their low cost and high capability, these types of waste can be used for cost-effective removal of phosphate from wastewater. 相似文献
8.
Rabia Rasool Inam Ullah Bismillah Mubeen Sultan Alshehri Syed Sarim Imam Mohammed M. Ghoneim Sami I. Alzarea Fahad A. Al-Abbasi Bibi Nazia Murtaza Imran Kazmi Muhammad Shahid Nadeem 《International journal of molecular sciences》2022,23(3)
Breast cancer is a diverse disease caused by mutations in multiple genes accompanying epigenetic aberrations of hazardous genes and protein pathways, which distress tumor-suppressor genes and the expression of oncogenes. Alteration in any of the several physiological mechanisms such as cell cycle checkpoints, DNA repair machinery, mitotic checkpoints, and telomere maintenance results in genomic instability. Theranostic has the potential to foretell and estimate therapy response, contributing a valuable opportunity to modify the ongoing treatments and has developed new treatment strategies in a personalized manner. “Omics” technologies play a key role while studying genomic instability in breast cancer, and broadly include various aspects of proteomics, genomics, metabolomics, and tumor grading. Certain computational techniques have been designed to facilitate the early diagnosis of cancer and predict disease-specific therapies, which can produce many effective results. Several diverse tools are used to investigate genomic instability and underlying mechanisms. The current review aimed to explore the genomic landscape, tumor heterogeneity, and possible mechanisms of genomic instability involved in initiating breast cancer. We also discuss the implications of computational biology regarding mutational and pathway analyses, identification of prognostic markers, and the development of strategies for precision medicine. We also review different technologies required for the investigation of genomic instability in breast cancer cells, including recent therapeutic and preventive advances in breast cancer. 相似文献
9.
10.
Abstract. This article establishes the strong consistency and asymptotic normality (CAN) of the quasi-maximum likelihood estimator (QMLE) for generalized autoregressive conditionally heteroscedastic (GARCH) and autoregressive moving-average (ARMA)-GARCH processes with periodically time-varying parameters. We first give a necessary and sufficient condition for the existence of a strictly periodically stationary solution of the periodic GARCH (PGARCH) equation. As a result, it is shown that the moment of some positive order of the PGARCH solution is finite, under which we prove the strong consistency and asymptotic normality of the QMLE for a PGARCH process without any condition on its moments and for a periodic ARMA-GARCH (PARMA-PGARCH) under mild conditions. 相似文献